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We calculate the expected mid-infrared (MIR) molecular hydrogen line emission from the first objects in the Universe. As a result of their low masses, the stellar feedback from massive stars is able to blow away their gas content and collect it into a cooling shell where H2 rapidly forms and IR roto-vibrational (as for example the rest-frame 2.12 μm) lines carry away a large fraction (up to 10 per cent) of the explosion energy. The fluxes from these sources are in the range 10−21–10−17 erg s−1 cm−2 . The highest number counts are expected in the 20-μm band, where about 105 sources deg−2 are predicted at the limiting flux of 3×10−18 erg s−1 cm−2. Among the planned observational facilities, we find that the best detection perspectives are offered by the Next Generation Space Telescope ( NGST ), which should be able to reveal about 200 first objects in one hour observation time at its limiting flux in the above band. Therefore, mid-IR instruments appear to represent perfect tools to trace star formation and stellar feedback in the high ( z ≳5) redshift Universe.  相似文献   
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The Proterozoic basement of the Province of Zambezia (Mozambique) is located near the southern end of the so called Mozambique Belt. Rb-Sr data derived from the analyses of 66 whole rocks and a few mineral samples bear witness of a magmatic and metamorphic episode referable to the Kibaran (ca. 1000 Ma) and helped to model the late-Proterozoic evolution as follows. At 1100–1050 Ma a pre-orogenic, calc-alkaline magmatism was responsible for the emplacement of now deformed granite and granodiorite. This phase was accompanied by rhyolitic volcanism. A subsequent peak of deformation and metamorphism occurred at 1000-950 Ma and was associated with a second generation of substantially post-tectonic granites. A thermal event resulting in the emplacement of a final generation of granites and pegmatites can be dated to around 500-450 Ma.The metamorphic basement has not preserved its protolith age, probably as a result of extensive isotopic homogeneization of Sr in Kibaran times. Its maximum time of differentiation from the mantle should be around 1600 Ma.The very low values of initial Sr isotopic ratios suggest the absence of Archean crustal precursors and support the rather young, yet pre-Pan-African evolution of the southernmost Mozambique Belt.
Zusammenfassung Das proterozoische Grundgebirge der Provinz Zambesi (Mosambique) befindet sich in der Nähe des südlichen Endes des sogenannten Mozambique Belt. Rb/Sr Daten aus 66 Ganzgesteins- und einigen Mineralanalysen zeugen von einer magmatischen und metamorphen Episode die sich dem Kibaran (ca. 1000 Ma) zuordnen läßt, und wie sich im folgenden zeigt, hilfreich bei der Modellisierung der spätproterozoischen Entwicklung ist. Um 1100 bis 1050 Ma erfolgte ein präorogener kalkalkalischer Magmatismus, bestehend aus Graniten und Granodioriten, die heute deformiert vorliegen. Diese Phase wurde von rhyolithischem Vulkanismus begleitet. Von 1000 bis 950 Ma folgte der Höhepunkt der Deformation und Metamorphose, begleitet von einer bedeutenden 2. Generation posttektonischer Granite. Bedingt durch ein weiteres thermales Ereignis intrudierte die letzte Granit- und Pegmatitgeneration vor 500 bis 450 Ma.Im metamorphen Grundgebirge ist das Eduktalter vermutlich aufgrund der starken isotopischen Homogenisierung von Sr während der Kibara-Zeit nicht erhalten. Seine maximale Differentiationszeit vom Mantel muß vor 1600 Ma gewesen sein.Die sehr niedrigen Gehalte der initialen Sr-Isotopenverhältnisse lassen die Abwesenheit von archaischen Krustenvorläufern vermuten, und unterstützen die sehr junge, bis jetzt Prä-Pan-Afrikanische Entwicklung des südlichsten Mozambique Belts.

Résumé Le socle protérozoïque de la province du Zambèze, au Mozambique, se trouve à proximité de l'extrémité sud du «Mozambique Belt». Des mesures Rb/Sr effectuées sur 66 roches totales et sur quelques minéraux témoignent d'un épisode magmatique et métamorphique attribuable au Kibarien (environ 1.000 Ma), ce qui permet de se représenter comme suit l'histoire de cette région au Protérozoïque supérieur. Il y a 1.100 à 1.050 Ma, la région a connu une phase de magmatisme calco-alcalin qui s'est traduite par la mise en place de granites et granodiorites, aujord'hui déformés. Cette phase s'est accompagnée d'un volcanisme rhyolitique. Elle a été suivie, entre 1.000 et 950 Ma, d'une activité tectono-métamorphique majeure, à laquelle est associée une deuxième et importante génération de granites, post-tectoniques. Ultérieurement, la région a connu encore un épisode thermique, daté à 500-450 Ma, responsable de la mise en place d'une dernière génération de granite et de pegmatite.Le socle métamorphique n'a pas gardé de témoins de l'âge de son protolithe, en raison probablement de la forte homogénisation isotopique du Sr à l'époque kibarienne. Lâge maximal de sa différenciation à partir du manteau doit se situer autour de 1.600 Ma.La valeur très basse des rapports isotopiques initiaux du Sr suggère l'absence de précurseurs crustaux archéens et incite à admettre une évolution relativement jeune — bien que pré-panafricaine — du «Mozambique Belt» méridional.

() .. . , Rb/Sr 66 , , Kibara, 1000 , , , . 1100 1050 - - , , . . 1000 950 , - . , 500 450 . , , , Kibara. , , 1600 my . - .
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This paper is focused on the role of boron coordination in determining the 11B/10B isotopic fractionation between melt/glass and biotite at magmatic temperatures. For this purpose, three evolved volcanic rocks from Roccastrada, Mt. Amiata, and Mt. Cimini belonging to the Neogene-Quaternary magmatism of central Italy were studied. In these samples, the measured boron biotite-glass partition coefficient ranges between 0.004 and 0.011, indicating that boron behaves as an incompatible element during biotite crystallization. The 11B magic-angle spinning nuclear magnetic resonance (NMR) spectra reveal the presence of trigonal BO3/2 units, tetrahedral BO4/2 sites, and three-coordinated BO2/2O species containing one nonbridging oxygen. The relative contributions of these different boron sites were estimated by spectral deconvolution, and it was observed that the fraction of trigonally coordinated boron decreases with increasing K2O concentration in the glass. The 11B/10B isotopic fractionation between biotite and melt/glass was observed to be large even at magmatic temperatures and was found to be 1.0066 (Roccastrada sample), 1.00535 (Mt. Amiata sample), and 1.00279 (Mt. Cimini sample). Fractionation is mostly related to the relative amount of trigonal and tetrahedral boron sites in the glass network rather than to other processes, including the speciation of hydrous species in the glass structure. The measured α values are significantly higher than the calculated ones obtained using the reduced partition function ratios (RPFRs) for B(OH)3 and B(OH)4 as reported by Kakihana et al. (1977) and the abundance of trigonal and tetrahedral boron obtained by 11B NMR spectra. Furthermore, a nonlinear relationship is observed between the percentage of BO4 in the glass structure and the measured 1000lnα, suggesting that the approximation of monomeric B(OH)3 and B(OH)4 species contributions through ideal mixing in calculating the RPFRs in polyanions (Oi et al., 1989) probably does not apply to silicate glasses.The large B isotopic fractionation measured between glass and biotite and its dependence on the boron coordination in the glass are a limitation to the use of δ11B in the mineral to characterize magmas. Nonetheless, the high incompatible behavior of boron in the most common magmatic minerals rules out that fractional crystallization significantly modified the B isotopic composition of the melt.  相似文献   
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Landslide hazard in the Nebrodi Mountains (Northeastern Sicily)   总被引:1,自引:1,他引:1  
The eastern sector of the Nebrodi Mountains (NE Sicily), a part of the Apenninic-Maghrebian orogenic chain, is characterized by an high landslide hazard. The village of S. Domenica Vittoria, which lies in the area, has been particularly affected by various landslide phenomena, with resulting damage to buildings and infrastructure.The rocks outcropping in the area belong to the Cretaceous Monte Soro Flysch; they consist of an alternation of argillaceous and calcareous beds at the base and argillaceous and quartzarenitic beds at the top. The lithotechnical characteristics of the formation and the steepness of the slopes in the area lead to an elevated instability, as testified by the widespread occurrence of sub-vertical arcuate cliffs (landslide scarps) and sub-horizontal areas (landslide terraces), typical of a landslide-controlled morphology. From a kinematics point of view, the observed phenomena can be referred to multiple rotational slides, flows, and complex landslides, often with a retrogressive development and enlargement. Triggering causes lie principally in the intense rainfalls that determine the decay of the geomechanical properties of the terrain and supply discontinuos groundwater circulation that is evident in seasonal springs. Human activity, such as the construction of roads and buildings on steep slopes and dispersal of water from supply systems and sewers has a significant impact as well.Due to the instability of the area, expansion of the village, which is already limited by the morphological conditions, is made difficult by the high hazard level, especially in the areas at higher elevations, where the principal landslide scarps are located, and even more on the rims of the scarps. Considering the high hazard level, S. Domenica Vittoria has been inserted by the National Geological Service among the sites in Sicily to be monitored by means of a GPS network. The survey carried out along the entire slope hosting the village has furnished the base for geological and geomorphological knowledge needed for the planning of the network, to identify the areas at landslide risk, where parts of the village lie, including the areas of expansion of the village, the main roads, and a portion of the Favoscuro river bed.  相似文献   
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During the lower and middle Miocene the western Anatolia and the eastern Aegean Sea were dominated by a calcalkaline volcanism associated with minor acid and basic volcanics. The basic subcrustal volcanics consist mainly of alkali basalts and hawaiites (9.7–11.9 m.y.), nepheline hawaiites and nepheline trachyandesites (Kula area from 1.1 m.y. to the recent times). The rhyolitic volcanics (12.5 m.y.) derived by a partial melting process in the upper crust (87Sr/86Sr=0.7121). The calcalkaline suite (16.2–21.5 m.y., mean value87Sr/86Sr=0.708) shows a trend from latite-andesites to dacites and rhyodacites; a latite andesite system related to a sinking slab of lithosphere and constituted by a mixing of oceanic crust (tholeiite), oceanic sediments and/or tectonic fragments of sialic crust is envisaged.  相似文献   
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New Rb/Sr and K/Ar data on minerals and whole-rocks from the metamorphic basement of Northeastern Sardinia are presented. A formation of augen gneiss of volcano-sedimentary origin yields a Rb/Sr whole-rock age of 441±33 m.y.; a Rb/Sr isochron age of 306±10 m.y. is found for the minerals separated from one of these samples. K/Ar measurements on micas also yield ages of 319–284 m.y. A banded migmatite which originated through a process of metamorphic differentiation was analysed by the Rb/Sr method. Six bands, treated as whole-rock samples, fit an isochron of 344±7 m.y. Biotite and plagioclase from one of these bands yield an isochron age of about 300 m.y.The radiometric results reported in this paper and all those previously published are discussed in order to investigate the tectono-metamorphic history of this important segment of the ancient Mediterranean basement. It is argued that in this area there is only indirect evidence of a Caledonian orogenic event (late orogenetic acidic magmatites emplaced 458-441 m.y. ago) while the main features of the metamorphic basement must be related to the Hercynian orogeny the climax of which can be fixed at about 340 m.y. The concordance of the ages of the separated minerals (310-300 m.y.) suggests that the metamorphic succession stayed above the specific critical temperatures for about 40 m.y., after which it was suddenly uplifted contemporaneous with the emplacement of the, essentially post-kinematic, Hercynian granitoids.  相似文献   
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