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1.
We will report on the current configuration of the X-ray facility of the University of Ferrara recently used to perform reflectivity tests of mosaic crystals and to calibrate the experiment JEM–X aboard Integral. The facility is now located in the technological campus of the University of Ferrara in a new building (named LARIX laboratory= ̳LARge ̳Italian ̳X-ray facility) that includes a tunnel 100 m long with, on the sides, two large experimental rooms. The facility is being improved for determining the optical axis of mosaic crystals in Laue configuration, for calibrating Laue lenses and hard X-ray mirror prototypes.  相似文献   
2.
The sulfur isotopic composition of carbonate associated sulfate (CAS) has been used to investigate the geochemistry of ancient seawater sulfate. However, few studies have quantified the reliability of δ34S of CAS as a seawater sulfate proxy, especially with respect to later diagenetic overprinting. Pyrite, which typically has depleted δ34S values due to authigenic fractionation associated with bacterial sulfate reduction, is a common constituent of marine sedimentary rocks. The oxidation of pyrite, whether during diagenesis or sample preparation, could thus adversely influence the sulfur isotopic composition of CAS. Here, we report the results of CAS extractions using HCl and acetic acid with samples spiked with varying amounts of pyrite. The results show a very strong linear relationship between the abundance of fine-grained pyrite added to the sample and the resultant abundance and δ34S value of CAS. This data represents the first unequivocal evidence that pyrite is oxidized during the CAS extraction process. Our mixing models indicate that in samples with much less than 1 wt.% pyrite and relatively high δ34Spyrite values, the isotopic offset imparted by oxidation of pyrite should be much less than ? 4‰. A wealth of literature exists on the oxidation of pyrite by Fe3+ and we believe this mechanism drives the oxidation of pyrite during CAS extraction, during which the oxygen used to form sulfate is taken from H2O, not O2. Consequently, extracting CAS under anaerobic conditions would only slow, but not halt, the oxidation of pyrite. Future studies of CAS should attempt to quantify pyrite abundance and isotopic composition.  相似文献   
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High-pressure single-crystal X-ray diffraction measurements of lattice parameters of the compound Li2VOSiO4, which crystallises with a natisite-type structure, has been carried out to a pressure of 8.54(5) GPa at room temperature. Unit-cell volume data were fitted with a second-order Birch-Murnaghan EoS (BM-EoS), simultaneously refining V 0 and K 0 using the data weighted by the uncertainties in V. The bulk modulus is K 0 = 99(1) GPa, with K′ fixed to 4. Refinements of third order equations-of-state yielded values of K′ that did not differ significantly from 4. The compressibility of the unit-cell is strongly anisotropic with the c axis (K 0(c) = 49.7 ± 0.5 GPa) approximately four times more compressible than the a axis (K 0(a) = 195 ± 3 GPa).  相似文献   
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This paper reports a study of the field measurements and monitoring of wastewater discharge in sea water at Bari East (Italy). A wastewater sea outfall system is an integral and fundamental part of each wastewater treatment with ultimate sink in the sea water. The design of a water treatment plant and wastewater outfall must take into account the use of the environmental water, the values of physicochemical parameters to be respected in order to safeguard the use itself and the quality of the environmental water where wastewater is issued. In the present study measurements of sea current velocity components were carried out with a VM-ADP (Vessel-Mounted Acoustic Doppler Profiler). Salinity, wind directions and velocities were assessed with, for one survey, the total faecal coliforms and other biochemical parameters. It was emphasized that the measurements necessary for monitoring cannot be concentrated in the wastewater outfall pipe zone only, but should be extended to a neighbouring area of the outfall pipe, with an extension depending on the wastewater discharge, the polluting charge and the magnitude of the sea currents and the winds typical of the zone of interest. The analyses presented in this paper confirm that the sea zones close to the wastewater outfall pipe are particularly sensitive and vulnerable. Such results must be considered in the planning of a wastewater outfall pipe.  相似文献   
8.
Abstract. The importance of sponge spicules in the turnover of biogenic silica (BSi) in the detritic bottoms of the Eastern Ligurian Riviera was evaluated by studying sediment cores and the detrital matter collected by a trap over a one year period.
This study made evident that: i) Sponge spicules represent the main component of the BSi both in the sediments and in the trapped matter; ii) A correlation exists between the sponge biomass present on the overhanging cliff and the amount of sponge spicules found in the sediment below; iii) Inside the sediments, a superficial layer (10 cm deep) characterized by intensive silica dissolution processes can be observed; and iv) The amount of spicules collected using the trap is not constant throughout the year, but shows a characteristic trend with low values in spring and summer and high values in autumn and winter.  相似文献   
9.
A case study on the optimization of Posidonia oceanica density interpolation, using a data set from a large meadow at Porto Conte Bay (NW Sardinia, Italy), is presented. Ordinary point kriging, cokriging and a weighted average based on inverse square distance were used to interpolate density data measured in 36 sampling stations. The results obtained from different methods were then compared by means of a leave‐one‐out cross‐validation procedure. The scale at which interpolation was carried out was defined on the basis of the Hausdorff dimension of the variogram. Optimizing spatial scale and data points search strategy allowed obtaining more accurate density estimates independently of the interpolation method.  相似文献   
10.
Abstract. Growth of the shallow-water gorgonian Lophogorgia ceratophyta was investigated in an infralittoral station located in La Spezia Gulf, Ligurian Sea. Mean annual height growth rate was estimated to be 2.57 cm · a-1. The fractal dimension of the colonies was found to gradually evolve in complexity, exhibiting a simpler branching pattern in younger specimens. The maintenance of a low, invariable ramification complexity as an optimal choice in managing relationships between water and the colony's living tissues is also discussed.  相似文献   
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