Controls of δS and δO in dissolved sulphate: Learning from a detailed survey in the Llobregat River (Spain)     

Neus Otero  Albert Soler  Àngels Canals 《Applied Geochemistry》2008

The S and O isotopic composition of dissolved SO₄, used as a tracer for SO₄ sources, was applied to the water of the Llobregat River system (NE Spain). The survey was carried out at 30 sites where surface water was sampled on a monthly basis over a period of 2a. The concentration of dissolved SO₄ varied from 20 to 1575 mg L⁻¹. Sulphur isotopic compositions clustered in two populations: one – 93% of the samples – had positive values with a mode of +9‰; the other had negative values and a mode of −5‰. Data for δ¹⁸O_SO4 showed a mean value of +11‰, with no bi-modal distribution, though lower values of δ¹⁸O corresponded to samples with negative δ³⁴S. These values can not be explained solely by the contribution of bedrock SO₄ sources: that is, sulphide oxidation and the weathering of outcrops of sulphates, though numerous chemical sediments exist in the basin. Even in a river with a high concentration of natural sources of dissolved SO₄, such as the Llobregat River, the δ³⁴S values suggest that dissolved SO₄ is controlled by a complex mix of both natural and anthropogenic sources. The main anthropogenic sources in this basin are fertilizers, sewage, potash mine effluent and power plant emissions. Detailed river water sampling, together with the chemical and isotopic characterisation of the main anthropogenic inputs, allowed determination of the influence of redox processes, as well as identification of the contribution of natural and anthropogenic SO₄ sources and detection of spatial variations and seasonal changes among these sources. For instance, in the Llobregat River the input of fertilisers is well marked seasonally. Minimum values of δ³⁴S are reported during fertilization periods – from January to March – indicating a higher contribution of this source. The dual isotope approach, δ³⁴S and δ¹⁸O, is useful to better constrain the sources of SO₄. Moreover, in small-scale studies, where the inputs are well known and limited, the mixing models can be enhanced and the contribution of the different sources can be quantified to some extent.  相似文献   

Surface-layer flow in complex terrain: Comparison of models and full-scale observations   总被引：2，自引：0，他引：2  

John L. Walmsley  Ib Troen  Demetrius P. Lalas  Paul J. Mason 《Boundary-Layer Meteorology》1990,52(3):259-281

Four models of surface boundary-layer flow in complex terrain are compared with observations made at Blashaval Hill, North Uist, Scotland. The field experiment is described by Mason and King (1985). Three of the models are derived from the two-dimensional theory of Jackson and Hunt (1975) and are described in Mason and King (1985), Walmsley et al. (1986) and Troen and Petersen (1989). The fourth is a mass-consistent code based on Traci et al. (1979). The model results are in good agreement with each other and are generally within the observed range of variation ( ~ ± 16%) in normalized wind speed. For most wind direcions (7 of 11), model results of normalized wind speed at the summit were within 7% of the observed mean values. For some wind directions, calculations using the Guidelines of Walmsley et al. (1989) suggested that variations in surface roughness were important. This led us to apply one of our models incorporating nonuniform surface roughness. The lack of significant improvement for cases when water lay upstream of Blashaval Hill is attributed to compensating changes at summit and reference sites and to very local effects on the wind data. Sensitivity to topography lying to the west and northwest of Blashaval was also investigated. Results suggested an influence from those distant topographic features for some wind directions. When those features were incorporated, maximum errors in normalized wind speed at the summit were reduced from 18 to 13%.  相似文献   

Impacts of trawling on benthic macro-fauna and -flora of the Spencer Gulf prawn fishing grounds     

Ib Svane  Zoe Hammett  Peter Lauer   《Estuarine, Coastal and Shelf Science》2009,82(4):621-631

The overall effects of trawling on benthic habitats and their assemblages are dependent on the distribution and intensity of trawl effort. The benthic habitats of the Spencer Gulf prawn trawling grounds are subjected to known variable levels of trawling disturbance recorded from fisher's logbooks. These habitats have not been quantitatively investigated. The aim of the study was firstly to characterise the macro-faunal and -floral assemblages and secondly, to comparatively assess trawl impact by testing the null hypothesis of no differences between five sites exposed to different intensity of trawl effort. The distribution and abundance of benthic macro-fauna and -flora were studied at two sampling resolutions by using beam trawl sampling (10,000 m²) and underwater stereophotography (4.5 m²) at five sites with different levels of trawl disturbance (effort). The results showed that the Spencer Gulf prawn trawling grounds are characterised by sandy sediments with a low content of silt and clay, with the exception of one site with very fine gravel. Biomass, abundance and cover of macro-fauna and -flora were generally low throughout, but with large differences among sites. Biomass, abundance and cover were found to be negatively correlated to both trawl hours from 1994–1998 and during the period of study. ANOSIM and SIMPER analyses using biomass, abundance and percentage cover as variables showed significant differences between sites with eight species or taxonomic groups contributing more than 10% to the observed similarity within sites. The two northern sites were dominated by sponges and the bearded mussel, Trichomya hirsutus, and the southern hammer oyster, Malleus meridianus. Other species that contributed to the similarity within sites were the ascidian, Polycarpa viridis, mobile epifauna (the blue swimmer crab, Portunus pelagicus, and the western king prawn, Penaeus (Melicertus) latisulcatus) and demersal fish species (Degens leatherjacket, Thamnaconus degeni, and the Melbourne silver belly, Parequula melbournensis). Simpson's Index of Diversity (1 − λ) and species richness in the beam trawl samples were fairly even across all sites, but a significant effect of site was found in the stereophotographic transect samples. It was concluded that prawn trawling has a strong influence on the structure of the benthic habitats of the Spencer Gulf prawn fishing grounds highlighted by the magnitude of change and the strength of the gradient of effects. Confounding factors linked to the biophysical attributes of the sites are believed to be minor.  相似文献   

Radio Emission from Three-dimensional Relativistic Hydrodynamic Jets: Observational Evidence of Jet Stratification     

Aloy MA  Gómez JL  Ibáñez JM  Martí JM  Müller E 《The Astrophysical journal》2000,536(2):L85-L88

High-resolution, high signal-to-noise ratio, blue-violet spectra of three red giant branch tip stars in M15 have been obtained with the Keck I High-Resolution Echelle Spectrograph. These spectra have been analyzed to determine the abundances of several neutron-capture elements, including the radioactive chronometer element thorium. There are two principal results of this study. First, the abundances of the heavier (Z>/=56) elements for each of the three stars is well matched by a scaled solar system r-process abundance distribution. Second, a weighted mean-observed Th/Eu ratio for the stars implies an age for the neutron-capture material in M15 stars of 14+/-3 Gyr, in reasonable agreement with other recent age estimates for Galactic globular clusters.  相似文献   

Numerical modelling of the potential effects of a dam on a coastal aquifer in S. Spain     

M. L. Calvache  S. Ibáñez  C. Duque  W. Martín‐Rosales  M. López‐Chicano  J. C. Rubio  A. González  C. Viseras 《水文研究》2009,23(9):1268-1281

This study presents the results of a three‐dimensional variable‐density numerical modelling of the Motril‐Salobreña coastal aquifer and the possible effects of the entry into service in May 2005 of the Rules Dam, located just 17 km from the coast. Present parameters of the Motril‐Salobreña aquifer show that the system's conditions are very similar to a natural regime. The dam will substantially alter aquifer recharge, as the entry flow through the alluvial sediments of the Guadalfeo River will be entirely cut off or drastically reduced. Different scenarios reproducing the possible evolution of the aquifer under operation of the Rules Dam have been modelled. In most cases, results indicate that the conditions of the aquifer would worsen, with a general advance of the freshwater–saltwater interface. The area with most risk of saltwater intrusion is the old mouth of the Guadalfeo River, where the mixing zone could advance 1200 m inland. It is proposed that maintaining a 5–6 Mm³ year^?1 ‘ecological flow’ in the Guadalfeo River could prevent this saline advance. This application demonstrates that variable‐density models are potentially useful tools for estimating the effects of dams on the hydrodynamic and hydrochemical conditions of a coastal aquifer. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Identification of T-Waves in the Alboran Sea     

Enrique Carmona  Javier Almendros  Gerardo Alguacil  Juan Ignacio Soto  Francisco Luzón  Jesús M. Ibáñez 《Pure and Applied Geophysics》2015,172(11):3179-3188

  相似文献   

Importance of habitat heterogeneity and biotic processes in the spatial distribution of a riparian herb (Carex remota L.): a point process approach     

J. Uria-Diez  R. Ib��?ez  J. Mateu 《Stochastic Environmental Research and Risk Assessment (SERRA)》2013,27(1):59-76

This study attempts to understand the dependence on abiotic factors and on the biotic process of the population development. We used three spatial point process models (Poisson, Area-Interaction and shot-noise Cox processes) in both homogenous and inhomogeneous versions to model the distribution of three Carex remota cohorts in wet zones of a temperate forest in the north of Spain. The cohorts studied were adults and seedlings born in two consecutive years. With the use of these models we are able to simulate separately and jointly the effect on plant distribution of a homogeneous or heterogeneous habitat, and the absence or presence of some biotic processes, as seed dispersal and/or density-dependent interactions. The result of the bivariate function analysis does not reveal sufficient evidences, but suggests a weak positive relation between adults and seedlings that survived a dry period in the first summer. Models from the three cohorts show a decreasing degree of clustering from seedlings to adults. Besides, the results show that the importance of the main factors that explain the population structure changes along the development of Carex stages. Compared to seedlings, the adults pattern shows an increasing dependence on abiotic factors.  相似文献   

Propagating of sound and thermal waves in a reacting fluid     

S. Miguel H. Ibáñez  B. César A. Mendoza 《Astrophysics and Space Science》1987,137(1):1-15

The propagation of linear sound and thermal waves in a reacting fluid, in which the heating and cooling processes can be represented by a heat-loss functionL(, T, is studied. A complex dispersion relation is found, from which the phase velocity and the scale length for damping (or amplification), of the above two-wave mode are calculated Wave amplification may occur in reacting locally stable fluids. Results are applied to a hydrogen plasma model assumed to be heated at a non-specified constant rate and cooled by recombination, excitation, and ionization by collisions, and free-free transitions. The phase velocity , the scale-length for damping , and the relevant relaxation times are calculated as functions of the dimensionless frequency , for temperatures ranging from those at which the hydrogen plasma is neutral to those at which it becomes completely ionized.  相似文献   

Size-Resolved Aerosol Characterization for a Polluted Episode at the IfT Research Station Melpitz in Autumn 1997     

A. Plewka  T. Gnauk  E. Brüggemann  C. Neusüss  H. Herrmann 《Journal of Atmospheric Chemistry》2004,48(2):131-156

Inorganic ions, organic carbon (OC), elemental carbon (EC) and a variety of organic single species in airborne particles have been determined at the research station of the Leibniz – Institut für Troposphärenforschung (IfT) in Melpitz (Germany) in autumn 1997.Samples of eight selected measurement events were divided in two groups in order to investigate differences in the chemical composition of particles originating from southwesterly (SW – developed EU countries) or from easterly directions (E – less developed eastern countries). Differences between these two groups were tested statistically by Student's t-test.Five stage cascade impactor samples show nitrate as most abundant in the accumulation mode in the SW group. EC and sulphate show the most abundant mass fractions in the E group. That can be considered as a consequence of domestic coal heating and coal-fired power plant emissions in the region of westerly Poland, northern Czech Republic and easterly Germany. Higher nitrate concentrations in the SW group can be explained by stronger NO _x emissions caused by the leeward plume of the conurbation of Leipzig, as well as by the still higher traffic density in western Germany.The methane sulphonic acid (MSA) mass fraction was higher for SW air masses in accumulation mode particles, probably indicating marine origin. Succinic acid also showed higher mass fractions for the SW group. This could be caused by primary emission in automobile exhaust gases and photochemical formation during transport from SW. Indeed, during SW sampling, solar radiation intensity was higher than during E sampling.The observed differences in the particle composition are an expression of the still existing technology gradient in Europe. Future campaigns could show the development to a joint economy with smaller differences in anthropogenic emissions.  相似文献   

Development of a system of indicators for sustainable port management   总被引：2，自引：0，他引：2  

Peris-Mora E  Diez Orejas JM  Subirats A  Ibáñez S  Alvarez P 《Marine pollution bulletin》2005,50(12):1649-1660

The 1998 project ECOPORT, “Towards A Sustainable Transport Network”, developed by the Valencia Port Authority (VPA), established the bases for implementing an Environmental Management System (EMS) in industrial harbours. The use of data and information shall always be required to develop an efficient EMS. The objective of the present research (INDAPORT) study is to propose a system of sustainable environmental management indicators to be used by any port authorities. All activities performed within a port area are analysed for any potential environmental impacts and risks.

An environmental analysis of port activities has been carried out with the objective of designing the indicators system. Twenty-one corresponding activities have been identified for large industrial ports. Subsequently, the same methodology developed to date will be later applied to other Spanish and European ports. The study has been developed by using an original system and a methodology, which simultaneously use stage diagrams and systemic models (material and energy flow charts). Multi-criteria analysis techniques were used to evaluate potential impacts (identification of factors and evaluation of impacts).  相似文献