Thermal stability of ladderane lipids as determined by hydrous pyrolysis   总被引：1，自引：0，他引：1  

Andrea Jaeschke  Michael D. Lewan  Ellen C. Hopmans  Stefan Schouten  Jaap S. Sinninghe Damst 《Organic Geochemistry》2008,39(12):1735

Anaerobic ammonium oxidation (anammox) has been recognized as a major process resulting in loss of fixed inorganic nitrogen in the marine environment. Ladderane lipids, membrane lipids unique to anammox bacteria, have been used as markers for the detection of anammox in marine settings. However, the fate of ladderane lipids after sediment burial and maturation is unknown. In this study, anammox bacterial cell material was artificially matured by hydrous pyrolysis at constant temperatures ranging from 120 to 365 °C for 72 h to study the stability of ladderane lipids during progressive dia- and catagenesis. HPLC-MS/MS analysis revealed that structural alterations of ladderane lipids already occurred at 120 °C. At temperatures >140 °C, ladderane lipids were absent and only more thermally stable products could be detected, i.e., ladderane derivatives in which some of the cyclobutane rings were opened. These diagenetic products of ladderane lipids were still detectable up to temperatures of 260 °C using GC-MS. Thus, ladderane lipids are unlikely to occur in ancient sediments and sedimentary rocks, but specific diagenetic products of ladderane lipids will likely be present in sediments and sedimentary rocks of relatively low maturity (i.e., C₃₁ hopane 22S/(22S + 22R) ratio <0.2 or ββ/(αβ + βα + ββ) ratio of >0.5).  相似文献   

Dissolved carbon and 33-133-133-1anomalies in the water column caused by hydrocarbon seeps on the northwestern Gulf of Mexico slope     

Paul Aharon  Ellen R. Graber  Harry H. Roberts 《Geo-Marine Letters》1992,12(1):33-40

Alkalinity, dissolved inorganic carbon (DIC), and ¹³C profiles from seep sites on the northwestern Gulf of Mexico upper slope show anomalously negative ¹³C values of up to –4.5 PDB, increased levels of DIC of up to 2.45 mmole/liter, and slight alkalinity rises of up to 2.54 meq/liter, relative to water column profiles from a seep-free site (0.63, 2.04 mmole/liter, and 2.39 meq/liter). The observed DIC enrichments coupled with the¹³C-depletions are attributed to the release of CO₂ by microbial oxidation of crude oil in the seep environment, and its migration into the water column. The ¹³C composition of the migrating CO₂ is estimated to be –26.0 on the basis of dissolved carbon inventory. Manifestation of DIC and ¹³C anomalies in the water column caused by hydrocarbon seepage holds promise to be useful for hydrocarbon reconnaissance surveys over large offshore tracts on account of the simplicity of sampling acquisition, and rapidity of analytical techniques in the laboratory.  相似文献   

Contaminant concentrations and toxicity of sea-surface microlayer near Los Angeles, California     

Jeffrey N. Cross  John T. Hardy  Jo Ellen Hose  G.Patrick Hershelman  Liam D. Antrim  Richard W. Gossett  Eric A. Crecelius 《Marine environmental research》1987,23(4)

Sea-surface microlayer samples were collected from six nearshore areas receiving different amounts of anthropogenic inputs. The samples were analyzed for selected trace metals, chlorinated hydrocarbons, and polycyclic aromatic hydrocarbons. The relative toxicities of the samples were determined with fish embryo bioassays.Contaminant concentrations generally increased from offshore to the inshore stations. Contaminant concentrations were several orders of magnitude higher in microlayer samples from the highly industrialized Los Angeles and Long Beach harbors compared to samples from a site 15km offshore. Microlayer samples from the inshore stations were significantly more toxic, and induced significantly more developmental abnormalities and chromosome aberrations, than samples from the offshore stations.  相似文献   

Machine Learning for Improving Surface-Layer-Flux Estimates     

McCandless  Tyler  Gagne  David John  Kosović  Branko  Haupt  Sue Ellen  Yang  Bai  Becker  Charlie  Schreck  John 《Boundary-Layer Meteorology》2022,185(2):199-228

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Geology and tectonics of the Themis Regio-Lavinia Planitia-Alpha Regio-Lada Terra area,Venus: Results from Arecibo image data     

D. A. Senske  D. B. Campbell  J. W. Head  P. C. Fisher  A. A. Hine  A. deCharon  S. L. Frank  S. T. Keddie  K. M. Roberts  E. R. Stofan  J. C. Aubele  L. S. Crumpler  N. Stacy 《Earth, Moon, and Planets》1991,55(2):97-161

New radar images obtained from the Arecibo Observatory (resolution 1.5–4.0 km) for portions of the southern hemisphere of Venus show that: the upland of Phoebe Regio contains the southern extension of Devana Chasma, a rift zone extending 4200 km south from Theia Mons and interpreted as a zone of extension; Alpha Regio, the only large region of tessera within the imaged area, is similar to tessera mapped elsewhere on the planet and covers a smaller percentage of the surface than that observed in the northern high latitudes; the upland made of Ushas, Innini and Hathor Montes consists of three distinct volcanic constructs; Themis Regio is mapped as an ovoid chain of radar-bright arcuate single and double ring structures, edifices and bright lineaments. This area is interpreted as a region of mantle upwelling and on the basis of apparent split and separated features, a zone of localized faulting and extension. Linear zones of deformation in Lavinia Planitia are characterized by lineament belts that are often locally elevated, are similar to ridge belts mapped in the northern high latitudes and are interpreted to be characterized mainly by compression; radar-bright lava complexes within Lavinia Planitia are unique to this part of the planet and are interpreted to represent areas of eruption of high volumes of extremely fluid lava; the upland of Lada Terra is bound to the north by a linear deformation zone interpreted as extensional, is characterized by large ovoids and coronae, is interpreted to be associated with an area of mantle upwelling, and is in contrast to the northern high latitude highland of Ishtar Terra. Regions of plains in the southern hemisphere cover about 78%; of the mapped area and are interpreted to be volcanic in origin. Located within the area imaged (10–78 S) are 52 craters interpreted to be of impact origin ranging from 8 to 157 km in diameter. On the basis of an overall crater density of 0.94 craters/10⁶ km², it is determined that the age of this part of the Venus surface is similar to the 0.3 to 1.0 billion year age calculated for the equatorial region and northern high latitudes. The geologic characteristics of the portion of the Venus southern hemisphere imaged by Arecibo are generally similar to those mapped elsewhere on the planet. This part of the planet is characterized by widespread volcanic plains, large volcanic edifices, and zones of linear belt deformation. The southern hemisphere of Venus differs from northern high latitudes in that tessera makes up only a small percentage of the surface area and the ovoid chain in Themis Regio is unique to this part of the planet. On the basis of the analysis presented here, the southern hemisphere of Venus is interpreted to be characterized by regions of mantle upwelling on a variety of scales (ovoids, region made up of Ushas, Innini and Hathor Montes), upwelling and extension (Themis Regio) and localized compression (lineament belts in Lavinia Planitia).  相似文献   

Source(s) and cycling of the nonhydrolyzable organic fraction of oceanic particles     

Jeomshik Hwang  Ellen R.M. Druffel  Daniel J. Repeta 《Geochimica et cosmochimica acta》2006,70(20):5162-5168

A major fraction of particulate organic carbon (POC) in the deep ocean remains molecularly uncharacterized. In an effort to determine the chemical characteristics and source(s) of sinking POC, we studied a nonhydrolyzable fraction of sinking POC using ¹³C NMR (nuclear magnetic resonance) spectroscopy and analytical pyrolysis. ¹³C NMR spectra and products from analytical pyrolysis of the nonhydrolyzable fraction exhibit a strongly aliphatic character that is distinct from that of bulk POC. The aliphatic nature of this fraction is consistent with its low stable carbon isotope values. We hypothesize that the nonhydrolyzable fraction derives to a significant extent from a refractory component of organisms that selectively accumulates, resulting in its manifestation as a major part of POC sinking to the deep ocean and in underlying sediments.  相似文献   

Channel geometry of mountain streams in New Zealand     

Ellen E. Wohl  Andrew Wilcox 《Journal of Hydrology》2005,300(1-4):252-266

A dataset of 21 study reaches in the Porter and Kowai rivers (eastern side of the South Island), and 13 study reaches in Camp Creek and adjacent catchments (western side of the South Island) was used to examine downstream hydraulic geometry of mountain streams in New Zealand. Streams in the eastern and western regions both exhibit well-developed downstream hydraulic geometry, as indicated by strong correlations between channel top width, bankfull depth, mean velocity, and bankfull discharge. Exponents for the hydraulic geometry relations are similar to average values for rivers worldwide. Factors such as colluvial sediment input to the channels, colluvial processes along the channels, tectonic uplift, and discontinuous bedrock exposure along the channels might be expected to complicate adjustment of channel geometry to downstream increases in discharge. The presence of well-developed downstream hydraulic geometry relations despite these complicating factors is interpreted to indicate that the ratio of hydraulic driving forces to substrate resisting forces is sufficiently large to permit channel adjustment to relatively frequent discharges.  相似文献   

Modeling regional landslide susceptibility using dynamic soil moisture profiles     

Ram L. Ray  Jennifer M. Jacobs  Ellen M. Douglas 《山地科学学报》2018,15(8):1807-1824

A landslide susceptibility mapping study was performed using dynamic hillslope hydrology. The modified infinite slope stability model that directly includes vadose zone soil moisture (SM) was applied at Cleveland Corral, California, US and Krishnabhir, Dhading, Nepal. The variable infiltration capacity (VIC-3L) model simulated vadose zone soil moisture and the wetness index hydrologic model simulated groundwater (GW). The GW model predictions had a 75% NASH-Sutcliffe efficiency when compared to California’s in-situ GW measurements. The model performed best during the wet season. Using predicted GW and VIC-3L vadose zone SM, the developed landslide susceptibility maps showed very good agreement with mapped landslides at each study region. Previous quasi-dynamic model predictions of Nepal’s hazardous areas during extreme rainfall events were enhanced to improve the spatial characterization and provide the timing of hazardous conditions.  相似文献   

Sugarloaf Mountain,central Arizona,USA: A small-scale example of Miocene basalt-rhyolite magma mixing to yield andesitic magmas     

Ellen J. Craig  R.V. Fodor 《Chemie der Erde / Geochemistry》2018,78(1):116-139

Sugarloaf Mountain is a 200-m high volcanic landform in central Arizona, USA, within the transition from the southern Basin and Range to the Colorado Plateau. It is composed of Miocene alkalic basalt (47.2–49.1?wt.% SiO₂; 6.7–7.7?wt.% MgO) and overlying andesite and dacite lavas (61.4–63.9?wt.% SiO₂; 3.5–4.7?wt.% MgO). Sugarloaf Mountain therefore offers an opportunity to evaluate the origin of andesite magmas with respect to coexisting basalt. Important for evaluating Sugarloaf basalt and andesite (plus dacite) is that the andesites contain basaltic minerals olivine (cores Fo_76-86) and clinopyroxene (～Fs_9-18Wo_35-44) coexisting with Na-plagioclase (An_48-28Or_1.4–7), quartz, amphibole, and minor orthopyroxene, biotite, and sanidine. Noteworthy is that andesite mineral textures include reaction and spongy zones and embayments in and on Na-plagioclase and quartz phenocrysts, where some reacted Na-plagioclases have higher-An mantles, plus some similarly reacted and embayed olivine, clinopyroxene, and amphibole phenocrysts.Fractional crystallization of Sugarloaf basaltic magmas cannot alone yield the andesites because their ～61 to 64?wt.% SiO₂ is attended by incompatible REE and HFSE abundances lower than in the basalts (e.g., Ce 77–105 in andesites vs 114–166?ppm in basalts; Zr 149–173 vs 183–237; Nb 21–25 vs 34–42). On the other hand, andesite mineral assemblages, textures, and compositions are consistent with basaltic magmas having mixed with rhyolitic magmas, provided the rhyolite(s) had relatively low REE and HFSE abundances. Linear binary mixing calculations yield good first approximation results for producing andesitic compositions from Sugarloaf basalt compositions and a central Arizona low-REE, low-HFSE rhyolite. For example, mixing proportions 52:48 of Sugarloaf basalt and low incompatible-element rhyolite yields a hybrid composition that matches Sugarloaf andesite well ? although we do not claim to have exact endmembers, but rather, viable proxies. Additionally, the observed mineral textures are all consistent with hot basalt magma mixing into rhyolite magma. Compositional differences among the phenocrysts of Na-plagioclase, clinopyroxene, and amphibole in the andesites suggest several mixing events, and amphibole thermobarometry calculates depths corresponding to 8–16?km and 850° to 980?°C. The amphibole P-T observed for a rather tight compositional range of andesite compositions is consistent with the gathering of several different basalt-rhyolite hybrids into a homogenizing ‘collection' zone prior to eruptions. We interpret Sugarloaf Mountain to represent basalt-rhyolite mixings on a relatively small scale as part of the large scale Miocene (～20 to 15 Ma) magmatism of central Arizona. A particular qualification for this example of hybridization, however, is that the rhyolite endmember have relatively low REE and HFSE abundances.  相似文献   

A well‐established Early–Middle Pleistocene marine sequence on south‐east Zakynthos island,western Greece: Magneto‐biostratigraphic constraints and palaeoclimatic implications     

Maria D. Papanikolaou  Maria V. Triantaphyllou  Ellen S. Platzman  Philip L. Gibbard  Conall Mac Niocaill  Martin J. Head 《第四纪科学杂志》2011,26(5):523-540

The chronostratigraphy of a long, onshore Early–Middle Pleistocene marine sedimentary sequence on the south‐east part of Zakynthos island, Greece, is presented. Correlation of the succession with the isotope record of Ocean Drilling Program Site 963 reveals the combined influence of tectonics and eustacy in this area. The sequence is divided into three formations by two main unconformities that apparently relate to sea‐level lowstands associated with two major northern hemisphere glaciations, those of marine isotope stages (MIS) 22 and 12. The Zakynthos sequence in many ways is comparable with the Italian Valle di Manche section. Magnetostratigraphic and rock magnetic analyses, supported by biostratigraphy, document the position of the Matuyama/Brunhes Chron boundary (0.77 Ma), the top and base of the Jaramillo Subchron (0.99–1.07 Ma), the Cobb Mountain Subchron (1.173–1.185 Ma) and the top of the Olduvai Subchron (1.78 Ma). The underlying strata are constrained exclusively by detailed nannofossil biostratigraphy extending at least to the lowermost Pleistocene at around 2.54 Ma and therefore certainly incorporating the base of the Olduvai Subchron (1.95 Ma) and possibly the Gauss/Matuyama Chron boundary (2.58 Ma). In addition, a remarkable increase in sedimentation rate (from 3.2 and 28 cm ka^?1 to 167 cm ka^?1) and hence resolution above the Matuyama/Brunhes boundary (Middle Pleistocene) reveals one short‐lived magnetic excursion, possibly 17a (0.66 Ma), within the normal polarity Brunhes Chron. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献