High-resolution observations of a complete sample of 27 FR II radio galaxies and quasars with 0.3 < z < 0.6     

G. M. Gilbert  J. M. Riley  M. J. Hardcastle  J. H. Croston  G. G. Pooley  P. Alexander 《Monthly notices of the Royal Astronomical Society》2004,351(3):845-890

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The estimation of acid dissociation constants in seawater media from potentionmetric titrations with strong base. I. The ionic product of water — Kw     

A.G Dickson  J.P Riley 《Marine Chemistry》1979,7(2):89-99

The various assumptions implicit in the calculation of acid dissociation constants (based on ionic medium standard states) from potentiometric titrations using a cell with liquid junction (i.e. a pH measuring cell) have been examined. It was concluded that results can be obtained having an accuracy commensurate with the experimental precision. It has been shown that although the precise composition of the medium is a function of the hydrogen ion concentration (because of the protolytic nature of some of the ions in the media, e.g., sulphate and fluoride), the effect of such variations in the medium composition can be compensated for when defining the activity of hydrogen ion on an ionic medium standard state by defining the concentration of hydrogen ion as: where β_HSO4 and β_HF are the relevant association constants and S_T and F_T are the total concentrations of sulphate and fluoride, respectively.This approach was used to obtain values for the ionic product of water (K_W) in artificial seawater media at various temperatures and ionic strengths. These were fitted to give the equation (molal concentration units): where I is the formal ionic strength of the artificial seawater medium and T is the absolute temperature. The values obtained are in reasonable agreement with those found by previous workers.  相似文献   

The dissolution of opaline silica of diatom tests in sea water   总被引：3，自引：0，他引：3  

Akiyoshi Kamatani  John P. Riley  Geoffrey Skirrow 《Journal of Oceanography》1980,36(4):201-208

Two different series of measurements have been made of the solubilities and rates of solution in sea water of acid-washed siliceous tests of the diatomsThalassiosira decipiens andRhizosolenia hebetata. The kinetic approach was carried out on the assumption that the tests behave as identical solid spheres. If the tests were present in considerable excess over that required for saturation of the water with respect to silica, the dissolution obeyed first order reaction kinetics and its rate was proportional to the surface area of the exposed tests. When the tests were not in excess the kinetics of dissolution appeared to be more complex. This was considered to be due to a decrease in specific surface area as dissolution proceeded. An expression developed to allow for the change of surface area as a sphere dissolves offers a partial explanation of the kinetics when the tests are not present in excess.  相似文献   

Kinetic studies of the rate of dissolution of silica and diatom tests in sea water     

Lucinda M. L. Hubbard  John P. Riley 《Journal of Oceanography》1984,40(2):148-154

Kinetic studies have been carried out on the dissolution of 10μm beads of silica and of the siliceous tests of two species of diatoms (Thalassiosira fluviatus andSkeletonema costatum) in sea water at 10–50°C and over the pH range 6–9. At all temperatures dissolution of the biogenous silica occurred most rapidly at pH 8 and most slowly at pH 6. First order kinetics were closely followed when the silica was present in a considerable excess over that required for saturation, the rate being proportional to the area of the silica. Apparent deviation from this type of kinetics occurred when there was insufficient silica to bring about saturation. This was undoubtedly due to the progressive decrease in the surface area which takes place as the particle dissolves. Application of the rather simplistic model developed by Kamataniet al. (1980), which makes allowance for this decrease, gave a close correspondence with the data until ∼ 90% of the silica had dissolved.  相似文献   

A method of alternating characteristics with application to advection-dominated environmental systems     

Katerina Georgiou  John Harte  Ali Mesbah  William J. Riley 《Computational Geosciences》2018,22(3):851-865

We present a numerical method for solving a class of systems of partial differential equations (PDEs) that arises in modeling environmental processes undergoing advection and biogeochemical reactions. The salient feature of these PDEs is that all partial derivatives appear in linear expressions. As a result, the system can be viewed as a set of ordinary differential equations (ODEs), albeit each one along a different characteristic. The method then consists of alternating between equations and integrating each one step-wise along its own characteristic, thus creating a customized grid on which solutions are computed. Since the solutions of such PDEs are generally smoother along their characteristics, the method offers the potential of using larger time steps while maintaining accuracy and reducing numerical dispersion. The advantages in efficiency and accuracy of the proposed method are demonstrated in two illustrative examples that simulate depth-resolved reactive transport and soil carbon cycling.  相似文献   

Regional subglacial quarrying and abrasion below hard-bedded palaeo-ice streams crossing the Shield–Palaeozoic boundary of central Canada: the importance of substrate control     

Syed Bukhari  Nick Eyles  Shane Sookhan  Riley Mulligan  Roger Paulen  Maarten Krabbendam  Niko Putkinen 《Boreas: An International Journal of Quaternary Research》2021,50(3):781-805

Three-dimensional surface visualization models derived from high-resolution LiDAR data provide new information about the type and scale of erosional processes below Late Wisconsin palaeo-ice streams traversing the boundary between Canadian Shield crystalline rocks with offlapping Palaeozoic limestones in central Ontario. The hard bed is directly analogous to that found below ice streams in East Antarctica and East Greenland and provides insight into the effects of abrupt changes in substrate type on subglacial processes. Erosion of hard crystalline Canadian Shield rock was largely ineffectual consisting of areal abrasion of rounded whalebacks and local lee side plucking. In contrast, fast flow over the strike of gently dipping well-bedded and jointed Palaeozoic limestones cut large flow-parallel grooves and ridges akin to mega-scale glacial lineations reflecting intense abrasion below narrow streams of subglacial debris dominated by hard crystalline Shield clasts (erodents). Regionally extensive plucking of structurally weak, well-jointed and bedded limestone produced large volumes of rubbly carbonate debris leaving a 25-km-wide belt of uncontrolled hummocky rubble terrain (long known as the Dummer Moraine in Southern Ontario) some 350 km long and locally as much as 10 m thick. Subglacial plucking and abrasion under fast flowing ice were highly effective in stripping limestone cover rocks from Precambrian basement, and over many glacial cycles, may have played a role in the location and excavation of numerous large and deep lake basins around the Shield–Palaeozoic boundary zone in North America.  相似文献   

A 408-MHz variability study of two fields in the region 6^h30^m, +45°     

J. M. Riley  & D. A. Green 《Monthly notices of the Royal Astronomical Society》1998,301(1):203-209

Variability in 408-MHz flux density, over a 1-yr interval between 1995 and 1996, has been investigated using the DRAO Synthesis Telescope for a complete sample of 322 sources with S _408 MHz > 80 mJy at galactic latitude b  = 15°; four sources are found to show significant flux density variations. These results, taken with those from a similar study at b  = 58°, indicate that 408-MHz variability over a time-scale of 1 yr is more uncommon than has previously been thought; variations at a level >10 per cent could have been detected in a statistically complete sample of about 150 of these sources and none was found. Variability over a period of 18 yr has also been investigated by comparing the DRAO data with those from the B3 catalogue for 182 sources with S _408 MHz > 200 mJy; five variables are found. Large flux density variations over a period of 18 yr are much more common than over 1 yr, with roughly one source in 15 showing variations at the 15 per cent level or greater. The statistics are not good enough to show any conclusive evidence for a dependence of variability on galactic latitude. Roughly half of the variable sources have spectra that are steep at high frequencies and flatten at low frequencies; the other half have flat radio spectra over the entire frequency range. Simultaneous observations at 1420 MHz, also with the DRAO Synthesis Telescope, have been used to investigate variability at this frequency as well, and indicate that over a period of 1 yr roughly half of the flat-spectrum sources vary at the 5 per cent level or greater.  相似文献   

Comparison of Observations at ACE and <Emphasis Type="Italic">Ulysses</Emphasis> with Enlil Model Results: Stream Interaction Regions During Carrington Rotations 2016 – 2018     

L. K. Jian  C. T. Russell  J. G. Luhmann  P. J. MacNeice  D. Odstrcil  P. Riley  J. A. Linker  R. M. Skoug  J. T. Steinberg 《Solar physics》2011,273(1):179-203

During the latitudinal alignment in 2004, ACE and Ulysses encountered two stream interaction regions (SIRs) each Carrington rotation from 2016 to 2018, at 1 and 5.4 AU, respectively. More SIR-driven shocks were observed at 5.4 AU than at 1 AU. Three small SIRs at 1 AU merged to form a strong SIR at 5.4 AU. We compare the Enlil model results with spacecraft observations from four aspects: i) the accuracy of the latest versions of models (WSA v2.2 and Enlil v2.7) vs. old versions (WSA v1.6 and Enlil v2.6), ii) the sensitivity to different solar magnetograms (MWO vs. NSO), iii) the sensitivity to different coronal models (WSA vs. MAS), iv) the predictive capability at 1 AU vs. 5.4 AU. We find the models can capture field sector boundaries with some time offset. Although the new versions have improved the SIR timing prediction, the time offset can be up to two days at 1 AU and four days at 5.4 AU. The models cannot capture some small-scale structures, including shocks and small SIRs at 1 AU. For SIRs, the temperature and total pressure are often underestimated, while the density compression is overestimated. For slow wind, the density is usually overestimated, while the temperature, magnetic field, and total pressure are often underestimated. The new versions have improved the prediction of the speed and density, but they need more robust scaling factors for magnetic field. The Enlil model results are very sensitive to different solar magnetograms and coronal models. It is hard to determine which magnetogram-coronal model combination is superior to others. Higher-resolution solar and coronal observations, a mission closer to the Sun, together with simulations of greater resolution and added physics, are ways to make progress for the solar wind modeling.  相似文献   

From the Sun to the Earth: The 13 May 2005 Coronal Mass Ejection     

M. M. Bisi  A. R. Breen  B. V. Jackson  R. A. Fallows  A. P. Walsh  Z. Mikić  P. Riley  C. J. Owen  A. Gonzalez-Esparza  E. Aguilar-Rodriguez  H. Morgan  E. A. Jensen  A. G. Wood  M. J. Owens  M. Tokumaru  P. K. Manoharan  I. V. Chashei  A. S. Giunta  J. A. Linker  V. I. Shishov  S. A. Tyul’bashev  G. Agalya  S. K. Glubokova  M. S. Hamilton  K. Fujiki  P. P. Hick  J. M. Clover  B. Pintér 《Solar physics》2010,265(1-2):49-127

We report the results of a multi-instrument, multi-technique, coordinated study of the solar eruptive event of 13 May 2005. We discuss the resultant Earth-directed (halo) coronal mass ejection (CME), and the effects on the terrestrial space environment and upper Earth atmosphere. The interplanetary CME (ICME) impacted the Earth’s magnetosphere and caused the most-intense geomagnetic storm of 2005 with a Disturbed Storm Time (Dst) index reaching ?263 nT at its peak. The terrestrial environment responded to the storm on a global scale. We have combined observations and measurements from coronal and interplanetary remote-sensing instruments, interplanetary and near-Earth in-situ measurements, remote-sensing observations and in-situ measurements of the terrestrial magnetosphere and ionosphere, along with coronal and heliospheric modelling. These analyses are used to trace the origin, development, propagation, terrestrial impact, and subsequent consequences of this event to obtain the most comprehensive view of a geo-effective solar eruption to date. This particular event is also part of a NASA-sponsored Living With a Star (LWS) study and an on-going US NSF-sponsored Solar, Heliospheric, and INterplanetary Environment (SHINE) community investigation.  相似文献   

Relationships between land use and stream invertebrate community structure in a South Island,New Zealand,coastal stream catchment     

Matthew J. Hall  Gerard P. Closs  Ralph H. Riley 《新西兰海洋与淡水研究杂志》2013,47(3):591-603

Macroinvertebrate community composition was compared across streams draining catchments dominated by either native bush, agricultural or urban land uses within the Water of Leith stream catchment near Dunedin, New Zealand. Land use was associated with differences in taxon richness and faunal composition of communities present in each stream. The mean abundance levels of Ephemeroptera, Plecoptera, and Trichoptera were highest in native bush catchments, and lowest in urban catchments. In contrast, the mean abundance of Oligochaeta exhibited the opposite pattern. Increasing dominance of the urban and agricultural streams by pollution tolerant taxa was reflected in the Macroinvertebrate Community Index and Quantitative Macroinvertebrate Community Index scores.  相似文献