Ion Irradiation of Asphaltite: Optical Effects and Implications for Trans-Neptunian Objects and Centaurs     

Moroz  L. V.  Baratta  G.  Distefano  E.  Strazzulla  G.  Starukhina  L. V.  Dotto  E.  Barucci  M. A. 《Earth, Moon, and Planets》2003,92(1-4):279-289

Trans-Neptunian Objects (TNOs) and Centaurs show remarkable colour variationsin the visual and near-infrared spectral regions. Surface alteration processes such asspace weathering (e.g., bombardment with ions) and impact resurfacingmay play an important role in the colour diversity of such bodies. Ion irradiation ofhydrocarbon ices and their mixtures with water ice transforms neutral (grey) surfacecolours of ices to red and further to grey. Along with the ices, TNOs and Centaursprobably contain complex carbonaceous compounds, in particular, complexhydrocarbons. Unlike ices, such refractory organic materials have originally lowvisual albedos and red colours in the visible and near-infrared ranges. Here wepresent the first results of ion irradiation experiments on asphaltite. Asphaltite isa natural complex hydrocarbon material. The reflectance spectra of asphaltite inthe 0.4–0.8 μm range have been recorded before irradiation and after eachirradiation step. We demonstrate that irradiation of this red dark material with30 keV H⁺ and 15 keV N⁺ ions gradually transforms its colour from redto grey as a result of carbonization. A moderate increase in the visual albedo hasbeen observed. These results may imply that the surfaces of primitive red objectsoptically dominated by complex refractory organics may show a similar spaceweathering trend. Our laboratory results were compared with published coloursof TNOs and Centaurs. A broad variety of spectral colours observed for TNOs andCentaurs may be reproduced by various spectra of irradiated organics correspondingto different ion fluences. However, such objects probably also contain ices and silicatecomponents which show different space weathering trends. This fact, together with alack of information about albedos, may explain difficulties to reveal correlations between surface colours within TNO and Centaur populations and their other properties, such as absolute magnitudes and orbital parameters.  相似文献   

Cloning of a chub metallothionein cDNA and development of competitive RT-PCR of chub metallothionein mRNA as a potential biomarker of heavy metal exposure   总被引：3，自引：0，他引：3  

Hayes RA  Regondi S  Winter MJ  Butler PJ  Agradi E  Taylor EW  Kevin Chipman J 《Marine environmental research》2004,58(2-5):665-669

Metallothionein has been assayed in a range of aquatic animal tissues as an indicator of metal exposure. We sequenced chub (Leuciscus cephalus) metallothionein cDNA which showed over 90% homology to common carp, goldfish and stone loach and 77% homology to rainbow trout sequences for metallothionein. We then used the extended primer method to develop an accurate quantitative competitive RT-PCR assay for metallothionein mRNA. RT-PCR was used to measure metallothionein mRNA in feral chub from a range of field sites, with different levels of heavy metal pollution, in the West Midlands, UK. Measurements were complemented by analysis of liver and gill metallothionein protein by capillary electrophoresis. There was no significant difference in the metallothionein protein levels between fish of different rivers and there was no evidence of elevation of mRNA at the sites of highest metal exposure. The level of metal exposure (e.g. zinc, nickel and cadmium each ranging between 15 and 28 microg/l ) at the pH (7.5-8.5) of these rivers appears insufficient to elevate hepatic or gill metallothionein in chub. A lack of elevation of hepatic metallothionein mRNA in chub exposed to zinc, copper and manganese for 24 h and 10 days in the laboratory also suggests a non-responsiveness of this species.  相似文献   

A Block-Based Theoretical Model Suited to Gravitational Sliding     

Tinti  Stefano  Bortolucci  Elisabetta  Vannini  Cesare 《Natural Hazards》1997,16(1):1-28

An original theoretical model has been devised to simulate mass flow over hill slopes due to gravitational sliding. The sliding mass is discretized into a sequence of contiguous blocks which are subjected to gravitational forces, to bottom friction and to surface resistance stresses that are generally negligible for subaerial flows, but are relevant for submarine slides. The blocks interact with each other while sliding down the hill flanks because of internal forces that dissipate mechanical energy and produce a momentum exchange between the individual blocks, yet conserving the total momentum of the mass. Internal forces are expressed in terms of interaction coefficients depending on the instantaneous distance between the block centers of mass, which is a measure of the deformation experienced by the blocks: the functional dependence includes three parameters, namely the interaction intensity ¯, the deformability parameter and the shape parameter , by means of which a wide range of interaction types can be fully accounted for. The time integration is performed numerically by solving the equations for the block velocities and positions at any time ti by means of the block accelerations at the previous time t_i-1, and by subsequently updating the block accelerations, which allows to proceed iteratively to the following times. The model has been tested against laboratory results available from literature and by means of several numerical experiments involving a simplified geometry both for the sliding body and the basal surface, with the purpose of clarifying the influence of the model parameters on the slide dynamics. The model improves the performance of the existing kinematic models for slides, moreover preserving an equivalent numerical simplicity. Future applications and possible improvements of this model are suggested.  相似文献   

Atmospheric nitrogen inputs into the North Sea: effect on productivity     

Gerrit de Leeuw  Lucinda Spokes  Tim Jickells  Carsten Ambelas Skjth  Ole Hertel  Elisabetta Vignati  Susanne Tamm  Michael Schulz  Lise-Lotte Srensen  Britta Pedersen  Laura Klein  K. Heinke Schlünzen 《Continental Shelf Research》2003,23(17-19):1743

The ANICE (Atmospheric Nitrogen Inputs into the Coastal Ecosystem) project addressed the atmospheric deposition of nitrogen to the North Sea, with emphasis on coastal effects. ANICE focused on quantifying the deposition of inorganic nitrogen compounds to the North Sea and the governing processes. An overview of the results from modelling and experimental efforts is presented. They serve to identify the role of the atmosphere as a source of biologically essential chemical species to the marine biota. Data from the Weybourne Atmospheric Observatory (UK) are used to evaluate the effect of short episodes with very high atmospheric nitrogen concentrations. One such episode resulted in an average deposition of 0.8 mmol N m⁻² day⁻¹, which has the potential to promote primary productivity of 5.3 mmol C m⁻² day⁻¹. This value is compared to long-term effects determined from model results. The total calculated atmospheric deposition to the North Sea in 1999 is 948 kg N km⁻¹, i.e. 0.19 mmol N m⁻² day⁻¹ which has the potential to promote primary productivity of 1.2 mmol C m⁻² day⁻¹. Detailed results for August 1999 show strong gradients across the North Sea due to adjacent areas where emissions of NO_x and NH₃ are among the highest in Europe. The average atmospheric deposition to the southern part of the North Sea in August 1999 could potentially promote primary production of 2.0 mmol C m⁻² day⁻¹, i.e. 5.5% of the total production at this time of the year in this area of the North Sea. For the entire study area the atmospheric contribution to the primary production per m² is about two-third of this value. Most of the deposition occurs during short periods with high atmospheric concentrations. This atmospheric nitrogen is almost entirely anthropogenic in origin and thus represents a human-induced perturbation of the ecosystem.  相似文献   

Large wood transport modelling by a coupled Eulerian–Lagrangian approach     

Elisabetta Persi  Gabriella Petaccia  Stefano Sibilla 《Natural Hazards》2018,91(1):59-74

The paper discusses a model which predicts the trajectory of floating rigid bodies and may be applied to compute the motion of woody “debris” mobilized during floods. The model couples a Discrete Element (DE) Lagrangian approach for the calculation of motion of rigid bodies with the Eulerian solution of the shallow water equations (SWE), in order to simulate the transport of a cylinder in a two-dimensional stream. It differs from existing models since it is based on a dynamic approach, adapting the Basset–Boussinesq–Oseen equation. In a first step, forces are computed from flow and log velocities; then, the equations of dynamics are solved to model the planar roto-translation of the body. Model results and physical reliability are clearly affected by the values of the drag and side coefficients, especially since logs, modelled as cylinders, are able to change their orientation towards the flow. Experimental studies to evaluate drag and side coefficients can be found in the literature for a submerged cylinder, with various orientations. To extend such results to the case of a floating log, the authors performed a series of laboratory tests on partially submerged cylinders, implementing the outcomes in the proposed DE-SWE model. The coupled model is validated against existing laboratory data concerning spheres and wooden cylinder transport.  相似文献   

Clinopyroxenes from mantle-related xenocrysts in alkaline basalts from Hannuoba (China): augite–pigeonite exsolutions and their thermal significance     

Elisabetta?Brizi  Sabrina?NazzareniEmail author  Francesco?Princivalle  Pier?Francesco?Zanazzi 《Contributions to Mineralogy and Petrology》2003,145(5):578-584

Optically homogeneous augite xenocrysts, closely associated with spinel–peridotite nodules, occur in alkali basalts from Hannuoba (Hebei province, China). They were studied by electron and X-ray diffraction to define the occurrence and significance of pigeonite exsolution microtextures. Sub-calcic augite (Wo₃₄) exsolved into En_62–62Fs_25–21Wo_13–17 pigeonite and En_46–45Fs_14–14Wo_40–42 augite, as revealed by TEM through diffuse coarser (001) lamellae (100–300 Å) and only incipient (100) thinner ones (<70 Å). C2/c augite and P2₁/c pigeonite lattices, measured by CCD-XRD, relate through a(Aug)?a(Pgt), b(Aug)?b(Pgt), c(Aug)≠c(Pgt) [5.278(1) vs 5.189(1)Å] and β(Aug)≠β(Pgt) [106.55(1) vs 108.55(2)°]. Cell and site volumes strongly support the hypothesis that the augite xenocrysts crystallised at mantle depth from alkaline melts. After the augite xenocrysts entered the magma, (001) lamellae first formed by spinodal decomposition at a T_min of about 1,100 °C, and coarsened during very rapid transport to the surface; in a later phase, possibly on cooling, incipient (100) lamellae then formed.  相似文献   

Physical investigation of the potentially hazardous Asteroid (144898) 2004 VD17     

F. De Luise  D. Perna  E. Dotto  I.N. Belskaya  G.B. Valsecchi  A. Rossi  P. Paolicchi 《Icarus》2007,191(2):628-635

In this paper we present the observational campaign carried out at ESO NTT and VLT in April and May 2006 to investigate the nature and the structure of the near-Earth object (144898) 2004 VD17. In spite of a great quantity of dynamical information, according to which it will have a close approach with the Earth in the next century, the physical properties of this asteroid are largely unknown. We performed visible and near-infrared photometry and spectroscopy, as well as polarimetric observations. Polarimetric and spectroscopic data allowed us to classify 2004 VD17 as an E-type asteroid. A good agreement was also found with the spectrum of the aubrite meteorite Mayo Belwa. On the basis of the polarimetric albedo (pv=0.45) and of photometric data, we estimated a diameter of about 320 m and a rotational period of about 2 h. The analysis of the results obtained by our complete survey have shown that (144898) 2004 VD17 is a peculiar NEO, since it is close to the breakup limits for fast rotator asteroids, as defined by Pravec and Harris [Pravec, P., Harris, A.W., 2000. Icarus 148, 12-20]. These results suggest that a more robust structure must be expected, as a fractured monolith or a rubble pile in a “strength regime” [Holsapple, K.A., 2002. Speed limits of rubble pile asteroids: Even fast rotators can be rubble piles. In: Workshop on Scientific Requirements for Mitigation of Hazardous Comets and Asteroids, Washington, September, 2002].  相似文献   

The light curve of asteroid 2867 Steins measured by VIRTIS-M during the Rosetta fly-by     

F. Tosi  A. Coradini  G. Filacchione  M.C. De Sanctis  M.A. Barucci  S. Mottola  E. Dotto  The VIRTIS Team 《Planetary and Space Science》2010,58(9):1066-1076

On 5 September 2008, the Rosetta spacecraft encountered the asteroid 2867 Steins on its way to the comet 67P/Churyumov-Gerasimenko. This was the first of two planned asteroid fly-bys performed by the probe, the second fly-by being with the much larger asteroid 21 Lutetia in July 2010. The VIRTIS imaging spectrometer (IFOV 0.250 mrad, overall spectral range 0.25-5.1 μm) onboard Rosetta acquired data of Steins already before the closest approach phase, when the target was spatially unresolved, in order to obtain a light curve of the asteroid in the infrared spectral range extending up to 5 μm, that was never explored before. The VIRTIS light curve campaign started at 11:30 UTC onboard time, when the spacecraft was about 221,377 km away from the target, and ended at 17:58 UTC, at a distance of 20,741 km away from Steins. During this timeframe, the solar phase angle of the asteroid was roughly constant, ranging from 38.2° to 36.3°.Assuming the most recent value derived for the rotational period of Steins (Lamy et al., 2008), the VIRTIS observations covered slightly more than one rotation of the asteroid. In this interval, VIRTIS collected 8 hyperspectral cubes where Steins was captured 119 times, both in the visual and in the infrared range. Given the low signal and the unresolved appearance of the source, for which the instrument was not designed, only a small subset of wavelengths turned out to be suitable to sample the light curve. Nevertheless, in both the VIS and NIR ranges we find a similar trend, with two different maxima and minima during one rotational period, and amplitudes consistent with the results in the visual range obtained in previous works, including the data set acquired by the OSIRIS camera onboard Rosetta. We also report the presence of a new broad feature centered at approximately 0.81-0.82 μm, which is seen in the visual data throughout the rotation of the asteroid.  相似文献   

Natural background levels and threshold values derivation for naturally As, V and F rich groundwater bodies: a methodological case study in Central Italy     

Elisabetta Preziosi  Giuseppe Giuliano  Raffaella Vivona 《Environmental Earth Sciences》2010,61(5):885-897

Natural background levels (NBL) and threshold values (TV) derivation is an important task for EU Member States to correctly assess the chemical status of groundwater bodies within the context of the recently adopted Groundwater Directive. Attempts are being made both by water authorities and scientific community to test application viability of proposed methods to different real situations and to develop tailored adjustments and refinements. The aim of this paper is to describe a methodological case study of NBL and TV determination in a large area (5,500 km²) located in Central Italy where both natural and anthropogenic contamination occurs, resulting in several substances be detected in ground waters with concentration frequently exceeding drinking water standards. This paper shows the key role played in the determination process by knowledge on the hydrogeological setting and hydrogeochemical features. The adoption of appropriate pre-selection criteria of samples, the establishment of TV at the groundwater body scale for natural origin substances, and the evaluation of TVs exceedances in a multiparameter context are experimentally discussed. Beyond the critical evaluation of NBL and TV determination method, this research aims at increasing consciousness in the water management agencies that groundwater status assessment should be conceived as a scientific evaluation procedure and not as a mere technical/administrative exercise to be performed using any set of available data. As such, it should be supported by adequate knowledge of hydrogeological setting, hydrochemical processes occurring in groundwater bodies, and human activities acting overland to be progressively verified.  相似文献   

Spectral alteration of the Meteorite Epinal (H5) induced by heavy ion irradiation: a simulation of space weathering effects on near-Earth asteroids     

G. Strazzulla  E. Dotto  R. Brunetto  A. Blanco 《Icarus》2005,174(1):31-35

We present results obtained for Epinal (H5), an ordinary chondrite meteorite, irradiated with 60 keV Ar⁺⁺ ions, simulating solar wind heavy particle irradiation. Bidirectional reflectance spectra (0.3-2.67 μm) measured after irradiating Epinal samples with different ion fluences exhibit a progressive reddening that is similar to the spread of spectra observed for S-type near-Earth asteroids. The timescales for inducing the same effects in space as those obtained in laboratory are estimated to be ¹⁰⁴-¹⁰⁶ yr. These results suggest irradiation by heavy ions may be a very efficient weathering process in near-Earth space.  相似文献