The carbohydrates in relation to mineralogic and granulometric composition of surface sediments in the karst estuary (River Krka estuary,Yugoslavia)     

Olga Hadz̆ija  Mladen Jurac̆ić  Marija Luić  Maja Tonković  Biserka Jeric̆ević 《Estuarine, Coastal and Shelf Science》1985,21(5):701-709

The investigation of mineral, granulometric and chemical composition of sediments of the River Krka estuary (Yugoslavia) were performed in order to elucidate the origin of the sediments and the pattern of sedimentation. Estuarine surface sediments were found to be fine-grained with a bimodal distribution. Environmental conditions in estuarine sediments favour conservation of the organic matter (anoxic conditions). The carbohydrates in the sediments were investigated to determine whether they are of terrigenous or authigenous origin. Glucose, galactose, mannose, xylose, rhamnose, glucosamine and glucuronic acid were detected in the sediments. Their mutual relationship indicates a preferentially terrigenous source of sedimented organic material in estuarine sediments.  相似文献   

Biomarker distributions as indicators for the depositional environment of lacustrine sediments in the Valjevo-Mionica basin (Serbia)     

Aleksandra Šajnović  Ksenija Stojanović  Branimir Jovančićević  Olga Cvetković 《Chemie der Erde / Geochemistry》2008,68(4):395-411

In this study, the molecular composition and biomarker distribution of lacustrine sediments from Val-1 drillhole in the central zone of the western part of the Valjevo-Mionica basin were investigated at depth interval of 0–400 m. Former investigations have shown that the core material can be separated into six depth intervals based on bulk geochemical, mineralogical and sedimentological characteristics. Concerning the quality of organic matter, presence of specific minerals, and high salinity and anoxicity, or alkalinity, three zones are of highest interest, defined at depth intervals of 15–75 m (A), 75–200 m (B) and 360–400 m (F). The first aim of the study was to identify which biomarkers characterize these specific intervals. The second aim, addressing the transitions zones of these intervals, was to extend the changes in the characteristics of the organic substance, to reflect the changes of conditions in the depositional environment as well as to define biomarker parameters which are the most sensitive sedimentological indicators.The sediments from the hypersaline anoxic and alkaline environment show high contribution of algal precursor biomass, what is in accordance with the good quality of organic substances in the sediments from these zones. High squalane content and low content of regular isoprenoid C₂₅ are typical for hypersaline anoxic environment, whereas sediments from alkaline environment have high regular isoprenoid C₂₅ content.Transition to specific sedimentation zones is characterized by change in total organic matter content, and of both free and pyrolysis-derived, and change in hydrogen index value. In the biomarker distributions, more significant changes were detected in distributions of n-alkanes and isoprenoids, compared to polycyclic alkanes. The most intensive changes in alkane distribution are reflected in changes in n-C₁₇ content compared to n-C₂₇, and phytane compared to n-C₁₈. In addition, significant sensitivity was seen in ratios between squalane and n-alkane C₂₆ (hypersaline depositional environment), or isoprenoid C₂₅ and n-alkane C₂₂ for high alkalinity environment.This study showed that Sq/n-C₂₆ ratio can be used to assess the quality of organic substance in immature lacustrine sediments.  相似文献   

Reaction mechanism of uranyl in the presence of zero-valent iron nanoparticles     

Olga Riba  Thomas B. Scott  Geoffrey C. Allen 《Geochimica et cosmochimica acta》2008,72(16):4047-4057

The current study provides an investigation of abiotic reduction of an oversaturated uranyl solution driven by iron nanoparticle oxidation. The reactivity of nano-scale zero-valent iron (ZVI) under mildly oxic conditions (1.2% O₂ and 0.0017% CO₂) was studied in 1000 ppm uranyl solution in the pH range 3-7, at reaction times from 10 min to 4 h. Reductive precipitation of UO₂ was observed as the main process responsible for the removal of uranium from solution with the kinetics of reaction becoming increasingly favourable at higher pH. Despite working with an oversaturated uranium solution, the precipitation of UO₂ occurred in preference to precipitation of UO₃·2H₂O (metaschoepite) at reaction times between 1 and 4 h and for uranyl solutions initially set up at pH ?5. Characterisation of both solid and solution phases was performed using X-ray photoelectron spectroscopy (XPS), focused ion beam (FIB) imaging, X-ray diffraction (XRD) and inductively coupled plasma atomic emission spectroscopy (ICP-AES).  相似文献   

An aromatase inhibitor and tamoxifen decrease plasma levels of o,p'-DDT and its metabolites in Nile tilapia (Oreochromis niloticus)     

Leaños-Castañeda O  Gold-Bouchot G  Van Der Kraak G  Lister A  Ceja-Moreno V  Simá-Alvarez R 《Marine environmental research》2004,58(2-5):337-342

The objective of this study was to determine if tamoxifen or an aromatase inhibitor (4-hydroxyandrostenedione; 4-OHA) affected plasma concentrations of o,p' -DDT and its metabolites, o,p'-DDD and o,p'-DDE, in mature tilapia. Male and female tilapia were injected 6 times intraperitoneally with o,p'-DDT (40 mg/kg) alone or in combination with 4-OHA (2 mg/kg) over a 12 day period. An additional group of male fish was injected with tamoxifen (5 mg/kg) plus o,p'-DDT. At the end of the treatment period, plasma samples were extracted and analyzed by GC/ECD. Females injected only with o,p'-DDT had significantly higher levels of o,p'-DDT compared with males. Interestingly, females and males treated concomitantly with o,p'-DDT and 4-OHA or tamoxifen had significantly lower concentrations of plasma o,p'-DDT (about 50%) compared with fish treated with only o,p'-DDT. These initial results suggest that an interaction between endocrine-active compounds occurs in vivo in tilapia and may involve alterations in metabolism of o,p'-DDT.  相似文献   

Dynamics of climate extremes in northern Eurasia in the late 20th century     

A. B. Shmakin  V. V. Popova 《Izvestiya Atmospheric and Oceanic Physics》2006,42(2):138-147

Changes in climatic parameters and in temperature and precipitation extremes in northern Eurasia in the late 20th century are analyzed. A spatial distribution of temperature and precipitation anomalies and of a set of indices of climate extremes is presented. Changes in climate extremes show a tendency toward a milder climate, mainly in winter. At the same time, the frost-free period has substantially decreased in the eastern, northern, and central parts of European Russia. In some regions during summer, there is an increase in the frequency of extreme events such as heavy rains, droughts, and sharp cooling. It is shown that the geographic pattern of present-day climate anomalies is linked to variations in the large-scale atmospheric circulation. The main mechanism of the current warming in northern Eurasia is a winter intensification of zonal flow linked to the increased frequency of positive anomalies of the North Atlantic Oscillation index.  相似文献   

Composition and distribution of meiobenthos in amursky bay (peter the great bay, the east sea)     

Olga N. Pavlyuk  Julia A. Trebukhova 《Ocean Science Journal》2005,40(3):10-16

Qualitative and quantitative composition of meiobenthos was studied in Amursky Bay (Peter the Great Bay, the East Sea). Ten taxonomic groups were found, where nematodes were dominant. Density of meiobenthos in ground sediments of the Bay were not uniform, and the average density was measured at 126.4±62.3 ind. m^-2. 56 species of nematodes were detected, and dominant species wereSabatieria palmaris, Paracanthonchus macrodon, Sphaerolaimus limosus, S. gracilis andOncholaimium ramosum. Five taxocenes of nematodes were allocated based on the results of cluster analysis and species domination according to density. Low diversity in species composition of nematodes was noted in the northwestern part of the Bay, which is a zone of desalination, and in the eastern part, which is exposed to household drains.  相似文献   

On the influence of mass loss and convective overshooting on the evolution of massive stars     

A. G. Massevitch  E. I. Popova  A. V. Tutukov  L. R. Yungelson 《Astrophysics and Space Science》1979,62(2):451-463

Evolution of massive stars losing mass with the rateM H L/V C is computed (for =1,2,7). It is shown that observed mass loss rates correspond to 0.3 and, therefore, mass loss by stellar wind cannot play any significant role in the evolution of normal massive stars. However, for several types of massive stars (WR, OH/IR, X-ray sources) enhanced mass loss explains their peculiar features. Computations of evolutionary sequences of massive stars with convective overshooting taken into account (as a formal increase of the convective core) show that a significant broadening of the hydrogen-burning band in the H-R diagram may be obtained.  相似文献   

Study of physical properties of spectroscopic binary stars     

E. I. Popova  A. V. Tutukov  L. R. Yungelson 《Astrophysics and Space Science》1982,88(1):55-80

The main results of a study of a catalogue of physical parameters of 1041 spectroscopic binaries are presented. The distribution of spectroscopic binaries over all main parametersM ₁, a, e, M₁/M₂, P, and certain dependencies between some of them have been found.

1. It appears that among bright (m _v?3 ^m –5 ^m ) stars withM?1M _⊙, about 40% are apparently spectroscopic binaries with comparable masses of components.
2. The majority of spectroscopic binaries with the ratio of the large semiaxis of the orbit to the radius of the primarya/R ₁?20, have eccentricities close to zero. This is probably a consequence of the tidal circularization of orbits of close binaries by viscous friction.
3. The discovery of duplicity of double-line spectroscopic binaries is possible only if the semiamplitude of radial velocityK ₁ is almost 10 times higher than the semiamplitude of the radial velocity of a single-line spectroscopic binary of the same mass.
4. Double-line spectroscopic binaries witha/R _⊙?6(M ₁/M _⊙)^1/3,M ₁≈M ₂?1.5M _⊙ are almost almost absent, and the number of stars witha/R _⊙?6(M ₁/M _⊙)^1/3,M ₁≈1.5M _⊙ is relatively low.
5. The distribution of unevolved SB stars over the large semiaxis may be described by the expression d(N _d/N_t)≈0.2 d loga for 6(M ₁/M _⊙)^1/3?a/R _⊙?100.
6. The intial mass-function for primaries of spectroscopic binaries is the same Salpeter function dN _d≈M ₁ ^?2.35 dM ₁ for 1?M ₁/M _⊙?30.
7. It is possible to explain the observed ratio of the number of single-line spectroscopic binaries to the number of double-line binaries if one assumes that the average initial mass ratio is close to 1 and that the mass of the postmass-exchange remnant of the primary exceeds the theoretical one and/or that half of the angular momentum of the system is lost during mass-exchange.
8. The above-mentioned distributions ofM ₁ anda and assumptions on the mass of remnant and/or momentum loss also allow us to explain the observed shapes of dN/dM, dN/dq, and dN/da distributions after some selection effects are taken into account.

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Mudstone lithogeochemistry and formation conditions of Vendian deposits in the Shkapovo-Shikhan Basin     

A. V. Maslov  M. V. Isherskaya  Yu. L. Ronkin  M. T. Krupenin  N. P. Gorbunova  T. Ya. Gulyaeva  O. P. Lepikhina  O. Yu. Popova  G. M. Yatluk 《Lithology and Mineral Resources》2006,41(3):250-270

Variation of geochemical modules and indices in mudstones from the Upper Vendian Kairovo and Shkapovo groups of the Shkapovo-Shikhan Basin provides the comprehensive information on changes in maturity of the fine aluminosiliciclastic material delivered in the basin, characterizes the redox environment in bottom water, and makes it possible to reconstruct the rock composition in provenance and its evolution through time. The generally moderate maturity of the fine terrigenous clastic material suggests that a nearly semiarid-semihumid climate dominated in paleodrainage area throughout the Late Vendian. It has been established that reducing environment did not exist in bottom water of the central Shkapovo-Shikhan Basin throughout the Late Vendian. Intermediate rocks prevailed in the paleodrainage area. More silicic rocks could occur only in the early Staropetrovo and late Salikhovo times. Data points of mudstones from the Kairovo and Shkapovo Groups plotted on the Cr-Ni, Co-V, Co/Hf-Ce/Cr, La-Th, and La/Sm-Sc/Th diagrams indicate that both Archean and more mature Paleoproterozoic crustal blocks existed in different proportions in the Late Vendian within source areas.  相似文献   

A millennial-scale record of Holocene tsunamis on the Kronotskiy Bay coast, Kamchatka, Russia     

Tatiana K PineginaJoanne Bourgeois  Lilia I BazanovaIvan V Melekestsev  Olga A Braitseva 《Quaternary Research》2003,59(1):36-47

Deposits from as many as 50 large tsunamis during the last 7000 years are preserved on the Pacific coast of the Kamchatka Peninsula near the mouth of the Zhupanova River, southern Kronotskiy Bay. These deposits are dated and correlated using Holocene marker tephra layers. The combined, preserved record of tsunami deposits and of numerous marker tephras on Kamchatka offers an unprecedented opportunity to study tsunami frequency. For example, from the stratigraphy along southern Kronotskiy Bay, we estimate frequency of large tsunamis (>5 m runup). In the last 3000 years, the minimum frequency is about one large tsunami per 100 years, and the maximum about one large tsunami per 30 years; the latter frequency occurred from about 0 to 1000 A.D. This time interval corresponds to a period of increased seismicity and volcanic activity that appears to be recorded in many places on the Kamchatka Peninsula.  相似文献