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Abstract— We present the results of irradiation experiments aimed at understanding the structural and chemical evolution of silicate grains in the interstellar medium. A series of He+ irradiation experiments have been performed on ultra‐thin olivine, (Mg,Fe)2SiO4, samples having a high surface/volume (S/V) ratio, comparable to the expected S/V ratio of interstellar dust. The energies and fluences of the helium ions used in this study have been chosen to simulate the irradiation of interstellar dust grains in supernovae shock waves. The samples were mainly studied using analytical transmission electron microscopy. Our results show that olivine is amorphized by low‐energy ion irradiation. Changes in composition are also observed. In particular, irradiation leads to a decrease of the atomic ratios O/Si and Mg/Si as determined by x‐ray photoelectron spectroscopy and by x‐ray energy dispersive spectroscopy. This chemical evolution is due to the differential sputtering of atoms near the surfaces. We also observe a reduction process resulting in the formation of metallic iron. The use of very thin samples emphasizes the role of surface/volume ratio and thus the importance of the particle size in the irradiation‐induced effects. These results allow us to account qualitatively for the observed properties of interstellar grains in different environments, that is, at different stages of their evolution: chemical and structural evolution in the interstellar medium, from olivine to pyroxene‐type and from crystalline to amorphous silicates, porosity of cometary grains as well as the formation of metallic inclusions in silicates.  相似文献   
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Avicennia pollen grains have been discovered in marine facies from the Middle Miocene deltaic series of Châteauredon (southeastern France). Based on the local stratigraphy, an age between 15.8 and 16.5 Ma is proposed for these grains. The age and the transgressive context of the Avicennia bearing-levels are in agreement with the maximum extension of the mangrove known in the western Mediterranean during interval N8–NN4 pro parte, in relation with the Langhian highstand. This mangrove occurrence at 42°N latitude during Middle Miocene is a more northern witness of the mangrove sites known in Languedoc and Provence areas. It also implies a lower climatic gradient than today. To cite this article: J.-J. Châteauneuf et al., C. R. Geoscience 338 (2006).  相似文献   
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On December 4, 1983 an eruption started at vents located 1.5 km southwest of the summit of Piton de la Fournaise at the base of the central cone. After 31 months of quiescence this was one of the longest repose period in the last fifty years. The eruption had two phases: December 4 to January 18 and January 18 to February 18. Phase 1 produced about 8 × 106 m3 of lava and Phase II about 9 × 106 m3. The erupted lava is an aphyric basalt whose mineralogical and geochemical composition is close to that of other lavas emitted since 1977.The precursors of the December 4 outbreak were limited to two-week shallow (1.5–3 km) seismic crisis of fewer than 50 events. No long-term increase was noted in the local seismicity which is very quiet during repose periods and no long-term ground inflation preceded the eruption. Outbreaks of Phases I and II were preceded by short (2.5 hours and 1.5 hours) seismic swarms corresponding to the rise of magma toward the surface from a shallow reservoir. Large ground deformation explained by the emplacement of the shallow intrusions, was recorded during the seismic swarms. A summit inflation was observed in early January, before the phase II outbreak, while the phase I eruption was still continuing.Piton de la Fournaise volcanological observatory was installed in 1980. Seismic and ground deformation data now available for a period of 4 years including the 1981 and the 1983–1984 eruptions, allow us to describe the physical behavior of the volcano during this period. These observations lead us to propose that the magma transfer from deep levels to the shallow magma reservoir is not a continuous process but a periodic one and that the shallow magma reservoir was not resupplied before the 1981 and 1983–1984 eruptions. Considerations on the eruptive history and the composition of recent lavas indicate that the reservoir was refilled in 1977.  相似文献   
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Caledonian eclogite-facies metamorphism partially reworking Grenvillian granulite-facies anorthosite allows us to study the processes of garnet reequilibration at high pressure and to reconstruct the evolution of the unit near metamorphic peak conditions. Our results indicate that eclogite-facies metamorphism happened in two successive phases: first, inherited granulitic garnet was fractured and reequilibrated from their boundaries (crystal or fracture rims); then eclogite-facies minerals were crystallised in the fractures as overgrowths on inherited garnets. The reequilibration of inherited garnets is achieved through Fe2+Mg−1 exchange, whereas eclogite-facies garnets crystallised during the subsequent phase are notably richer in Ca than un- and re-equilibrated granulitic garnet. Pseudosection construction shows that this lack in Ca reequilibration cannot be related to variations in thermodynamic conditions (a H2O, reacting system composition) between the two phases. From the compilation of the available data, the reequilibration of granulitic garnet seems to be controlled by the inefficient intra- and inter-granular transport properties of Ca compared to Fe2+ and Mg. While these kinetic factors confine garnet reequilibration to Fe2+Mg−1 exchange, the extent of reequilibration along this exchange vector is controlled by partitioning with adjacent omphacite. On the contrary to the diffusional reequilibration of granulitic garnet that lasted for several My according to our modelling of the diffusional relaxation, the strong compositional gradients between eclogite-facies and reequilibrated garnets, which are almost unaffected by diffusional reequilibration, provide evidence that rapid exhumation followed the crystallisation of eclogite-facies minerals. We propose that the movement reversal itself, from burial to exhumation, and associated deformation and fluid flow, triggered this crystallisation event. The resulting evolution near metamorphic peak conditions is therefore strongly asymmetrical: on the one hand, the prograde diffusional relaxation profiles indicate slow movement during the last stages of burial, whereas the unaffected retrograde overgrowth indicates fast exhumation rates.  相似文献   
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We present and describe in detail the advantages and limitations of a technique that combines in an optimal way model results and proxy-data time series in order to obtain states of the climate system consistent with model physics, reconstruction of past radiative forcing and proxy records. To achieve this goal, we select among an ensemble of simulations covering the last millennium performed with a low-resolution 3-D climate model the ones that minimise a cost function. This cost function measures the misfit between model results and proxy records. In the framework of the tests performed here, an ensemble of 30 to 40 simulations appears sufficient to reach reasonable correlations between model results and reconstructions, in configurations for which a small amount of data is available as well as in data-rich areas. Preliminary applications of the technique show that it can be used to provide reconstructions of past large-scale temperature changes, complementary to the ones obtained by statistical methods. Furthermore, as model results include a representation of atmospheric and oceanic circulations, it can be used to provide insights into some amplification mechanisms responsible for past temperature changes. On the other hand, if the number of proxy records is too low, it could not be used to provide reconstructions of past changes at a regional scale.  相似文献   
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The deep drill hole SG6 in western Siberia (66°N, 78.5°E) penetrated 1.1  km of lower Triassic basalts, which are possibly an extension of the central Siberian Permo– Triassic flood basalt province. About 300 samples of these basalts were progressively demagnetized and measured. Principal component analysis often shows multiple magnetizations carried by haematite and magnetite. The corrected mean inclinations are +77° and −77° for the haematite component. A magnetostratigraphic scale was derived and showed a N–R–N–R–N succession. This is quite different from the Noril'sk and Taimyr typical polarity scale, R–N.
  The basalts found in the SG6 deep drill hole are slightly younger than those of central Siberia and Taimyr. They correspond to middle–upper Induan age, whereas the Noril'sk and Taimyr sections correspond to an uppermost Permian and lower Induan age. Altogether they indicate that, after a high output rate of volcanic material near the Permo–Triassic boundary, this activity slowed down drastically on the Siberian platform and Taimyr, but persisted for several million years in western Siberia.  相似文献   
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