Solid‐state 13C NMR characterization of insoluble organic matter from Antarctic CM2 chondrites: Evaluation of the meteoritic alteration level     

Hikaru YABUTA  Hiroshi NARAOKA  Kinya SAKANISHI  Hiroyuki KAWASHIMA 《Meteoritics & planetary science》2005,40(5):779-787

Abstract— Chemical structures of the insoluble organic matter (IOM) from the Antarctic CM2 chondrites (Yamato [Y‐] 791198, 793321; Belgica [B‐] 7904; Asuka [A‐] 881280, 881334) and the Murchison meteorite were analyzed by solid‐state ¹³C nuclear magnetic resonance (NMR) spectroscopy. Different types of carbons were characterized, such as aliphatic carbon (Ali‐C), aliphatic carbon linked to hetero atom (Hetero‐Ali‐C), aromatic carbon (Aro‐C), carboxyls (COOR), and carbonyls (C=O). The spectra of the IOM from Murchison and Y‐791198 showed two major peaks: Ali‐C and Aro‐C, while the spectra from the other meteorites showed only one major peak of Aro‐C. Carbon distribution was determined both by manual integration and deconvolution. For most IOM, the Aro‐C was the most abundant (49.8–67.8%) of all carbon types. When the ratios of Ali‐C to Aro‐C (Ali/Aro) were plotted with the atomic hydrogen to carbon ratio (H/C), a correlation was observed. If we use the H/C as a parameter for the thermal alteration event on the meteorite parent body, this result shows a different extent of thermal alteration. In addition, IOM with a lower Ali/Aro showed a lower ratio of Ali‐C to COOR plus C=O (Ali / (COOR + C=O)). This result suggests that the ratio of CO moieties to aliphatic carbon in IOM might reflect chemical oxidation that was involved in hydrothermal alteration.  相似文献   

Increase in medium-size rainfall events will enhance the C-sequestration capacity of biological soil crusts     

CuiHua Huang  Fei Peng  Itaru Shibata  Jun Luo  Xian Xue  Kinya Akashi  Atsushi Tsunekawa  Tao Wang 《寒旱区科学》2019,11(1):81-92

Biological soil crusts(BSCs) play important roles in the carbon(C) balance in arid regions. Net C balance of BSCs is strongly dependent on rainfall and consequent activation of microbes in the BSCs. The compensation-rainfall size for BSCs(the minimum rainfall amount for a positive net C balance) is assumed to be different with BSCs of different developmental stages. A field experiment with simulated rainfall amount(SRA) of 0, 1, 5, 10, 20, and 40 mm was conducted to examine the C fluxes and compensation-rainfall size of BSCs in different parts of fixed dunes in the ecotone between the Badain Jaran Desert and the Minqin Oasis. We found algae-lichen crust on the interdunes and crest, algae crust on the leeward side, and lichen-moss crust on the windward. Even a small rainfall(1 mm) can activate both photosynthesis and respiration of all types of BSCs. The gross ecosystem production, ecosystem respiration, and net ecosystem exchange were significantly affected by SRA, hours after the simulated rainfall, position on a dune, and their interactions. The rapid activation of photosynthesis provides a C source and therefore could be responsible for the increase of C efflux after each rewetting. C-uptake and-emission capacity of all the BSCs positively correlated with rainfall size, with the lowest C fluxes on the leeward side. The compensation rainfall for a net C uptake was 3.80, 15.54, 8.62, and 1.88 mm for BSCs on the interdunes, the leeward side, the crest, and the windward side, respectively. The whole dune started to show a net C uptake with an SRA of 5 mm and maximized with an SRA of about 30 mm. The compensation-rainfall size is negatively correlated with chlorophyll content. Our results suggest that BSCs will be favored in terms of C balance, and sand dune stabilization could be sustained with an increasing frequency of 5-10 mm rainfall events in the desert-oasis transitional zone.-  相似文献   

Equivalent linear method considering frequency dependent characteristics of stiffness and damping   总被引：4，自引：0，他引：4  

Nozomu Yoshida  Satoshi Kobayashi  Iwao Suetomi  Kinya Miura 《Soil Dynamics and Earthquake Engineering》2002,22(3)

Equivalent linear dynamic response analysis of ground is based on complex moduli and Fourier series expansion; therefore, it is not an equivalent method but an approximate method. Two deficiencies in the conventional equivalent linear method represented by SHAKE are described first. The maximum shear strength is overestimated, resulting in overestimation of the peak acceleration under a strong ground motion, and the amplification is underestimated at high frequency. The latter sometimes results in underestimation of the peak acceleration under weak ground shaking, and gives an incident wave with unrealistic large accelerations or a divergence of analysis in deconvolution analysis under strong ground motion. Both deficiencies are shown to come from the same cause, i.e. computing the effective strain as a constant fraction of the maximum strain. Since this is a key concept of the equivalent linear analysis, one cannot overcome both deficiencies at the same time in the conventional method. An apparent frequency dependence in stiffness and damping is shown to appear in the dynamic response, although soil itself does not show frequency dependent characteristics. Following this observation, the effective strain is expressed in terms of frequency from the similarity concept of the strain–frequency relationship between time domain and frequency domain. This enables the reduction of both deficiencies at the same time, resulting in a marked improvement in the equivalent linear analysis. The accuracy of the proposed method is examined by the simulations of three vertical array records during large earthquakes. The proposed method always gives much better prediction than conventional equivalent linear methods for both convolution and deconvolution analyses, and it is confirmed to be applicable at more than 1% shear strain.  相似文献   

The design of diamond Compton telescope     

Kinya Hibino  Toshisuke Kashiwagi  Shoji Okuno  Kaori Yajima  Yukio Uchihori  Hisashi Kitamura  Takeshi Takashima  Mamoru Yokota  Kenji Yoshida 《Astrophysics and Space Science》2007,309(1-4):541-544

We have developed radiation detectors using the new synthetic diamonds. The diamond detector has an advantage for observations of “low/medium” energy gamma rays as a Compton telescope. The primary advantage of the diamond detector can reduce the photoelectric effect in the low energy range, which is background noise for tracking of the Compton recoil electron. A concept of the Diamond Compton Telescope (DCT) consists of position sensitive layers of diamond-striped detector and calorimeter layer of CdTe detector. The key part of the DCT is diamond-striped detectors with a higher positional resolution and a wider energy range from 10 keV to 10 MeV. However, the diamond-striped detector is under development. We describe the performance of prototype diamond detector and the design of a possible DCT evaluated by Monte Carlo simulations.   相似文献