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1.
V.A. Kashirtsev T.M. Parfenova A.K. Golovko B.L. Nikitenko I.N. Zueva O.N. Chalaya 《Russian Geology and Geophysics》2018,59(10):1380-1388
The composition and distribution of phenanthrenes (polyaromatic compounds) have been studied in chloroform extracts from dispersed organic matter (OM) of clayey, siliceous, carbonate, and terrigenous rocks of different ages and facies and from some oils of the Siberian Platform. Phenanthrenes have been analyzed by gas chromatography-mass spectrometry. High contents of 1,7,8-trimethylphenanthrene and 1,1,7,8-tetramethyl-1,2,3,4-tetrahydrophenanthrene are present in the OM of Vendian and Cambrian carbonate-shale deposits and in ancient oils of the Nepa-Botuobiya and Anabar anteclises. The OM of Permian continental deposits and oils of the Vilyui syneclise is dominated by 1-methyl-7-isopropylphenanthrene (retene). A triangular diagram for identification of the types of original OM of rocks and classification of genetically related oils has been constructed based on the assessment of phenanthrene biomarker distribution. Putative pathways of the formation of phenanthrene biomarkers are discussed. 相似文献
2.
The main episode of Cenozoic volcanic activity occurred simultaneously with formation of the Sayan—Baikal uplift, before the rift depressions were initiated. Volcanism and rifting in this region have developed as independent processes, connected with each other only by an ultimate primary mantle energy source. The volcanic regions do not coincide with the rift depressions, except in the Tunka graben.Chemical features of the volcanics show that during the entire period of volcanic activity there was a complex alternation of basaltic lavas of alkaline, intermediate and tholeiitic composition. Both alkaline and subalkaline lavas are distributed over the entire volcanic region, excepting the Tunka depression where tholeiitic lavas are predominant. However, there is neither mineralogical nor chemical evidence for the existence of two separate magma types within the Baikal rift zone.Judging by the presence of high-pressure, lherzolitic megacrysts of clinopyroxene, and to a lesser extent titaniferous biotite and amphibole in alkaline basalts, variations of lava chemistry are connected with high-pressure fractionation of initial melts, which was more complete for sources outside the rift zone. The predominance of tholeiitic lavas in the Tunka depression is likely to have been caused by a higher degree of partial melting and quick ascent of magma to the surface, facilitated by a high geothermal gradient under the depression where crustal extension is taking place. 相似文献
3.
A. Sajnović K. Stojanović G. S. Pevneva A. K. Golovko B. Jovančičević 《Geochemistry International》2010,48(7):678-694
This paper reports an investigation of 60 samples of lacustrine sedimentary rocks of Neogene age lying at depths of 0–400
m in the Valjevo-Mionica Basin, Serbia. The goal of the study was to determine the origin and type of primary organic matter
(OM), the degree of thermal alteration, the generation potential of OM from the rocks of this basin, and conditions in the
sedimentation environment during the formation of the rocks. The potential of OM of the rocks was estimated on the basis of
the thermolysis of a representative sample after its preliminary debituminization. 相似文献
4.
The peculiarities of magnetosensitive lines in the penumbral spectrum and the abnormal distribution of circular polarization in them are explained satisfactorily in terms of superposition of radiation originating in different elements of penumbral fine structure. Complicated asymmetric rv
– contours can be represented as a sum of two components related to bright (BR) and dark (DR) penumbral regions. Crossover effect in sunspot penumbra appears, when there is considerable relative radial mass velocity in BR and DR, having the magnetic field of different polarities in them. Such conditions are supposed to exist in the penumbra of some sunspots, situated close to the solar limb. 相似文献
5.
The total hydrocarbon composition and average structural-group characteristics of typical Paleozoic crude oils of the Timan–Pechora petroliferous basin are described. The hydrocarbon (HC) types of crudes are compared, which were conventionally determined from the composition of their gasoline fractions, by mass-spectrometric analysis of the HC composition of crudes, and by structural-group analysis of crudes, based on radiospectrometric data. The analyses have shown the presence of 30 structural types of HCs with up to 43 carbon atoms. The whole series of members up to C43 are specific only for HCs with no more than three rings in the molecule. It has been established that the carbonate strata in the basin under investigation, independently of the depth of their occurrence and the age of the host deposits, generate and accumulate heavy high-resin high-sulfur oils rich in alicyclic structures and assigned by HC composition to the naphthene–methane or even naphthene type. Terrigenous reservoirs here abound in crudes of methane–naphthene type. The contents of sulfur and resinous substances and the fraction of carbon atoms in alicyclic HC structures decrease as the depth of occurrence of the host deposits grows, thus reflecting the known gradual process of “methanization” of petroleum composition. 相似文献
6.
A. Šajnović K. Stojanović V. Simić G. S. Pevneva A. K. Golovko B. Jovančiećević 《Geochemistry International》2011,49(10):1022-1034
Liquid thermolysis products of various types of immature kerogen from sedimentary lacustrine rocks from the Valjevo-Mionica
basin in Serbia were studied to evaluate the generation potential of kerogen contained in the organic matter (OM) of the rocks,
determine the composition of the biomarkers and alkylaromatics in the liquid thermolysis products, and elucidate the effect
of Pt4+ and Ru3+ ions (which were added in the form of inorganic salts) on the yield and hydrocarbon composition of the liquid thermolysis
products. For this purpose, representative bitumen-free samples A and B of the sedimentary rocks were subjected to thermolysis
under various conditions. Rock A contains high amount of immature organic matter, which is dominated by kerogen type I/II
and was generated under strongly reduced sedimentation conditions at a high salinity. Sample B is poorer in immature OM than
sample A, and the OM of the former contains kerogen type II/III and was generated predominantly in a reduced environment.
The content of the liquid products and the concentrations of hydrocarbons obtained in the course of thermolysis of bitumen-free
sample A and the typical oil distribution of the biomarkers and alkylaromatics in the thermolysis products confirm a high
generation potential of OM in this rock. In all of our experiments on the thermolysis of bitumen-free sample B, the yield
of liquid products and hydrocarbons is low. According to the kerogen type, the thermolysis of this rock generates much gases.
The Pt4+ and Ru3+ ions (added in the form of simple inorganic salts) increased the yield of liquid (kerogen type I/II) and gaseous (kerogen
type II/III) products. During the thermolysis of various type of immature kerogen in the lacustrine sedimentary rocks at a
temperature of 400°C, the OM attained maturation corresponding to the early catagenesis level. Saturated biomarkers and alkylaomatics
in the thermolysis products of both samples display typical oil distributions. The type of the source OM most strongly affects
the composition of n-alkanes and alkylnaphthalenes. The metal ions used in this research served as catalysts for the methylation process during
the thermolysis of immature kerogen, regardless of its type. The effect of the Pt4+ and Ru3+ ions on other transformations of the hydrocarbons, for example, the destruction of high-molecular n-alkanes to low-molecular ones and on isomerization reactions in molecules of polycyclic biomarkers and alkylaromatics to
thermodynamically more stable isomers in the thermolysis products is controlled, first of all, by the type of the source OM. 相似文献
7.
We generalized experimental data on the structural group composition and macrostructural characteristics of high-molecular compounds (HMCs)—hydrocarbons, resins, and asphaltenes—from more than 180 crude oil samples extracted from different oil fields of Eurasia. Most of oil resin molecules contain 1–3 structural blocks, each consisting of 0–3 aromatic and 0–5 naphthenic rings in different combinations, with the total number of rings in each block not exceeding 5–6. The average molecular weights of resins are no more than 100–1500 a.m.u. Asphaltenes differ from resins from the same source in the larger number of structural blocks (mainly tri- or tetracyclic aromatic) in molecule (up to five), lower degrees of substitution of aromatic cores, and smaller portions of carbon atoms in saturated fragments. The average molecular weights of asphaltenes measured by naphthalene cryoscopy do not exceed 2500 a.m.u. Owing to intermolecular interactions, HMCs form various associates and polymolecular particles, including quasi-crystalline “batches” and multibatch aggregates. Spontaneous disintegration and formation of such particles make the oils dynamically equilibrium polydisperse systems. We have developed the main regularities of compositional and structural changes of HMCs depending on the depth of occurrence, age, and lithologic composition of oil-bearing deposits. Being chemically labile heteroatomic substances, petroleum HMCs are more rapidly subjected to compositional and structural transformations than hydrocarbons, i.e., are more responsive to changes in strata conditions. 相似文献
8.
G.S. Pevneva N.G. Voronetskaya Yu.A. Golovko A.K. Golovko 《Russian Geology and Geophysics》2010,51(3):296-303
Naphthene-benzenes, naphthene-naphthalenes, and naphthene-phenantrenes have been extracted with methanol from mono-, bi-, and triarene fractions of oils of different genetic types from the West Siberian, Timan–Pechora, North Caucasian, and Pannonian (Serbia) oil-and-gas-bearing basins. The hydrocarbon composition and molecular-mass distribution (MMD) of naphthene-arenes have been determined by mass spectrometry. Naphthene-benzene and naphthene-naphthalene molecules contain one to six naphthenic cycles, whereas naphthene-phenantrene molecules contain one to three naphthenic rings. The number of carbon atoms in the alkyl groups of naphthene-benzenes, naphthene-naphthalenes, and naphthene-phenantrenes reaches 38, 20, and 19, respectively. Distinctive features of group compositions and MMD of naphthene-arenes have been revealed in oils generated by different organic matter. 相似文献
9.
The nature and behaviour of large-scale patterns on the solar surface, indicated by the areas of brightness-temperature depressions in the millimetric wavelength range, is studied. A large sample of 346 individual, low-temperature regions (LTRs) was employed to provide reliable statistical evidence. An association of 99% was found between the locations of LTRs and the large-scale magnetic field inversion lines, and 60% of the LTRs were associated with the inversion line filaments. A tentative physical association with filaments is reconsidered, and one particularly well-observed case is presented. The heights of the perturbers causing brightness-temperature depressions are discussed. The long-term evolution of the latitudinal distribution of LTRs is presented in a butterfly diagram. Two belts of low-temperature regions outline the active region belts, shifting with them towards the equator during the solar activity cycle. The low-temperature region belts of the forthcoming cycle appear already at the maximum of the actual cycle at latitudes of about 55 °. The superpositions of the temperature minima distributions in the synoptic maps show patterns appearing as giant cells and compatible with indications inferred from magnetographic data. The reliability of the inferred cells is considered, and a statistical analysis reveals a negligible probability for an accidental distribution appearing in the form of giant cells. 相似文献
10.