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1.
Carbonate-rich sedimentary rocks of the western Anabar region, northern Siberia, preserve an exceptional record of evolutionary and biogeochemical events near the Proterozoic/Cambrian boundary. Sedimentologically, the boundary succession can be divided into three sequences representing successive episodes of late transgressive to early highstand deposition; four parasequences are recognized in the sequence corresponding lithostratigraphically to the Manykal Formation. Small shelly fossils are abundant and include many taxa that also occur in standard sections of southeastern Siberia. Despite this coincidence of faunal elements, biostratigraphic correlations between the two regions have been controversial because numerous species that first appear at or immediately above the basal Tommotian boundary in southeastern sections have first appearances scattered through more than thirty metres of section in the western Anabar. Carbon- and Sr-isotopic data on petrographically and geochemically screened samples collected at one- to two-metre intervals in a section along the Kotuikan River, favour correlation of the Staraya Reckha Formation and most of the overlying Manykai Formation with sub-Tommotian carbonates in southeastern Siberia. In contrast, isotopic data suggest that the uppermost Manykai Formation and the basal 26 m of the unconformably overlying Medvezhya Formation may have no equivalent in the southeast; they appear to provide a sedimentary and palaeontological record of an evolutionarily significant time interval represented in southeastern Siberia only by the sub-Tommotian unconformity. Correlations with radiometrically dated horizons in the Olenek and Kharaulakh regions of northern Siberia suggest that this interval lasted approximately three to six million years, during which essentially all 'basal Tommotian' small shelly fossils evolved.  相似文献   
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The thick, richly fossiliferous succession of the upper Windermere Supergroup, Mackenzie Mountains, northwestern Canada, provides a test of integrated biostratigraphic and chemostratigraphic frameworks in terminal Proterozoic correlation. The C- and Sr-isotopic abundances of lower Keele Formation carbonates approximate those for other pre-Varanger samples, confirming that the simple disc-like fossils of the underlying Twitya Formation predate all known diverse Ediacaran faunas. "Tepee" and Sheepbed carbonates record strong post-glacial isotopic excursions; in contrast, delta13C values for Gametrail through Risky carbonates vary only within the narrow range of about +l% to +2%. A second negative excursion occurs in Ingta Formation carbonates that immediately underlie the paleontologically determined Precambrian-Cambrian boundary. The upper Windermere profile as a whole compares closely with curves determined for other terminal Proterozoic successions. The lowermost diverse Ediacaran assemblages in the Sheepbed Formation correlate chemostratigraphically with the oldest fauna in Namibia, but the two assemblages differ in taxonomic composition. Blueflower assemblages correlate both chemostratigraphically and taxonomically with faunas from Australia, China, Siberia, and elsewhere. Increasing data support the hypothesis that paleontological and geochemical data together provide a reliable means of correlating terminal Proterozoic sedimentary rocks throughout the world.  相似文献   
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The MER rover Opportunity has carried out the first outcrop-scale investigation of ancient sedimentary rocks on Mars. The rocks, exposed in craters and along fissures in Meridiani Planum, are sandstones formed via the erosion and re-deposition of fine grained siliciclastics and evaporites derived from the chemical weathering of olivine basalts by acidic waters. A stratigraphic section more than seven meters thick measured in Endurance crater is dominated by eolian dune and sand sheet facies; the uppermost half meter, however, exhibits festoon cross lamination at a length scale that indicates subaqueous deposition, likely in a playa-like interdune setting. Silicates and sulfate minerals dominate outcrop geochemistry, but hematite and Fe3D3 (another ferric iron phase) make up as much as 11% of the rocks by weight. Jarosite in the outcrop matrix indicates precipitation at low pH. Cements, hematitic concretions, and crystal molds attest to a complex history of early diagenesis, mediated by ambient ground waters. The depositional and early diagenetic paleoenvironment at Meridiani was arid, acidic, and oxidizing, a characterization that places strong constraints on astrobiologial inference.  相似文献   
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New data returned from the Mars Exploration Rover (MER) mission have revealed abundant evaporites in the sedimentary record at Meridiani Planum. A working hypothesis for Meridiani evaporite formation involves the evaporation of fluids derived from the weathering of martian basalt and subsequent diagenesis. On Earth, evaporite formation in exclusively basaltic settings is rare. However, models of the evaporation of fluids derived from experimentally weathering synthetic martian basalt provide insight into possible formation mechanisms. The thermodynamic database assembled for this investigation includes both Fe2+ and Fe3+ in Pitzer's ion interaction equations to evaluate Fe redox disequilibrium at Meridiani Planum. Modeling results suggest that evaporation of acidic fluids derived from weathering olivine-bearing basalt should produce Mg, Ca, and Fe-sulfates such as jarosite and melanterite. Calculations that model diagenesis by fluid recharge predict the eventual breakdown of jarosite to goethite as well as the preservation of much of the initial soluble evaporite component at modeled porosity values appropriate for relevant depositional environments (< 0.30). While only one of several possible formation scenarios, this simple model is consistent with much of the chemical and mineralogical data obtained on Meridiani Planum outcrop.  相似文献   
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After a short introduction into the field of the zeolites the use of the molecular sieve 4 A as builder in the washing process is treated. Structure and ion-exchange capacity are characterized, the mechanism of the elimination of calcium-ions is described and the environmental behaviour is examined. Finally, other potential applications of zeolitic ion exchangers are presented.  相似文献   
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We want to develop a dialogue between geophysicists and hydrologists interested in synergistically advancing process based watershed research. We identify recent advances in geophysical instrumentation, and provide a vision for the use of electrical and magnetic geophysical instrumentation in watershed scale hydrology. The focus of the paper is to identify instrumentation that could significantly advance this vision for geophysics and hydrology during the next 3–5 years. We acknowledge that this is one of a number of possible ways forward and seek only to offer a relatively narrow and achievable vision. The vision focuses on the measurement of geological structure and identification of flow paths using electrical and magnetic methods. The paper identifies instruments, provides examples of their use, and describes how synergy between measurement and modelling could be achieved. Of specific interest are the airborne systems that can cover large areas and are appropriate for watershed studies. Although airborne geophysics has been around for some time, only in the last few years have systems designed exclusively for hydrological applications begun to emerge. These systems, such as airborne electromagnetic (EM) and transient electromagnetic (TEM), could revolutionize hydrogeological interpretations. Our vision centers on developing nested and cross scale electrical and magnetic measurements that can be used to construct a three‐dimensional (3D) electrical or magnetic model of the subsurface in watersheds. The methodological framework assumes a ‘top down’ approach using airborne methods to identify the large scale, dominant architecture of the subsurface. We recognize that the integration of geophysical measurement methods, and data, into watershed process characterization and modelling can only be achieved through dialogue. Especially, through the development of partnerships between geophysicists and hydrologists, partnerships that explore how the application of geophysics can answer critical hydrological science questions, and conversely provide an understanding of the limitations of geophysical measurements and interpretation. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
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