Novae as Thermonuclear Laboratories     

D.D. Clayton 《Astrophysics and Space Science》2003,285(2):353-361

Fred Hoyle undertook a study of observational consequences of the thermonuclear paradigm for the nova event in the years following his 1972 resignation from Cambridge University. The most fruitful of these have been in the areas of gamma-ray astronomy, by which one attempts to measure the level of radioactivity in the nova envelope, and of presolar grain studies in laboratories, by which one measures anomalous isotopic ratios that fingerprint condensation in the thermonuclear event. This work summarizes progress with these two astronomical measures of the novae. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Seasonal δS variations in two high elevation snow pits measured by S-S double spike thermal ionization mass spectrometry     

Jacqueline L. Mann  Christopher A. Shuman  Karl J. Kreutz 《Geochimica et cosmochimica acta》2008,72(15):3907-3927

δ³⁴S and sulfate concentrations were determined in snow pit samples using a thermal ionization mass spectrometric technique capable of 0.2‰ accuracy and requires ≈5 μg (0.16 μmol) natural S. The technique utilizes a ³³S-³⁶S double spike for instrumental mass fractionation correction, and has been applied to snow pit samples collected from the Inilchek Glacier, Kyrgyzstan and from Summit, Greenland. These δ³⁴S determinations provide the first high-resolution seasonal data for these sites, and are used to estimate seasonal sulfate sources. Deuterium (δD) and oxygen (δ¹⁸O) isotope data show that the Inilchek and Summit snow pit samples represent precipitation over ≈20 months.The δ³⁴S values for the Inilchek ranged from +2.6 ± 0.4‰ to +7.6 ± 0.4‰ on sample sizes ranging from 0.3 to 1.8 μmol S. δ³⁴S values for Greenland ranged from +3.6 ± 0.7‰ to +13.3 ± 5‰ for sample sizes ranging from 0.05 to 0.29 μmol S. The concentration ranged from 92.6 ± 0.4 to 1049 ± 4 ng/g for the Inilchek and 18 ± 9 to 93 ± 6 ng/g for the Greenland snow pit. Anthropogenic sulfate dominates throughout the sampled time interval for both sites based on mass balance considerations. Additionally, both sites exhibit a seasonal signature in both δ³⁴S and concentration. The thermal ionization mass spectrometric technique has three advantages compared to gas source isotopic methods: (1) sample size requirements of this technique are 10-fold less permitting access to the higher resolution S isotope record of low concentration snow and ice, (2) the double spike technique permits δ³⁴S and S concentration to be determined simultaneously, and (3) the double spike is an internal standard.  相似文献   

Geochemistry, petrology and ages of the lunar meteorites Kalahari 008 and 009: New constraints on early lunar evolution     

A.K. Sokol  V.A. Fernandes  T. Schulz  A. Bischoff  R.N. Clayton  K. Nishiizumi  L. Schultz  K. Mezger 《Geochimica et cosmochimica acta》2008,72(19):4845-4873

Kalahari 008 and 009 are two lunar meteorites that were found close to each other in Botswana. Kalahari 008 is a typical lunar anorthositic breccia; Kalahari 009 a monomict breccia with basaltic composition and mineralogy. Based on minor and trace elements Kalahari 009 is classified as VLT (very-low-Ti) mare basalt with extremely low contents of incompatible elements, including the REE. The Lu-Hf data define an age of 4286 ± 95 Ma indicating that Kalahari 009 is one of the oldest known basalt samples from the Moon. It provides evidence for lunar basalt volcanism prior to 4.1 Ga (pre-Nectarian) and may represent the first sample from a cryptomare. The very radiogenic initial ¹⁷⁶Hf/¹⁷⁷Hf (εHf = +12.9 ± 4.6), the low REE, Th and Ti concentrations indicate that Kalahari 009 formed from re-melting of mantle material that had undergone strong incompatible trace element depletion early in lunar history. This unusually depleted composition points toward a hitherto unsampled basalt source region for the lunar interior that may represent a new depleted endmember source for low-Ti mare basalt volcanism. Apparently, the Moon became chemically very heterogeneous at an early stage in its history and different cumulate sources are responsible for the diverse mare basalt types.Evidence that Kalahari 008 and 009 may be paired includes the similar fayalite content of their olivine, the identical initial Hf isotope composition, the exceptionally low exposure ages of both rocks and the fact that they were found close to each other. Since cryptomaria are covered by highland ejecta, it is possible that these rocks are from the boundary area, where basalt deposits are covered by highland ejecta. The concentrations of cosmogenic radionuclides and trapped noble gases are unusually low in both rocks, although Kalahari 008 contains slightly higher concentrations. A likely reason for this difference is that Kalahari 008 is a polymict breccia containing a briefly exposed regolith, while Kalahari 009 is a monomict brecciated rock that may never have been at the surface of the Moon.Altogether, the compositions of Kalahari 008 and 009 permit new insight into early lunar evolution, as both meteorites sample lunar reservoirs hitherto unsampled by spacecraft missions. The very low Th and REE content of Kalahari 009 as well as the depletion in Sm and the lack of a KREEP-like signature in Kalahari 008 point to a possible source far from the influence of the Procellarum-KREEP Terrane, possibly the lunar farside.  相似文献   

Multi-decadal synthesis of benthic–pelagic coupling in the western arctic: Role of cross-shelf advective processes     

Kenneth H. Dunton  Jonathan L. Goodall  Susan V. Schonberg  Jacqueline M. Grebmeier  David R. Maidment 《Deep Sea Research Part II: Topical Studies in Oceanography》2005,52(24-26):3462

Using geographic information systems (GIS) software and geostatistical techniques, we utilized three decades of water-column chlorophyll a data to examine the relative importance of autochthonous versus allochthonous sources of reduced carbon to benthic communities that occur from the northern Bering to the eastern Beaufort Sea shelf. Spatial trend analyses revealed areas of high benthic biomass (>300 g m⁻²) and chlorophyll (>150 mg m⁻²) on both the southern and northern Chukchi shelf; both areas are known as depositional centers for reduced organic matter that originates on the Bering Sea shelf and is advected northward in Anadyr and Bering shelf water masses. We found a significant correlation between biomass and chlorophyll a in the Chukchi Sea, reflective of the strong benthic–pelagic coupling in a system that is utilized heavily by benthic-feeding marine mammals. In contrast, there was no significant correlation between biomass and chlorophyll in the Beaufort Sea, which by comparison, is considerably less productive (biomass and chlorophyll, <75 g m⁻² and <50 mg m⁻², respectively). One notable exception is an area of relatively high biomass (50–100 g m⁻²) and chlorophyll (80 mg m⁻²) near Barter Island in the eastern Beaufort Sea. Compared to other adjacent areas in the Beaufort Sea, the chlorophyll values in the vicinity of Barter Island were considerably higher and likely reflect a long-hypothesized upwelling in that area and close coupling between the benthos and autochthonous production. In the Bering Sea, a drop in benthic biomass in 1994 compared with previous measurements (1974–1993) may support earlier observations that document a decline in biomass that began between the 1980s and 1990s in the Chirikov Basin and south of St. Lawrence Island. The results of this study indicate that the benthos is an excellent long-term indicator of both local and physical advective processes. In addition, this work provides further evidence that secondary production on arctic shelves can be significantly augmented by reduced carbon advected from highly productive adjacent shelves.  相似文献   

Significance of vertical flux as a sink for surface water DMSP and as a source for the sediment surface in coastal zones of northern Europe     

Sauveur Belviso  Grard Thouzeau  Sabine Schmidt  Marit Reigstad  Paul Wassmann  Elena Arashkevich  Jacqueline Stefels 《Estuarine, Coastal and Shelf Science》2006,68(3-4):473

In April 1997 and 1998 the significance of sedimentation as a sink for epipelagic dimethylsulphoniopropionate (DMSP) production and as a source for marine sediments was reassessed using a newly designed sediment trap. The behaviour of the traps in immersion was monitored continuously and the collection efficiency was evaluated with ²³⁴Th measurements. Net DMS(P) fluxes were corrected for some physical and biological losses during the whole sedimentation process providing reliable estimates of gross DMSP fluxes. It is shown that daily losses by sedimentation account for between 0.1% and 16% of seawater particulate DMSP (DMSPp) standing stocks, and between 3% and 75% of daily DMSPp production. In the Malangen fjord we observed temporal increases of DMSP production and standing stocks which resulted also in increases of DMSP vertical fluxes and DMS(P) concentrations at the sediment surface. This result illustrates how tight the coupling can be between pelagos and benthos, and confirms that DMS(P) concentration in the sediment was a reliable diagnostic indicator of vertical export from overlying waters in Malangen fjord. In Ullsfjord, however, DMS(P) concentrations in the sediment were poorly indicators of Phaeocystis pouchetii export during the early stage of growth of a bloom. The high load of DMS(P) in Balsfjord's sediments could neither be attributed to local vertical sedimentation nor to short-term lateral advection of fresh DMSP-containing phytoplanktonic material, and provides indication that this tracer sometimes also can be misleading. The highest loads of DMS(P) in sediments and the fastest rates of sedimentation occurred in the Southern Bight of the North Sea.  相似文献   

Geospatial Analysis: A Comprehensive Guide to Principles,Techniques, and Software Tools,Second Edition ‐ by Michael J. de Smith,Michael F. Goodchild,and Paul A. Longley     

Jacqueline W. Mills 《Transactions in GIS》2008,12(5):645-647

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Uncertainty as the overlap of alternate conditional distributions     

Olena Babak  Clayton V. Deutsch 《Computational Geosciences》2008,12(4):503-512

An important task in modern geostatistics is the assessment and quantification of resource and reserve uncertainty. This uncertainty is valuable support information for many management decisions. Uncertainty at specific locations and uncertainty in the global resource is of interest. There are many different methods to build models of uncertainty, including Kriging, Cokriging, and Inverse Distance. Each method leads to different results. A method is proposed to combine local uncertainties predicted by different models to obtain a combined measure of uncertainty that combines good features of each alternative. The new estimator is the overlap of alternate conditional distributions.  相似文献   

Experimental study of a jotunite (hypersthene monzodiorite): constraints on the parent magma composition and crystallization conditions (P,T, f O 2) of the Bjerkreim-Sokndal layered intrusion (Norway)     

Jacqueline Vander Auwera  John Longhi 《Contributions to Mineralogy and Petrology》1994,118(1):60-78

The Bjerkreim-Sokndal layered intrusion is part of the Rogaland anorthosite Province of southern Norway and is made of cumulates of the anorthositemangerite-charnockite suite. This study presents experimental phase equilibrium data for one of the finegrained jotunite (Tjörn locality) occurring along its northwestern lobe. These experimental data show that a jotunitic liquid similar in composition to the Tjörn jotunite, but slightly more magnesian and with a higher plagioclase component is the likely parent of macrocyclic units (MCU)III and IV of the intrusion. The limit of the olivine stability field in the experimentally determined phase diagram as well as comparison of the Al₂O₃ content of low-Ca pyroxenes from experiments and cumulates (1.5%) yields a pressure of emplacement 5 kbar. Experimentally determined Fe-Ti oxide equilibria compared to the order of cumulus arrival in the intrusion show that the oxygen fugacity was close to FMQ (fayalite-magnetite-quartz) during the early crystallization. It subsequently decreased relative to this buffer when magnetite disappeared from the cumulus assemblage and then increased until the reentry of this mineral. Calculated densities of experimental liquids show a density increase with fractionation at 7, 10 and 13 kbar due to the predominance of plagioclase in the crystallizing assemblage. At 5 kbar and 1 atm (FMQ-1), where plagioclase is the liquidus phase, density first increases and then drops when olivine (5 kbar) or olivine+ilmenite (1 atm: FMQ-1) precipitate. At 1 atm and NNO (nickel-nickel oxide), the presence of both magnetite and ilmenite as near liquidus phases induces a density decrease. In the Bjerkreim magma chamber, oxides are early cumulus phases and liquid density is then supposed to have decreased during fractionation. This density path implies that new influxes of magma emplaced in the chamber were both hotter and denser than the resident magma. The density contrast inferred between plagioclase and the parent magma shows that this mineral was not able to sink in the magma, suggesting anin situ crystallization process.  相似文献   

Aqueous alteration of the Bali CV3 chondrite: evidence from mineralogy, mineral chemistry, and oxygen isotopic compositions     

Keller LP  Thomas KL  Clayton RN  Mayeda TK  DeHart JM  McKay DS 《Geochimica et cosmochimica acta》1994,58(24):5589-5598

A petrographic, geochemical, and oxygen isotopic study of the Bali CV3 carbonaceous chondrite revealed that the meteorite has undergone extensive deformation and aqueous alteration on its parent body. Deformation textures are common and include flattened chondrules, a well-developed foliation, and the presence of distinctive (100) planar defects in olivine. The occurrence of alteration products associated with the planar defects indicates that the deformation features formed prior to the episode of aqueous alteration. The secondary minerals produced during the alteration event include well-crystallized Mg-rich saponite, framboidal magnetite, and Ca-phosphates. The alteration products are not homogeneously distributed throughout the meteorite, but occur in regions adjacent to relatively unaltered material, such as veins of altered material following the foliation. The alteration assemblage formed under oxidizing conditions at relatively low temperatures (<100 degrees C). Altered regions in Bali have higher Na, Ca, and P contents than unaltered regions which suggests that the fluid phase carried significant dissolved solids. Oxygen isotopic compositions for unaltered regions in Bali fall within the field for other CV3 whole-rocks, however, the oxygen isotopic compositions of the heavily altered material lie in the region for the CM and CR chondrites. The heavy-isotope enrichment of the altered regions in Bali suggest alteration conditions similar to those for the petrographic type-2 carbonaceous chondrites.  相似文献   

Solar system isotopic anomalies: Supernova neighbor or presolar carriers?     

Donald D. Clayton 《Icarus》1977,32(3):255-269

I evaluate several nuclear and chemical problems related both to the recent scenario suggesting that the known isotopic anomalies in the solar system have resulted from a supernova near the protosolar nebula and to the model of extinct presolar carriers. Major features include: (1) Large quantities of extinct ²⁴⁸Cm and ³⁶Cl are predicted from the Cameron-Truran model of a minor injection about 10⁶ yr before condensation; (2) an extinct-carrier model of ²⁶Mg is set forth in detail with a solid chemistry picture of the early solar system; (3) a major thermonuclear supernova responsible for ²⁶Al, ²⁴⁴Pu, and ⁴⁰K would have to have occurred several million years (3 m.y.) before condensation and contributed a large fraction of the major stable chemical elements; (4) carbon isotope families are to be expected if the oxygen isotope families are due to a late injection of ¹⁶O; (5) the Earth and E meteorites may have condensed primarily in a carbon-rich nebula existing before admixtures of a major late ¹⁶O-rich mixture; (6) the extinct-presolar-carrier model is the single best explanation of all anomalies.  相似文献