Scanning electron microscopy,cathodoluminescence, and Raman spectroscopy of experimentally shock‐metamorphosed quartzite     

Arnold Gucsik  Christian Koeberl  Franz Brandsttter  Eugen Libowitzky  Wolf Uwe Reimold 《Meteoritics & planetary science》2003,38(8):1187-1197

Abstract— We studied unshocked and experimentally (at 12, 25, and 28 GPa, with 25, 100, 450, and 750°C pre‐shock temperatures) shock‐metamorphosed Hospital Hill quartzite from South Africa using cathodoluminescence (CL) images and spectroscopy and Raman spectroscopy to document systematic pressure or temperature‐related effects that could be used in shock barometry. In general, CL images of all samples show CL‐bright luminescent patchy areas and bands in otherwise nonluminescent quartz, as well as CL‐dark irregular fractures. Fluid inclusions appear dominant in CL images of the 25 GPa sample shocked at 750°C and of the 28 GPa sample shocked at 450°C. Only the optical image of our 28 GPa sample shocked at 25°C exhibits distinct planar deformation features (PDFs). Cathodoluminescence spectra of unshocked and experimentally shocked samples show broad bands in the near‐ultraviolet range and the visible light range at all shock stages, indicating the presence of defect centers on, e.g., SiO₄ groups. No systematic change in the appearance of the CL images was obvious, but the CL spectra do show changes between the shock stages. The Raman spectra are characteristic for quartz in the unshocked and 12 GPa samples. In the 25 and 28 GPa samples, broad bands indicate the presence of glassy SiO₂, while high‐pressure polymorphs are not detected. Apparently, some of the CL and Raman spectral properties can be used in shock barometry.  相似文献   

Optical anisotropy of zoned magnetites due to form birefringence     

Dr. E. Libowitzky 《Mineralogy and Petrology》1995,52(1-2):107-111

Summary Five polished samples of zoned magnetites from skarn deposits showed optical anisotropy effects under the ore microscope, though X-ray powder diffraction investigations indicated cubic magnetite. Using high magnification ore microscopy (oil immersion lenses, monochromatic light), extremely fine zones with slightly different reflectivity were observed. Scanning electron microscopy (SEM) of etched samples confirmed zones with a thickness between a few m and 100 nm. EDX analyses showed differences in the composition of these zones, ranging from almost pure magnetite to contents of CaO, MgO, A1₂O₃, SiO₂ up to 4 wt.% in total. Thus, the extremely thin, parallel zones of magnetite, with slightly different compositions and different optical constants (reflectivity, absorption, refraction), obviously lead to optical anisotropy due to form birefringence.

---

Optische anisotropie zonarer Magnetite aufgrund von formdoppelbrechung

Zusammenfassung Fünf Anschliffe von zonar gebauten Magnetiten aus Skarn-Lagerstätten zeigten unter dem Erzmikroskop optische Anisotropie-Erscheinungen, obwohl Röntgen-Pulverauf-nahmen kubischen Magnetit ergaben. Mittels hochauflösender Erzmikroskopie (Öl-Immersion, monochromatisches Licht) wurden extrem feine Zonierungen mit etwas unterschiedlichem Reflexionsvermögen beobachtet. Rasterelektronenmikroskopie (SEM) von angeätzten Proben bestätigte eine Zonendicke zwischen einigen Yin und 100 nm. EDX Analysen zeigten Unterschiede in der Zusammensetzung dieser Zonen, die von fast reinem Magnetit bis zu CaO-, MgO-, A1₂O_3-, SiO₂-Gehalten von insgesamt 4 Gew.% reichen. Offensichtlich fiihren die extrem diinnen, parallelen Zonierungen mit unterschiedlicher Zusammensetzung, und folglich unterschiedlichen optischen Konstanten (Reflexion, Absorption, Lichtbrechung) zu optischer Anisotropie durch Formdoppelbrechung.

  相似文献   

“Dreieck”, a simple BASIC-program for plotting triangular concentration diagrams on IBM (XT/AT)-compatible personal computer systems     

Mag. Dr. E. Libowitzky 《Mineralogy and Petrology》1990,41(2-4):257-258

  相似文献   

Sulfide and platinum mineralization in the Merensky Reef: evidence from hydrous silicates and fluid inclusions   总被引：5，自引：1，他引：5  

Christian G. Ballhaus  Eugen F. Stumpfl 《Contributions to Mineralogy and Petrology》1986,94(2):193-204

The base metal sulfides of the Merensky Reef are associated with hydrous silicates and intense deuteric hydrous alteration of cumulus and postcumulus silicates. Biotite and phlogopite crystallized in the vicinity of sulfides from a volatile-enriched highly fractionated intercumulus melt. Amphibole, chlorite, and talc are later alteration phases of cumulus pyroxene and intercumulus plagioclase. Biotite is often accompanied by zircon, rutile, and quartz. Accessory quartz hosts a complex suite of H₂O-NaCl-(CaCl₂)-CO₂-CH₄ fluid inclusions which have thus far not been described from the Merensky Reef. The earliest fluid inclusion compositions are NaCl-(H₂O) with less than 10 vol.% water; CO₂ coexisting with a halite daughter crystal and brine; and polyphase inclusions with up to six daughter and accidental phases and high contents of divalent cations. The maximum trapping temperature is around 730° C at 4 to 5 kb pressure. Later inclusion generations are H₂O-NaCl, CO₂-H₂O, and pure CO₂ and CH₄. The presence of Cl-rich fluids during the intercumulus stage of the crystallizing Merensky Reef is directly related to the mode of sulfide precipitation. Prior to sulfide unmixing in a hydrous magma sulfur is likely to be present as H₂S. Sulfur saturation causes reaction of H₂S with oxides of the silicate melt to form a sulfide melt plus water. During reaction the magma is enriched in water until a separate fluid unmixes. It carries all compounds with high fluid/melt partition coefficients, as well as metals capable of forming OH- and Cl-complexes. Precious metals are assumed to have fractionated into the Cl-rich fluid as Cl-complexes rather than being dissolved in the sulfide melt. During the cooling evolution of the fluid the precious elements precipitate around the periphery of sulfide melt droplets. The model proposed explains the distribution pattern of platinum-group minerals in the Merensky Reef better than any orthomagmatic mineralization concept offered so far.  相似文献   

Anmerkungen zu „Geochemische Untersuchungen an Sedimenten des Persischen Golfs“     

Martin Hartmann  Heinz Lange  Eugen Seibold 《Contributions to Mineralogy and Petrology》1971,31(2):159-163

Ohne Zusammenfassung  相似文献   

Biologische Untersuchung der Limmat zwischen Zürichsee und Wettingen, 1974 bis 1980     

Prof.Dr. Eugen A. Thomas  Dr. Ferdinand Schanz 《Aquatic Sciences - Research Across Boundaries》1981,43(2):296-339

Biological investigations of that part of the River Limmat lying between Quaibrücke and Wettingen were carried out from 1974 to 1980. An influence of the waste water from the Werdhölzli sewage treatment plant on the plant and animal communities of the river bed was evident. This influence was especially plain to be seen immediately below the point of introduction of the waste water. The incidence of pollution indicators decreased downriver from this point. Biotests, using periphyton from stones taken from the shore of the Zürichsee, yielded harvests which were clearly higher in Limmat water taken from points downstream from the sewage works than in water taken from points upstream.  相似文献   

Tektonik und Dimensionalanalyse     

Eugen Wegmann 《International Journal of Earth Sciences》1948,36(1):83-84

Ohne Zusammenfassung  相似文献   

Die Altersfolge der primär ausgeschiedenen sulfidischen Mineralien in den oberschlesischen Zink- und Bleierzlagerstätten und die Bedeutung der Altersfolge der primär ausgeschiedenen Mineralien der Erzlagerstätten überhaupt     

Bergrat Dr. phil. Eugen Schulz 《International Journal of Earth Sciences》1913,4(2):126-136

Ohne Zusammenfassung  相似文献   

On the breakdown of zircon upon “dry” thermal annealing     

Tamás Váczi  Lutz Nasdala  Richard Wirth  Mathias Mehofer  Eugen Libowitzky  Tobias Häger 《Mineralogy and Petrology》2009,97(1-2):129-138

Zircon samples without and with secondary chemical alteration from diverse sources were subjected to heat treatment at 1400 °C for 96 h. Resulting new phases and textures suggest that decomposition of zircon into component oxides occurred in all experiments to various degrees. The crucible material was found to have a strong influence on the extent of breakdown, especially in the case of altered starting materials. In this study the progressive stages of the breakdown of zircon grains are described. The factors that may govern the decomposition are discussed, including radiation damage, secondary alteration and external reaction conditions (sample container, atmosphere). Alumina crucibles should generally be avoided in dry annealing of zircon, to minimise uncontrolled breakdown into oxides.  相似文献   

Short-term Tests of Potassium dIdD Vector Magnetometer     

Eugen Vujić 《Acta Geophysica》2015,63(5):1276-1295

  相似文献