Origin of nickel in water solution of the chalk aquifer in the north of France and influence of geochemical factors     

Daniel Bernard  Jamal El Khattabi  Emilie Lefevre  Hani Serhal  Sabine Bastin-Lacherez  Isam Shahrour 《Environmental Geology》2008,53(5):1129-1138

In the north of France, high registers of nickel are sometimes recorded within the chalk aquifer. In a confined context, the presence of pyrite in the covering clays or in the marcasite nodules encrusted in the clay may constitute a natural source of trace metals. With an objective of sanitary control, the limits of chemical contents regulating the quality of water destined for human consumption have been lowered by the European Framework Directive in the field of water policy (2000/60/EC). As a result, nickel limits have been reduced from 50 to 20 μg/l. The analyses, carried out on three water catchment fields in our area of study, were centred on variable parameters (Eh, O₂(d), pH, Conductivity, T°), major elements (SO₄, NO₃) and metals (Fe, Ni, Mn, Co). The acquired data enabled us to identify from one hand, the conditions which are presented within the site, special thanks to the evolution of nitrate and iron contents and on the other hand, the natural origin (geological) of nickel for two of the three sites studied based essentially on the evaluation of the Nickel/Cobalt ratio. Thus, on the first site, the evolution of nickel content and nitrate content showed the influence of the phenomenon of denitrification on the re-mobilisation of the nickel. Whereas on the second site, a high variation of total iron content and oxygen dissolved in solution highlighted a particular phenomenon of oxidation of the pyrite through molecular oxygen. Finally, the correlation with the sulphates clearly showed behaviour of the nickel, once released, that was entirely dependent on the phenomenon of adsorption on the iron and manganese hydroxides.  相似文献   

Probabilistic seismic hazard zonation of Syria     

Abdallah I. Husein Malkawi  Robert Y. Liang  Jamal H. Nusairat  Azm S. Al-Homoud 《Natural Hazards》1995,12(2):139-151

Earthquake hazard maps for Syria are presented in this paper. The Peak Ground Acceleration (PGA) and the Modified Mercalli Intensity (MMI) on bedrock, both with 90% probability of not being exceeded during a life time of 50, 100 and 200 years, respectively are developed. The probabilistic PGA and MMI values are evaluated assuming linear sources (faults) as potential sources of future earthquakes. A new attenuation relationship for this region is developed. Ten distinctive faults of potential earthquakes are identified in and around Syria. The pertinent parameters of each fault, such as theb-parameter in the Gutenberg-Richter formula, the annual rate ₄ and the upper bound magnitudem ₁ are determined from two sets of seismic data: the historical earthquakes and the instrumentally recorded earthquake data (AD 1900–1992). The seismic hazard maps developed are intended for preliminary analysis of new designs and seismic check of existing civil engineering structures.  相似文献   

Effect of aluminum and chromium on the germination and growth of two Vigna species     

S. N. Jamal B. Sc.  M. Sc.  M. Zafar Iqbal B.Sc.  M.Sc  Ph.D.  M. Athar M.Sc  MPhil.  Ph.D.  D.Sc 《International Journal of Environmental Science and Technology》2006,3(1):53-58

The study deals with the effect of metal toxicity (aluminum, chromium and combination of both the metals) on seed germination, root length, shoot length, seedling length and dry biomass of Vigna radiata and V. sinensis. Chromium adversely affected the seedling by significantly reducing the growth whereas aluminum did not show such effect in both the species. Percentage of germination was good in both the species at different concentration of treatment (aluminum, chromium and combined treatment). Shoot length was also not much affected in V. sinensis as it was greatly inhibited in V. radiata. Both the species showed the purpling of stem. Dry biomass of V. radiata showed positive effect than V. sinensis. However, dry biomass decreased to a lesser extent when treated with aluminum, chromium and combined treatment as compared to control.  相似文献   

De nouveaux éléments structuraux du complexe aquifère profond du bassin du Rharb (Maroc) : implications hydrogéologiques     

Malika Kili  Bouabid El Mansouri  Jamal Chao  Abderrahman Ait Fora 《Comptes Rendus Geoscience》2006,338(16):1194-1202

The Rharb basin is located in northwestern Morocco. It is a part of one of the most important hydrogeological basins of Morocco, and extends over some 4000 km². The nature of its Plio-Quaternary sedimentary fill and its structural and palaeoenvironmental contexts are reflected by great variations in aerial and temporal facies distribution. This distribution, in turn, is a direct cause of the observed complexity in the geometry of potentially water-bearing beds. In the present work, we present an image of potential new hydrogeological reservoirs and define new structures that partially explain their architecture. To cite this article: M. Kili et al., C. R. Geoscience 338 (2006).  相似文献   

Tectonic and hydrodynamic control of landslides in the northern area of the Central Rif, Morocco   总被引：1，自引：0，他引：1  

Jamal El Khattabi  Erick Carlier   《Engineering Geology》2004,71(3-4):255-264

The northern edge of the Central Rif (Morocco) is subject to numerous landslides where mechanisms do not correspond to the classical models used by geomechanics specialists. It is necessary to adopt a multidisciplinary approach that combines geomorphology, geology, hydrogeology, and geotechnics in order to understand how such slope failures are generated, especially in a region with a heterogeneous structure characterised by significant lithological differences, severe fracturing, and thrust sheets where tectonic contacts play a major role in groundwater circulation. This report shows that these failures are essentially controlled by the tectonic contact separating the Tisirene and Chouamat thrust sheets and by subsurface hydrodynamic conditions. A model of spatial and temporal variations in the factor of safety is proposed.  相似文献   

An Experimental Study of Cutting Performances of Worn Picks     

Cihan Dogruoz  Naci Bolukbasi  Jamal Rostami  Cemil Acar 《Rock Mechanics and Rock Engineering》2016,49(1):213-224

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Impact of Overcut on Interaction Between Shield and Ground in the Tunneling with a Double-shield TBM     

Rohola Hasanpour  Jamal Rostami  Yılmaz Özçelik 《Rock Mechanics and Rock Engineering》2016,49(5):2015-2022

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Performance Assessment of Hard Rock TBM and Rock Boreability Using Punch Penetration Test     

Ho-Young Jeong  Jung-Woo Cho  Seokwon Jeon  Jamal Rostami 《Rock Mechanics and Rock Engineering》2016,49(4):1517-1532

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TiO<Subscript>2</Subscript>-based shaped catalyst for the recovery of elemental sulfur from H<Subscript>2</Subscript>S and SO<Subscript>2</Subscript> gas streams     

V. Nourozi Rad  M. Anbia  M. Hossaini Sadr 《International Journal of Environmental Science and Technology》2018,15(3):631-636

The Claus process has been used for the conversion of H₂S and SO₂ to elemental sulfur. These two sulfur compounds need special attention because they are very poisonous with negative impact on both the environment and human health. Here, highly active Fe–Ni/TiO₂ catalyst has been prepared and shaped by three different binders (bentonite, polyethylene glycol and carboxymethyl cellulose) into extrudes. Comparing the mechanical strength and surface area of prepared extrudes, the optimal shaped catalyst was selected with 20% of bentonite, 2% of PEG and 2% of CMC. The optimal catalyst was characterized by X-ray powder diffraction, temperature-programmed reduction, Brunauer–Emmett–Teller specific surface area, Barrett–Joyner–Halenda, scanning electron microscopy and energy-dispersive X-ray techniques and used for sulfur recovery process. The performance of this product for sulfur recovery via Claus process was excellent with the conversion of hydrogen sulfide of 76.77% and sulfur dioxide of 97.83%. The catalyst also provides high hydrolysis activity of CS₂ (83.06%). Therefore, a highly active TiO₂-supported shaped catalyst with 85.62% of conversion efficiency has been prepared successfully to convert the small amounts of H₂S, SO₂ and CS₂ to elemental sulfur.  相似文献   

Removal of diazinon pesticide from aqueous solutions using MCM-41 type materials: isotherms,kinetics and thermodynamics     

M. A. Amani  A. M. Latifi  K. Tahvildari  R. Karimian 《International Journal of Environmental Science and Technology》2018,15(6):1301-1312

In this research, ordered mesoporous silica, including MCM-41, was synthesized via sol–gel process and a propyl methacrylate-modified ordered mesoporous silica (MPS-MCM-41) was successfully synthesized via a postsynthesis grafting process. Then both MCM-41 and MPS-MCM-41 were characterized using FTIR, XRD, SEM and BET techniques. The synthesized materials were utilized as adsorbent for removal of diazinon pesticide from aqueous solutions. The effects of pH, contact time, adsorbent dose, initial concentration and temperature have been evaluated using removal efficiencies. Also, the kinetic, thermodynamic and isotherm models of diazinon adsorption were studied for the both MCM-41 and MPS-MCM-41. The results showed that the maximum adsorption capacities are 142 and 254 mg g^?1 for the MCM-41 and MPS-MCM-41, respectively, at the initial concentration of 50 mg L^?1, temperature of 298 K and adsorbent dose of 0.1 g L^?1. The highest percentages of diazinon removal are 56.4 and 87.2 (at adsorbent dose of 2 g L^?1 and the temperature of 318 K) for the MCM-41 and MPS-MCM-41, respectively. The Freundlich and Langmuir models are more compatible for describing equilibrium data of the diazinon adsorption capacity on the MCM-41 and MPS-MCM-41, respectively. Thermodynamic study indicated that the adsorption process of diazinon onto MCM-41 and MPS-MCM-41 is exothermic and has a spontaneous nature. The higher adsorption capacity and higher spontaneous nature of MPS-MCM-41 in comparison with MCM-41 might be due to the presence of the both hydrogen bonding and hydrophobic interaction between surface functional groups of MPS-MCM-41 (hydroxyl and propyl methacrylate) and diazinon functional groups.  相似文献