Age and depositional environment of the Draa Sfar massive sulfide deposit, Morocco     

C. Moreno  R. Sáez  F. González  G. Almodóvar  M. Toscano  G. Playford  A. Alansari  S. Rziki  A. Bajddi 《Mineralium Deposita》2008,43(8):891-911

The Draa Sfar mineralization consists of two main stratabound orebodies, Sidi M’Barek and Tazacourt, located north and south of the Tensift River (“Oued Tessift”), respectively. Each orebody is comprised by at least two massive sulfide lenses. The hosting rocks are predominantly black shales, although minor rhyolitic rocks are also present in the footwall to the southern orebody. Shales, rhyolitic volcanic rocks, and massive sulfides are all included into the Sarhlef Series, which is recognized as one of the main stratigraphic units of the Moroccan Variscan Meseta. Hydrothermal activity related with an anomalous thermal gradient, together with a high sedimentation rate in a tectonically driven pull-apart marine basin, favored the accumulation of organic-rich mud in the deepest parts of the basin and the sedimentary environment suitable for massive sulfide deposition and preservation. This took place by replacement of the hosting unlithified wet mud below the sediment–water interface. Geochemical data suggest a sedimentary environment characterized by oxic water column and anoxic sediment pile with the redox boundary below the sediment–water interface. The low oxygen availability within the sediment pile inhibited oxidation and pyritization of pyrrhotite. Biostratigraphic analysis, based on the palynological content of the hosting black shales, restricts the age of the sulfides to the Asbian substage (mid-Mississippian). This age is consistent with earlier geochronological constraints.  相似文献   

Impact evaluation on groundwater of the infiltration of an urban wastewater geopurification system placed over a detrital aquifer in a semiarid region (Spain)     

L. Moreno  J. J. Durán  M. A. Casermeiro  J. R. Quintana  Ma A. Fernández 《Environmental Geology》2008,54(3):465-477

Over a period of 4 years and 4 months, the geopurification installations at Dehesas de Guadix (Granada, Spain) were monitored to determine the impact on soil and groundwater of the controlled discharge of urban wastewater, and also to identify the best indicators of the entry of the recharged water into the aquifer. The installations are located in an area where the climate is Mediterranean sub-arid, with an average precipitation of less than 287 mm/year, and a rate of evapotranspiration that is almost three times greater. The system was controlled by determining the balance of majority nutrients and boron in the soil and in the groundwater, both at the points affected directly by the wastewater discharge and at others. The quantity of mass discharged was relatively large (COD 14,656 g/m², NO₃ 85 g/m², NO₂ 4 g/m², NH₄ 2,425 g/m², PO₄ 1,143 g/m², K 1,531 g/m², B 63 g/m²). It was observed that the elimination of nutrients within the soil (COD 97.5%, PO₄ 94.4%, K 59.17%, N _total 18.8%, B 12.69%) was very efficient except for the nitrogen, which nevertheless did not reach the groundwater, as it was eliminated at deep levels of the unsaturated zone. Only 12.69% of the boron was removed, and appreciable, increasing amounts of this element did reach the groundwater. Unexpectedly, none of the majority nutrients behaved as a reliable indicator of the impact on groundwater; despite this, the boron and the bicarbonate did clearly reflect the arrival of the recharged water, and are proposed as the best indicators.  相似文献   

Intercomparison of coastal area morphodynamic models     

J. Nicholson  I. Broker  J. A. Roelvink  D. Price  J. M. Tanguy  L. Moreno 《Coastal Engineering》1997,31(1-4)

Five different coastal area morphodynamic models have been set up to run on the same offshore breakwater layout and an intercomparison carried out on the hydrodynamic and morphodynamic output produced by each scheme. In addition, the predicted morphodynamics was checked against available laboratory and field data.It is concluded that the models are capable of producing realistic estimates for the dominant morphodynamic features associated with offshore breakwaters. Coupling of the wave, current and sediment transport components of each scheme is shown to yield bathymetry which attains a state of equilibrium, unlike models which are based on the initial transport field only.  相似文献   

Spatially resolved spectroscopic observations of Jupiter during the 1987 opposition     

F. Moreno  A. Molina 《Earth, Moon, and Planets》1989,46(3):207-219

Spectroscopic observations in the spectral region 6000–6600 » of major belts and zones of Jupiter have been carried out at Calar Alto Observatory (Spain) during the 1987 opposition, in support to the International Jupiter Watch Program. More than a hundred long-slit, medium resolution spectra have been taken at the coudé focus of the 1.52 m telescope. The longitudinal and latitudinal distribution of the equivalent widths of the methane and ammonia absorption bands at 6190 » and 6450 » have been investigated. Unlike the CH₄-6190 » band, the longitudinal distribution in the NH₃-6450 » band shows asymmetries in some of the Jovian regions analyzed, being the absorption greater at West than at East limbs. These results are interpreted in terms of inhomogeneous scattering models by the simultaneous variation of the NH₃ cloud optical thickness and its altitude level. The north-south scans show little latitudinal dependence on absorption in both methane and ammonia bands, although some relationship could be established between the absorption and relative continuum reflectivity variation.

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Resumen Se presentan los resultados obtenidos de las observaciones espectroscópicas de las principales zonas y cinturones de Júpiter realizadas durante la oposición de 1987 como una contribución al International Jupiter Watch Program. Las observaciones fueron llevadas a cabo haciendo uso del foco coudé del telescopio de 1.52 m del observatorio hispanoalemán de Calar Alto (España), habiéndose obtenido algo más de cien espectros, de resolución media, en la región espectral de 6000–6600 ». Se exponen los resultados de las anchuras equivalentes de las bandas de absorción del metano en 6190 » y del amoniaco en 6450 », estudiándose, al mismo tiempo, la distribución tanto longitudinal como latitudinal de las mismas. Mientras que los resultados para la banda del metano presentan un comportamiento simétrico en todas las regiones analizadas, las anchuras equivalentes para la banda NH₃-6450 » presentan un comportamiento asimétrico en algunas regiones del planeta, con una mayor absorción hacia el limbo del oeste que hacia el del este. Los resultados son interpretados en base a un modelo de scattering no homogéneo, variando, simultáneamente, el espesor óptico y la altitud de la nube de amoniaco. Los espectros tomados en la dirección norte-sur, aunque presentan una dependencia latitudinal pequeña en la absorción de las bandas mencionadas, sugieren una relación entre la absorción y las variaciones de reflectividad en el continuo.

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Also at Departamento de Física Aplicada, Facultad de Ciencias, Universidad de Granada, Campus Universitario Fuentenueva, Granada, Spain.  相似文献   

Iron(II) oxide determination in rocks and minerals     

Sandra Andrade  Raphael HypolitoHorstpeter H.G.J. Ulbrich  Marinês L. Silva 《Chemical Geology》2002,182(1):85-89

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.  相似文献   

An automated salt‐tracing gauge for flow‐velocity measurement     

Olivier Planchon  Norbert Silvera  Raphael Gimenez  David Favis‐Mortlock  John Wainwright  Yves Le Bissonnais  Gerard Govers 《地球表面变化过程与地形》2005,30(7):833-844

This article introduces the SVG (salt‐velocity gauge), a novel automated technique for measuring flow velocity by means of salt tracing. SVG allows a high measuring rate (up to one every 2 seconds), short control section length (down to 10 cm), high accuracy (+[sol ]?1·5 cm s^?1), and unbiased calculation of the mean velocity in experimental conditions with turbulent, supercritical flow. A few cubic centimetres of saturated salt solution (NaCl) are injected into the flow at regular time intervals using a programmable solenoid valve. The tracer successively passes two conductivity probes placed a short distance downstream. The transformation of the signal between the two probes is modelled as a one‐dimensional diffusion wave equation. Model calibration gives an estimation of the mean velocity and the diffusion for each salt plume. Two implementations of the SVG technique are described. The first was an outdoors simulated rainfall experiment in Senegal (conductivity probes at 40 cm apart, 8 Hz measurement rate, salt injections at 10 second intervals). Mean velocity was estimated to range between 0·1 and 0·3 m s^?1. The second was a laboratory‐based flume experiment (conductivity probes at 10 cm apart, 32 Hz, salt injections at 2 second intervals). Another SVG with probes at 34 cm apart was used for comparison. An acoustic Doppler velocimeter (ADV) was also used to give an independent assessment of velocity. Using the 10 cm salt gauge, estimated mean velocity ranged from 0·6 to 0·9 m s^?1 with a standard deviation of 1·5 cm s^?1. Comparisons between ADV, 10 cm SVG and 34 cm SVG were consistent and demonstrated that the salt‐tracing results were unbiased and independent of distance between probes. Most peaks were modelled with r² > 90 per cent. The SVG technology offers an alternative to the dye‐tracing technique, which has been severely criticized in the literature because of the wide interval of recommended values for the correction factor α to be applied to the timings. This article demonstrates that a fixed value of α is inappropriate, since the correction factor varies with velocity, diffusion and the length of the control section. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Vegetation and climate changes in northwestern Russia during the Lateglacial and Holocene inferred from the Lake Ladoga pollen record     

Larisa A. Savelieva  Andrei A. Andreev  Raphael Gromig  Dmitry A. Subetto  Grigory B. Fedorov  Volker Wennrich  Bernd Wagner  Martin Melles 《Boreas: An International Journal of Quaternary Research》2019,48(2):349-360

The new pollen record from the upper 12.75 m of a sediment core obtained in Lake Ladoga documents regional vegetation and climate changes in northwestern Russia over the last 13.9 cal. ka. The Lateglacial chronostratigraphy is based on varve chronology, while the Holocene stratigraphy is based on AMS ¹⁴C and OSL dates, supported by comparison with regional pollen records. During the Lateglacial (c. 13.9–11.2 cal. ka BP), the Lake Ladoga region experienced several climatic fluctuations as reflected in vegetation changes. Shrub and grass communities dominated between c. 13.9 and 13.2 cal. ka BP. The increase in Picea pollen at c. 13.2 cal. ka BP probably reflects the appearance of spruce in the southern Ladoga region at the beginning of the Allerød interstadial. After c. 12.6 cal. ka BP, the Younger Dryas cooling caused a significant decrease in spruce and increase in Artemisia with other herbs, indicative of tundra‐ and steppe‐like vegetation. A sharp transition from tundra‐steppe habitats to sparse birch forests characterizes the onset of Holocene warming c. 11.2 cal. ka BP. Pine forests dominated in the region from c. 9.0 to 8.1 cal. ka BP. The most favourable climatic conditions for deciduous broad‐leaved taxa existed between c. 8.1 and 5.5 cal. ka BP. Alder experiences an abrupt increase in the local vegetation c. 7.8 cal. ka BP. The decrease in tree pollen taxa (especially Picea) and the increase in herbs (mainly Poaceae) probably reflect human activity during the last 2.2 cal. ka. Pine forests have dominated the region since that time. Secale and other Cerealia pollen as well as ruderal herbs are permanently recorded since c. 0.8 cal. ka BP.  相似文献   

Bismuth‐melt trails trapped in cassiterite–quartz veins     

Frederico Sousa Guimares  Alexandre Raphael Cabral  Bernd Lehmann  Francisco Javier Rios  Moiss Augusto Bacellar vila  Marco Paulo de Castro  Glucia Nascimento Queiroga 《地学学报》2019,31(4):358-365

Native bismuth in the form of metallic melt has been considered instrumental to the formation of some metallic ore deposits via a mechanism dubbed the “Liquid Bismuth Collector Model.” Here, we provide petrographical documentation of trail‐forming, μm‐sized blebs of native bismuth in cassiterite–quartz veins from the Santa Bárbara greisen Sn deposit in the Rondônia tin province of northern Brazil. These inclusions suggest the trapping of a Bi melt that took place during vein formation, in a mechanism similar to the entrapment of fluid inclusions.  相似文献   

Stratigraphic modelling of platform architecture and carbonate production: a Messinian case study (Sorbas Basin,SE Spain)          下载免费PDF全文

Christophe Kolodka  Emmanuelle Vennin  Raphael Bourillot  Didier Granjeon  Guy Desaubliaux 《Basin Research》2016,28(5):658-684

The late Messinian mixed carbonate‐siliciclastic platforms of the Sorbas Basin, known as the Terminal Carbonate Complex, record significant changes in carbonate production and geometry. Their facies and stratigraphic architecture result from complex interactions between base‐level fluctuations, evaporite deformation/dissolution and detrital inputs. A 3D quantitative approach (with DIONISOS software) is used to explore the basin‐scale platform architecture and to quantify the carbonate production of the Terminal Carbonate Complex. The modelling strategy consists in integrating detailed 2D field‐based transects and modern carbonate system parameters (e.g. carbonate production rates, bathymetric and hydrodynamic ranges of production). This approach limits user impact and so provides more objective output results. Tests are carried out on carbonate production rates, subsidence and evaporite deformation/dissolution. Numerical modelling provides accurate predictions of geometries, facies distributions and depositional sequence thicknesses, validated by field data. Comparative statistical testing of the field transects and of the various model outputs are used to discern the relative contribution of the parameters tested to the evolution of basin filling. The 3D visualization and quantification of the main carbonate producers (ooids and microbialites) are discussed in terms of changes in base‐level and detrital supply. This study demonstrates that base‐level fluctuations have the greatest impact on the carbonate budget. Evaporite deformation/dissolution affects the type and amount of carbonate production, inducing a transition from an ooid‐ to microbialite‐dominated system and also has a major effect on stratigraphic architecture by inducing the migration of depocentres. The numerical modelling results obtained using modern carbonate system parameters could also be applied to subsurface ooid‐microbialite reservoirs, and the Terminal Carbonate Complex is a good analogue for such systems.  相似文献   

The last deglaciation in the Picos de Europa National Park (Cantabrian Mountains,northern Spain)     

Ana Moreno  Blas L. Valero‐Garcés  Montserrat Jiménez‐Sánchez  María José Domínguez‐Cuesta  M. Pilar Mata  Ana Navas  Penélope González‐Sampériz  Heather Stoll  Pedro Farias  Mario Morellón  J. Pablo Corella  Mayte Rico 《第四纪科学杂志》2010,25(7):1076-1091

A sedimentological and geochemical study of the Lago Enol sequence (Cantabrian Mountains, northern Spain), together with detailed geomorphological mapping, provides a first record of glacier evolution and climate change over the last 40 ka in the Picos de Europa National Park. The Enol glacier retreated from its maximum extent prior to 40 ka BP as demonstrated by the onset of proglacial lacustrine sedimentation in two glaciated depressions: the Comella hollow to the north (before 40 ka BP) and the Lago Enol (before 38 ka BP). These results support previous evidence that the maximum extent of southern European glaciers occurred earlier than in northern Europe. Alternation of homogeneous and laminated proglacial sediments during the glacier retreat illustrate a dynamic glacial evolution during the Marine Isotope Stage (MIS) 3 (40–26 ka BP). A slight warming is detected at 26 ka ago with the change from proglacial sediments (in a lake located in contact to the glacier) to glaciolacustrine sedimentation (in a non‐contact or distal lake). Finally, the onset of organic‐rich sediments took place at 18 ka ago. This last transition occurred in two phases, similarly to the North Atlantic Last Termination, suggesting a link between North Atlantic Deep Water formation oscillations and palaeohydrological variability in the Cantabrian Mountains. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献