Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

QUEST on DASI: a South Pole CMB polarization experiment     

Sarah Church  Peter Ade  James Bock  Melanie Bowden  John Carlstrom  Ken Ganga  Walter Gear  James Hinderks  Wayne Hu  Brian Keating  John Kovac  Andrew Lange  Eric Leitch  Olivier Mallie  Simon Melhuish  Anthony Murphy  Ben Rusholme  Creidhe O&#x;Sullivan  Lucio Piccirillo  Clem Pryke  Andy Taylor  Keith Thompson 《New Astronomy Reviews》2003,47(11-12):1083

QUEST on DASI is a ground-based, high-sensitivity, high-resolution (ℓ_max2500) experiment designed to map CMB polarization at 100 and 150 GHz and to measure the power spectra from E-modes, B-modes from lensing of the CMB, and B-modes from primordial gravitational waves. The experiment comprises a 2.6 m Cassegrain optical system, equipped with an array of 62 polarization-sensitive bolometers (PSBs), located at the South Pole. The instrument is designed to minimize systematic effects; features include differencing of pairs of orthogonal PSBs within a single feed, a rotatable achromatic waveplate, and axisymmetric rotatable optics. In addition the South Pole location allows both repeatable and highly controlled observations. QUEST on DASI will commence operation in early 2005.  相似文献   

A search for high-redshift molecular absorption lines towards millimetre-loud, optically faint quasars     

M. T. Murphy  S. J. Curran  J. K. Webb 《Monthly notices of the Royal Astronomical Society》2003,342(3):830-836

We describe initial results of a search for redshifted molecular absorption towards four millimetre-loud, optically faint quasars. A wide frequency bandwidth of up to 23 GHz per quasar was scanned using the Swedish–ESO Submillimetre Telescope at La Silla. Using a search list of commonly detected molecules, we obtained nearly complete redshift coverage up to   z _abs= 5  . The sensitivity of our data is adequate to have revealed absorption systems with characteristics similar to those seen in the four known redshifted millimetre-band absorption systems, but none were found. Our frequency-scan technique nevertheless demonstrates the value of wide-band correlator instruments for searches such as these. We suggest that a somewhat larger sample of similar observations should lead to the discovery of new millimetre-band absorption systems.  相似文献   

Enhancing understanding of breakdown and collapse in the Yorkshire Dales using ground penetrating radar on cave sediments     

P. Murphy  A.R. Westerman  R. Clark  A. Booth  A. Parr 《Engineering Geology》2008,99(3-4):160

Historical evidence shows block breakdown and collapse are actively occurring in large fault aligned caverns in the Yorkshire Dales karst. Deployment of ground penetrating radar at two such sites has provided detailed images of the sedimentary sequences below the present day cavern floor but no large blocks are imaged within the sediments. Solutional processes must be removing limestone from the sediment to allow continued cavern growth. Possible mechanisms to account for the lack of large blocks within the sediment fill are discussed.  相似文献   

The distributions of particulate atmospheric trace metals and mineral aerosols over the Indian Ocean     

R. Chester  A. S. Berry  K. J. T. Murphy 《Marine Chemistry》1991,34(3-4)

Data are presented for the concentrations of Al, Fe, Mn, Ni, Co, Cr, V, Cu, Zn, Pb and Cd in aerosols collected over two contrasting regions of the Indian Ocean. These are: (1) the northern Arabian Sea (AS), from which samples were collected in the northeast monsoon, during which the region receives an input of crustal material from the surrounding arid land masses; and (2) the Tropical Southern Indian Ocean (TSIO), a remote region from which samples were collected from air masses for which there were no large-scale up-wind continental aerosol sources. The TSIO samples can be divided into two populations: Population I aerosols, collected from air masses which have probably impinged on Madagascar, and Population II aerosols, which have been confined to open-ocean regions to the south of the area.The data indicate that there are strong latitudinal variations in the chemical signatures of aerosols over the Indian Ocean. The input of crustal material to the Arabian Sea gives rise to an average Al concentration of about 1000 ng m⁻³ of air in the northeast monsoon regime. As a result, the concentrations of all trace metals are relatively high, and the values of crustal enrichment factors are less than 10 for most metals, in the AS aerosols. In contrast, TSIO Population II ‘open-ocean southern air’ sampled during the southwest monsoon season, has an average Al concentration of only about 10 ng m⁻³ of air. Trace metal concentrations in the TSIO ‘open-ocean southern air’ during the southwest monsoon season are representative of ‘clean’ remote marine air and are generally similar to those reported over the central North Pacific.Mineral dust concentrations over the Indian Ocean decrease in a north to south direction, from about 15–20 μg m⁻³ of air in the extreme north to about 0.01–0.25 μg m⁻³ of air in the far south. The deposition of mineral dust over the northern Arabian Sea can account for approximately 75% of the non-carbonate material incorporated into the underlying sediments.In the Arabian Sea the dissolved atmospheric inputs of all the trace metals, with the exception of Cu and Co, exceed those from fluvial run-off by factors which range from 9.6 for Pb to 1.6 for Cr.  相似文献   

Material properties of North Atlantic cod eggs and early-stage larvae and their influence on acoustic scattering   总被引：1，自引：2，他引：1  

Chu  Dezhang; Wiebe  Peter H.; Copley  Nancy J.; Lawson  Gareth L.; Puvanendran  Velmurugu 《ICES Journal of Marine Science》2003,60(3):508-515

  相似文献   

The Southern Antarctic Circumpolar Current Front: physical and biological coupling at South Georgia     

Peter Ward  Mick Whitehouse  Mike Meredith  Eugene Murphy  Rachael Shreeve  Rebecca Korb  Jon Watkins  Sally Thorpe  Rachel Woodd-Walker  Andrew Brierley  Nathan Cunningham  Sharon Grant  Doug Bone 《Deep Sea Research Part I: Oceanographic Research Papers》2002,49(12):139

The coupling of physics and biology was examined along a 160 km long transect running out from the north coast of South Georgia Island and crossing the Southern Antarctic Circumpolar Current Front (SACCF) during late December 2000. Surface and near surface potential TS properties indicated the presence of three water types: a near-shore group of stations characterised by water which became progressively warmer and fresher closer to South Georgia, an offshore grouping in which sea surface temperatures and those at the winter water level were relatively warm (1.8°C and 0.5°C, respectively), and a third in which surface and winter water temperatures were cooler and reflected the presence of the SACCF. The transect bisected the SACCF twice, revealing that it was flowing in opposite directions, north-westward closest to South Georgia and south-eastwards at its furthest point from the island. The innermost limb was a narrow intense feature located just off the shelf break in 2000–3500 m of water and in which rapid surface baroclinic velocities (up to 35 cm s⁻¹) were encountered. Offshore in the outermost limb, shown subsequently to be a mesoscale eddy that had meandered south from the retroflected limb of the SACCF, flow was broader and slower with peak velocities around 20 cm s⁻¹. Chlorophyll a biomass was generally low (<1 mg m⁻³) over much of the transect but increased dramatically in the region of the innermost limb of the SACCF, where a deepening of the surface mixed layer was coincident with a subsurface chlorophyll maximum (7.4 mg m⁻³) and elevated concentrations down to 100 m. The bloom was coincident with depleted nutrient concentrations, particularly silicate, nitrate and phosphate, and although ammonium concentrations were locally depleted the bloom lay within an elevated band (up to 1.5 mmol m⁻³) associated with the frontal jet. Increased zooplankton abundance, higher copepod body carbon mass and egg production rates all showed a strong spatial integrity with the front. The population structure of the copepods Calanoides acutus and Rhincalanus gigas at stations within the front suggested that rather than simply resulting from entrainment and concentration within the jet, increased copepod abundance was the result of development in situ. Estimates of bloom duration, based on silicate and carbon budget calculations, set the likely duration between 82 and 122 d, a figure supported by the development schedule of the two copepod species. Given this timescale, model outputs from FRAM and OCCAM indicated that particles that occurred on the north side of South Georgia in December would have been in the central-southern Scotia Sea 2–3 months earlier, probably in sea ice affected regions.  相似文献   

Contributions to atmospheric methane by natural seepages on the U.K. continental shelf [Mar. Geol. 137 (1997) 165–189]     

Alan Judd  Gareth Davies  Jason Wilson  Richard Holmes  Gordon Baron  Ian Bryden 《Marine Geology》1997,140(3-4):427-455

Natural gas seepages occur on the United Kingdom's continental shelf and although published reports suggest that they are very rare, the petroleum industry has identified, but not publicly reported, many more. There is also very little data on the flux of gas from seabed seepages, and even less on the contribution of seepages to atmospheric concentrations of gases such as methane.

Potential gas source rocks include Quaternary and Tertiary peats as well as petroliferous source rocks such as the Carboniferous Coal Measures and the Upper Jurassic Kimmeridge Clays. There are also other organic-rich sediments which are potential source rocks. Together these cover a considerable part of the U.K. continental shelf.

Analogue seismic reflection (pinger) profiles acquired during the British Geological Survey's regional mapping programme have been reviewed to identify water column targets including fish and plumes of gas bubbles. The ability to distinguish targets is critical to an assessment of the distribution of gas seepages. Both theoretical predictions of target identity and the habits of shoaling fish have been investigated in order to identify a method of distinction.

Data from seabed seepages and measurements of seepage rates have been used to establish likely ranges of gas flux rates and the sizes of gas bubbles. The likelihood that a rising bubble will survive and escape into the atmosphere is determined primarily by bubble size and water depth; methane, the principal constituent of seepage gas, is relatively unreactive and sparingly soluble.

The studies have enabled a new estimate of the distribution of gas seepages on the U.K. continental shelf, and of the contribution to atmospheric methane levels. The results suggest that natural gas seepages are significantly more important as a source of methane than had hitherto been established. It is estimated that between 120,000 and 3.5 mtonnes of methane per year come from a continental shelf area of about 600,000 km². This represents between 2% and 40% of the total United Kingdom methane emission. It is suggested that similar contributions arise from other continental shelf areas worldwide, and that geological sources of atmospheric methane are more significant than is generally acknowledged.  相似文献   

Two Offner-based IR camera optical designs     

D. C. Murphy 《Experimental Astronomy》1994,3(1-4):141-142

Tracing results for two designs based on the Offner reimager are given: a practical 256×256 NICMOS-3 IR/CCD I-K camera designed for use on a f/13.5 1-m telescope yielding a 154×154 field, and a hypothetical 1024×1024 pixel nextgeneration IR camera for a f/7.5 2.5-m telescope yielding a 244×244 field. Both designs produce near-diffration limited results.  相似文献   

Relative flow of H⁺ and O⁺ ions in the topside ionosphere at mid-latitudes     

G.I. Bailey  R.J. Moffett  J.A. Murphy 《Planetary and Space Science》1977,25(10):967-972

Theoretical results on the daily variation of O⁺ and H⁺ field-aligned velocities in the topside ionosphere are presented. The results are for an L = 3 magnetic field tube under sunspot minimum conditions at equinox. They come from calculations of time-dependent O⁺ and H⁺ continuity and momentum balance in a magnetic field tube which extends from the lower F2 region to the equatorial plane (Murphy et al., 1976).There are occasions when ion counterstreaming occurs, with the O⁺ velocity upward and H⁺ velocity downward. The conditions causing this counterstreaming are described: the H⁺ layer is descending whilst O⁺ is supplied from below either to increase the O⁺ concentration at fixed heights or to replace O⁺ ions lost by charge exchange with neutral H. It is suggested that the results of observations at Arecibo by Vickrey et al. (1976) of O⁺ and H⁺ concentrations and counterstreaming velocities are significantly affected by $\text{E}\text{×}\text{B}$ drift.  相似文献