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Evert Lagrou 《GeoJournal》2000,51(1-2):99-112
The paper describes the different capital city functions that are accomodated in Brussels. There are in fact five different capitals in Brussels in search of a place. Their locations are conditioned by Brussels' eventful history. The analysis subsequently focuses on the rather negative relation between the local public intellectuals and the city's European capital functions. The location of the European headquarters within the existing urban fabric – unlike Luxemburg and Strasbourg – has caused residential expulsion and further confrontations with the local community during all expansions.Brussels has the most politically decisive institutions. The competition with Luxemburg and Strasbourg has in the past given rise to dubious building processes and hidden agendas regarding the further construction of the necessary space for Europe.Unlike most other capitals Brussels has a low degree of esteem from its citizens. The After-May 68- Movement reacting initially against the CIAM-realisations during the 1970s, continues its activities up until today against two highly symbolic projects: the North Station area called the Manhattan Quarter and the European Headquarters. The movement launched the term Brusselization on the international forum and continues to promote the negative image of its city – notwithstanding the complete change of the official urban planning.The article is a plea for the integration of the actual one-sided advocacy planning within a more comprehensive urban planning approach where strong and soft functions are more in balance. This can also improve the quality of the new European campus now under consideration to accomodate the entry of the East European states in the Union.  相似文献   
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We present MUSE, a software framework for combining existing computational tools for different astrophysical domains into a single multiphysics, multiscale application. MUSE facilitates the coupling of existing codes written in different languages by providing inter-language tools and by specifying an interface between each module and the framework that represents a balance between generality and computational efficiency. This approach allows scientists to use combinations of codes to solve highly coupled problems without the need to write new codes for other domains or significantly alter their existing codes. MUSE currently incorporates the domains of stellar dynamics, stellar evolution and stellar hydrodynamics for studying generalized stellar systems. We have now reached a “Noah’s Ark” milestone, with (at least) two available numerical solvers for each domain. MUSE can treat multiscale and multiphysics systems in which the time- and size-scales are well separated, like simulating the evolution of planetary systems, small stellar associations, dense stellar clusters, galaxies and galactic nuclei. In this paper we describe three examples calculated using MUSE: the merger of two galaxies, the merger of two evolving stars, and a hybrid N-body simulation. In addition, we demonstrate an implementation of MUSE on a distributed computer which may also include special-purpose hardware, such as GRAPEs or GPUs, to accelerate computations. The current MUSE code base is publicly available as open source at http://muse.li.  相似文献   
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We use numerically modelled data sets to investigate the sensitivity of electromagnetic interferometry by multidimensional deconvolution to spatial receiver sampling. Interferometry by multidimensional deconvolution retrieves the reflection response below the receivers after decomposition of the fields into upward and downward decaying fields and deconvolving the upward decaying field by the downward decaying field. Thereby the medium above the receiver level is replaced with a homogeneous half‐space, the sources are redatumed to the receiver level and the direct field is removed. Consequently, in a marine setting the retrieved reflection response is independent of any effect of the water layer and the air above. A drawback of interferometry by multidimensional deconvolution is a possibly unstable matrix inversion, which is necessary to retrieve the reflection response. Additionally, in order to correctly separate the upward and the downward decaying fields, the electromagnetic fields need to be sampled properly. We show that the largest possible receiver spacing depends on two parameters: the vertical distance between the source and the receivers and the length of the source. The receiver spacing should not exceed the larger of these two parameters. Besides these two parameters, the presence of inhomogeneities close to the receivers may also require a dense receiver sampling. We show that by using the synthetic aperture concept, an elongated source can be created from conventionally acquired data in order to overcome these strict sampling criteria. Finally, we show that interferometry may work under real‐world conditions with random noise and receiver orientation and positioning errors.  相似文献   
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The complexity of most geological and geophysical problems prompts sometimes the use of non linear mathematical methods to handle them. An adaptive neuro fuzzy inference system (ANFIS) that combines fuzzy logic with neural networks, is applied here to study a paleoclimate section from the Quaternary sedimentary fill of the Lake Mucubají (western Venezuela). The purpose of this work is to find a set of numerical relationships that could predict the possible connections between oxygen isotope (δ18O) values from two different locations in the northern hemisphere (Ammersee in southern Germany and an ice core from the Greenland Ice Core Project — GRIP) and rock-magnetic parameters measured in Mucubají samples (i.e. mass-specific magnetic susceptibility — χ, magnetic remanence S-ratio, mass-specific saturation isothermal remanent magnetization — SIRM and anhysteretic remanent magnetization — ARM). The best inferences in terms of coefficient of determionation R2 and the Root Mean-Square Error (RMSE) are obtained using those magnetic data as input that include information about magnetite grain size distributions, e.g., SIRM and ARM in FIS structures [1χ, 4ARM] and [4ARM, 1SIRM]. A comparison between Ammersee and GRIP actual data, as well as their corresponding inferences for the FIS structure [4ARM, 1SIRM], reveals a reasonable good inference of global trends for both records, overlooking the regional and/or local paleoclimate forcings that might have affected Ammersee. A better correlation between global isotope paleoclimate records and magnetic proxies, is perhaps prevented by the role played by local and regional paleoclimate and tectonism in Mucubají. We also argue that the ratio of ARM over SIRM appears to be related in a complex way to the onset and to the end of the Younger Dryas. Our novel approach to the assessment of a specific paleoclimate case study shows the potential of the ANFIS technique in solving problems where traditional univariate and multivariate linear regression methods could prove inadequate.  相似文献   
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The acid chemistry of confined waters in smectite interlayers have been investigated with first principles molecular dynamics (FPMD) simulations. Aiming at a systematic picture, we establish the model systems to take account of the three possible controlling factors: layer charge densities (0 e, 0.5 e and 1.0 e per cell), layer charge locations (tetrahedral and octahedral) and interlayer counterions (Na+ and Mg2+). For all models, the interlayer structures are characterized in detail. Na+ and Mg2+ show significantly different hydration characteristics: Mg2+ forms a rigid octahedral hydration shell and resides around the midplane, whereas Na+ binds to a basal oxygen atom and forms a very flexible hydration shell, which consists of five waters on average and shows very fast water exchanges. The method of constraint is employed to enforce the water dissociation reactions and the thermodynamic integration approach is used to derive the free-energy values and the acidity constants. Based on the simulations, the following points have been gained. (1) The layer charge is found to be the direct origin of water acidity enhancement in smectites because the neutral pore almost does not have influences on water dissociations but all charged pores do. (2) With a moderate charge density of 0.5 e per cell, the interlayer water shows a pKa value around 11.5. While increasing layer charge density to 1.0 e, no obvious difference is found for the free water molecules. Since 1.0 e is at the upper limit of smectites’ layer charge, it is proposed that the calculated acidity of free water in octahedrally substituted Mg2+-smectite, 11.3, can be taken as the lower limit of acidities of free waters. (3) In octahedrally and tetrahedrally substituted models, the bound waters of Mg2+ show very low pKa values: 10.1 vs 10.4. This evidences that smectites can also promote the dissociations of the coordinated waters of metal cations. The comparison between the two Mg2+-smectites reveals that different layer charge locations do not lead to obvious differences for bound and free water acidities.  相似文献   
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Pb(II) sorption experiments with calcite powders were conducted in suspensions equilibrated at atmospheric PCO2(g) and ambient temperature at pH 7.3, 8.2 and 9.4. Pb fractional sorption was low at pH 7.3 and 9.4 relative to pH 8.2, and correlated well with PbCO30(aq) speciation. Desorption experiments conducted for initial sorption times ranging from 0.5 h to 12 d reveal an almost completely reversible process at pH 8.2, attributed to the dominance of an adsorption mechanism, with slight and pronounced irreversibility at pH 7.3 and 9.4 respectively. Similarities in X-ray absorption near edge spectra (XANES) for 24 h and 12 d pH 7.3 and 9.4 sorption samples indicate no effect of initial sorption time. Results from linear combination (LC) fits of XANES spectra for samples sorbed at pH 9.4 confirm ∼75% adsorbed and ∼25% coprecipitated components. The coprecipitated fraction was attributed to the non-exchangeable metal observed in desorption experiments. At pH 7.3, ∼95% adsorbed and ∼5% coprecipitated components were obtained. A comparison of results from desorption experiments and LC-XANES alludes to an irreversibly bound adsorbed component for the pH 9.4 12 d sorption sample. Extended X-ray absorption fine structure spectroscopy (EXAFS) analysis of pH 7.3 and 9.4 12 d sorption samples confirms the presence of both adsorbed and coprecipitated metal. At pH 7.3 a first-shell Pb-O bond length of 2.38 Å is intermediate between that of adsorbed (2.34 Å) and coprecipitated (2.51 Å) Pb. At pH 9.4, two first-shell Pb-O distances at 2.35 Å and 2.51 Å were obtained, indicative of the occurrence of both adsorption and coprecipitation and a larger coprecipitated fraction relative to that at pH 7.3, consistent with LC-XANES results. We propose that the disparity in the fraction of coprecipitated metal with pH may be linked to the ability of sorbed Pb to inhibit near-surface dynamic exchange of Ca and CO3 species, which dictates step advance and retreat. Less effective inhibition of step motion at pH 9.4, due to lower fractional sorption, combined with highest rates of dynamic exchange results in a significant fraction of coprecipitated Pb at this pH. At low pH, though fractional sorption is also low, lower rates of exchange prohibit significant coprecipitation. At pH 8.2, effective inhibition of surface processes due to higher fractional sorption and lower rates of exchange compared to pH 7.3 and 9.4 preclude detectable coprecipitation. Other factors such as changes in surface speciation and solubility of the Pb-Ca solid solution with pH may also come into play. Overall, this study presents evidence for the influence of pH on Pb sorption mechanisms, and addresses the efficiency of Pb immobilization in calcitic systems.  相似文献   
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