Cr-spinel/olivine and Cr-spinel/liquid nickel partition coefficients from natural samples     

Chusi Li  Edward M. Ripley  Edmond A. Mathez 《Geochimica et cosmochimica acta》2008,72(6):1678-1684

The Nernst partition coefficient of nickel (D^Ni) between Cr-spinel and silicate melt in natural systems has been investigated using mid-ocean ridge basalts (MORB) and other volcanic rocks. The Cr-spinel/olivine D^Ni values in volcanic rocks are between 1.2 and 0.3, indicating that the Cr-spinel/liquid D^Ni values vary from slightly higher to significantly lower than the olivine/liquid D^Ni values in natural systems. The Cr-spinel/liquid D^Ni values from the MORB samples vary between 6 and 11, slightly higher than those from the S-bearing experiments of Satari et al. [Satari P., Brenan J. M., Horn I. and McDonough W. F. (2002) Experimental constraints on the sulfide- and chromite-silicate melt partitioning behavior of rhenium and platinum-group elements. Economic Geology97, 385-398]. The results of the MORB samples and the experiments of Satari et al. (2002) indicate a negative correlation between the Cr-spinel/liquid D^Ni and the X_Cr values in Cr-spinels (Cr cation number on the basis of 3 total cations in the spinel structure). Variations of Cr-spinel/liquid D^Ni values with Cr-spinel compositions can be estimated from an empirical equation based on the results of the MORB samples and the experiments by Satari et al. (2002). The choice of Cr-spinel/liquid D^Ni = 10 for numerical modeling by Righter et al. [Righter K., Leeman W. P. and Hervig R. L. (2006) Partitioning of Ni, Co, and V between spinel-structured oxides and silicate melts: importance of spinel composition. Chemical Geology227, 1-25] is reasonable for basaltic systems. For picritic and komatiitic systems a lower value of ∼5 is more appropriate.  相似文献   

Carbon Isotope Geochemistry of the Orinoco Basin     

F. C. Tan  J. M. Edmond 《Estuarine, Coastal and Shelf Science》1993,36(6)

Stable carbon isotope ratios have been used to study the sources of particulate organic carbon (POC) and total dissolved inorganic carbon in the Orinoco Basin. The isotopic composition of total dissolved inorganic carbon shows a range of from -8·1 to -23·0 ppt, an indication of dominance of biological processes. The isotopic composition of POC exhibits a range of from -24·1 to -34·6 ppt with little seasonal variation. The isotopic evidence indicates that the POC is predominantly of terrestrial origin rather than a result of in situ planktonic production. The similarity of isotopic composition of POC and coastal sediments suggests that riverine organic detritus has been transported 30-50 km offshore in a direction parallel to the Orinoco river channel.  相似文献   

Effect of shallow and narrow water on added mass of cylinders with various cross-sectional shapes     

Z.X. Zhou  Edmond Y.M. Lo  S.K. Tan 《Ocean Engineering》2005,32(10):1199-1215

The sway, heave and roll added masses of three uniform cylinders with semi-circular, rectangular and triangular cross-sectional shapes in shallow and narrow water are numerically analysed. The method is based on simulation of the potential flow induced by the cylinder's mode of motion. The effects of shallow and narrow water on added mass are analysed and presented. It is concluded that the shallow and narrow water effects on added mass depend on the different cross-section shapes of the cylinders. In particular, the water depth effect on sway added mass is stronger than that on heave added mass while the narrow water effect on sway is weaker than that on heave. The shallow water effect on added mass tends to weaken the narrow water effect. Lastly the effect of shallow and narrow water on added mass on a rectangular cylinder is the strongest while that on a triangular cylinder is the weakest.  相似文献   

Interaction between atmospheric flows and obstacles: Experiments in a rotating channel     

S. Alessio  L. Briatore  E. Ferrero  A. Longhetto  C. Giraud  O. Morra 《Boundary-Layer Meteorology》1992,60(3):235-241

We performed an experimental study using scale models in a hydrodynamic rotating channel, concerning the interactions between fluid flows and obstacles of different shapes. The study was meant to analyze the characteristics of the wakes observed on the lee side of quasi-bidimensional obstacles, in a neutral atmosphere.The obstacles were half-cylinders (with aspect ratio 0.87), placed transversally on the channel bottom and totally submerged in the fluid. We call them quasi-bidimensional since their width was a little smaller than the channel width, thus allowing the flow to partially go round their edges.The simulations were performed in the rotating hydraulic channel of ICG-CNR in Turin, and included various conditions of rotation period and flow speed. An interesting behaviour of the wakes was found on the lee side of subsynoptic-scale obstacles, modelled in conditions of Reynolds-Rossby similitude. More precisely, if a given threshold of flow velocity is exceeded, wake size is constant and is fully determined by the height of the obstacle.  相似文献   

Time-dependent behaviour of deep clays   总被引：1，自引：0，他引：1  

A. Giraud  G. Rousset 《Engineering Geology》1996,41(1-4):181-195

The time-dependent behaviour of deep saturated clays is related both to the effects of hydraulic diffusion and of viscosity. In this paper, we present first, by means of an experimental approach, the main features of the mechanical properties of deep clays. Then, we study the effects of these specific behaviours on the time-dependent behaviour of underground structures. We present theoretical and numerical investigations of the effects of pore pressure diffusion resulting from a tunnel excavation in a poroplastic or poroviscoplastic medium. Finite-element calculations show that the time-dependent convergence of the tunnel wall is non negligible. Then, we focus on the behaviour of a cylindrical thermal source buried in a deep clay.

Coupling effects between thermal, hydraulic and mechanical behaviours are very important in soft and low permeable deep clays (saturated compressible clays with high porosity). We show in particular that the displacements and the stresses are very sensitive to the constitutive model. Irreversible behaviour may be traduced by appearance of residual stresses within the rockmass.  相似文献   

Effect of suction on the mechanical behaviour of iron ore rock   总被引：1，自引：0，他引：1  

Dragan Grgic  Richard Giot  Franoise Homand  Albert Giraud 《国际地质力学数值与分析法杂志》2005,29(8):789-827

The effect of suction on the behaviour of iron ore has been studied from both physical and mechanical points of view. The porosity and the suction phenomena have been analysed using different experimental techniques. Uniaxial compressive tests on partially saturated samples have shown that the suction is responsible for strength and cohesion improvement. Considering the theory of partially saturated porous soils of Coussy and Dangla (Mécanique des sols non saturés (2002 edn). Hermès Science: 2002; 390), we have proposed a constitutive law for partially saturated iron ore. The real increase in the apparent cohesion due to the capillary attraction forces is overestimated if the yield function is written in terms of effective stresses. The effect of the capillary cohesion has been modelled with a function in the expression of the apparent cohesion of the yield function. The effect of suction on the mechanical behaviour has been represented in the effective stresses space and in the total stresses space like the Alonso model (Géotechnique 1990; 40 :405–430). Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Reproduction of the fiddler crabsUca longisignalis andUca spinicarpa in a Gulf of Mexico salt marsh     

Edmond C. Mouton  Darryl L. Felder 《Estuaries and Coasts》1995,18(3):469-481

Monthly field sampling of active animals in a Louisiana coastal salt marsh monitored changes in size class frequency distributions, ovarian development of females, and rates of egg extrusion for two species ofUca endemic to the Gulf of Mexico. Ovigerous females occurred no earlier than February forUca spinicarpa and April forUca longisignalis. Peak percentages of ovigerous females were observed in June 1992 forUca longisignalis (67%) and in March 1993 forUca spinicarpa (85%). Peaks in ash-free dry weight (AFDW, in g) of females coincide with peak periods of ovarian development and subsequent ovigery. Mean biomass as AFDW of males and females combined forUca longisignalis was 0.26 g individual^?1 and forUca spinicarpa was 0.17 g individual^?1. A significant correlation existed between AFDW and carapace width in both species, males and females.U. longisignalis appears to be of warm-temperate lineage, and its reproductive activity is the more seasonally restricted, with later ovarian development, earliest egg laying delayed to late spring, and peak ovigery in summer. In keeping with putative tropical affinities ofUca spinicarpa, ovarian development is episodic over a longer-period from late winter to summer, and eggs are produced earlier in the year. The more striking seasonality in reproductive activity and biomass peaks forUca longisignalis may also reflect some nutritional dependency on temperate, annual marsh plants that characterize its preferred habitats.  相似文献   

A comparison of single scattering and finite difference synthetic seismograms in realizations of 2-D elastic random media     

Richard T. Coates  Edmond E. Charrette 《Geophysical Journal International》1993,113(2):463-482

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Acoustic sounding of land and sea breezes     

P. Bacci  C. Giraud  A. Longhetto  R. Richiardone 《Boundary-Layer Meteorology》1984,28(1-2):187-192

Sodar measurements have been made at La Spezia, Italy during land- and sea-breeze conditions. The backscatter returns are discussed qualitatively, including their relation to the vertical structure of the boundary layer as revealed by vertical soundings of wind and temperature. During inversion conditions, the sodar signals may be difficult to interpret especially when there is a land breeze flowing over irregular terrain.  相似文献   

Refinement of the Kudo-Weill plagioclase thermometer and its application to basaltic rocks   总被引：1，自引：0，他引：1  

Edmond A. Mathez 《Contributions to Mineralogy and Petrology》1973,41(1):61-72

The Kudo-Weill plagioclase thermometer is applied to basaltic rocks. Comparison of measured and calculated crystallization temperatures shows that the latter are generally higher than measured values. The plagioclase thermometer predicts non-ideal behavoir of plagioclase solid solution and is in close agreement with experimental work at lower temperature. New equations are generated that relate plagioclase and melt chemistries to plagioclase crystallization temperatures; and these, combined with activity coefficient corrections, result in a refinement of the plagioclase thermometer.  相似文献