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1.
A core from the Cambay Shale Formation of the Cambay Basin, containing immature Type III organic matter, was pyrolysed at 300°C for different durations of time to different maturation levels. Fractionation effects were studied employing a three-step extraction technique after removal of the expelled pyrolysate. The extractable organic matter (EOM) obtained on extraction of the whole core is assumed to be that present in open pores, while that obtained on finely crushing the sample is assumed to be that present in closed pores. The EOM obtained from 1 cm chips is termed EOM from semi-open pores. The gross composition of the pyrolysates expelled during pyrolysis is not similar to the oils reservoired in the area, and there is no significant fractionation observed between expelled pyrolysates and unexpelled EOM. Our study indicates movement of fluids between closed, semi-open and open pores. In both systems, there is a higher concentration of EOM in open pores than in semi-open and closed pores, and the fraction of EOM in open pores is much greater in the artificial system than in the natural system. Fractionation effects on n-alkane and isoprenoid hydrocarbon-based parameters were also studied. n-Alkenes are present in semi-open and closed pores of the immature core and in the core after it was pyrolysed to 300°C for 6 and 48 h, but are absent in the open pores. n-Alkenes are present in closed pores in the naturally matured core. Presence of n-alkenes in the pyrolysates expelled during the 6 and 48 h experiments, but their absence in the open pores of the core, indicates that expulsion also occurs through temporary microfractures during laboratory pyrolysis, whereas in the natural system expulsion from closed pores seems to be only via semi-open and open pores. 相似文献
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A. J. Prakash P. Palroy D. D. Misra 《Fragblast: International Journal for Blasting and Fragmentation》2004,8(1):51-60
This paper presents the influence of various discontinuities, natural or artificial, on magnitude and frequencies of blast induced ground vibrations. These discontinuities were geological faults, a pond, a shaft incline, a trench and a pre-split plane interposed in the path of vibration propagation. In the post-trench region, ground vibrations in terms of peak particle velocity were significantly reduced and dominant frequencies in higher bands were consequently observed. Depth of trench with respect to blastholes were varied and consequent vibration characteristics were analyzed. The techniques of creating a trench and pre-split plane were successfully implemented in controlling vibration and in increasing the explosives charge to meet the scheduled production target of an opencast mine. Comparisons of ground vibration characteristics affected by a trench and a pre-split plane of the same depth are described in the text. The findings lead to the conclusion that such experimental data are necessary for production blasting in open cast mines under constrained conditions. 相似文献
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N. Misra P. K. Panda B. K. Parida B. K. Mishra 《International Journal of Environmental Science and Technology》2016,13(11):2735-2756
Driven by policies aimed at enhancing energy security and mitigating greenhouse gas emissions, the production and use of biofuels have significantly increased in recent years. Microalgae owing to its multiple advantages which include high lipid content, sustainable biomass production, effective land and water utilization are the most potential biofuel feedstock that can provide drop-in fossil fuel replacements without stimulating competition for agricultural resources and are considered to be more environmentally benign than the first- and second-generation biofuel feedstocks. However, there are many existing technical and scientific impediments that are yet to be resolved. Keeping this in view, the present review provides a concise account of the microalgal species known to accumulate high levels of lipid and describes the main factors that should be taken into consideration while selecting suitable algal strains for mass cultivation. The underlining advantages and limitations of raceway pond and photobioreactor cultivation systems are also examined. The recent advances in genetic engineering of microalgae to improve biomass and lipid productivity are then highlighted, which include the ongoing debate over the biosafety issues pertinent to the use of genetically modified algae. Furthermore, a wide range of high-value products that can be co-produced from microalgae have been discussed. The review concludes with a comprehensive summary of the major techno-economic constraints to commercialization of algal-derived biofuels along with promising methods for overcoming these challenges in order to produce cost-competitive and environmentally sustainable biofuel. 相似文献
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Chandrashekhar Azad Vishwakarma Ratan Sen Neha Singh Priyadarshini Singh Vikas Rena Kumari Rina Saumitra Mukherjee 《Journal of the Geological Society of India》2018,92(6):753-763
This paper focuses on the suitability of spring water for drinking and irrigation purposes in a part of eastern Himalaya, south Sikkim. There are many anthropogenic and geogenic factors contributing as a source of major cations and anions in the spring water. The spring water chemistry show a variation in EC, pH, TDS, Temperature, Na+, K+, Mg2+, Ca2+, Fe2+, Pb, Mn, Cu, HCO3-, Cl-, PO43-, NO3-, F- and SO42-. Mainly two types of water quality indexing has been used, one for suitability of spring water for drinking purposes and the other for irrigation purposes. For drinking purposes, Piper diagram used for determination of water type, water quality index (WQI) for quality monitoring and saturation index for mineral dissolution in water. % Na, RSC (Residual Sodium Carbon) and SAR (sodium absorption ratio) have been used for irrigation suitability. Piper diagram shows that CaHCO3 type of water was dominant in the study area. The WQI depicted excellent category and SAR, percent sodium and RSC (Residual Sodium Carbon) depict excellent, good and permissible category for irrigation purposes. Principle component analysis (PCA) was used to determine the major influencing factor responsible for the variability in the parameters analysed of spring water. 相似文献
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Chander Kumar Singh Rina Kumari Neha Singh Javed Mallick Saumitra Mukherjee 《水文研究》2013,27(17):2462-2474
The groundwater is the only source of drinking water in the Jaisalmer district of Rajasthan, India. The study area is a part of the Thar Desert. It has low and scattered population and no industries; hence, the possibility of anthropogenic input of fluoride is almost negligible. Thus, the enrichment of fluoride is only possible due to geochemical processes taking place in the groundwater of the region. A total of 100 groundwater samples, 34 samples from Jaisalmer and 66 samples from the Pokharan administrative blocks, were collected. It was observed that the concentration of fluoride ranged from 0.08 mg/l to 4.56 mg/l in the groundwater of Jaisalmer and from 0.56 mg/l to 6.60 mg/l in the samples of the Pokharan block. The alkaline condition (average pH, 7.7 ± 0.22 and 8.01 ± 0.25 in Jaisalmer and the Pokharan administrative block, respectively) in the region favours fluorite dissolution. Ion exchange, dissolution of calcite, semi‐arid climate, alkaline conditions and weathering are responsible for fluoride enrichment in the groundwater of the study area. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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Landsat imagery have been interpreted visually and under Additive Colour Viewer to interpret the regional geology and geomorphology in parts of Subarnarekha-Baitarani basin. The area lies south of Singhbhum shear zone and represents Precamrain shield. Important Simlipal ultrabasic volcanic complex of Orissa is included in the area. Although detailed map of the area is available, yet an attempt has been made to interpret the imagery for evaluating the results provided in comparison to the existing maps. Delineation of main lithological groups is possible. Having some data from the existing maps, lithoiogical boundary delineation of Mica Schist-Phyllite-Quartzite, Granites and Gneisses, Dhanjori Lava, Anorthosite-Gabbro Complex and Dolerite dykes, all of Precambrian age, has been done. Laterite and Quaternary sediments are also picked up. Lineament mapping has been carried out from imagery, which is difficult to map in the field. N--S and NNW-SSE lineament system is very prominent in Simlipal complex whereas in other parts NNW-SSE and NNE-SSW trends are common. The major fault plane running NNE-SSW in the area is responsible for the present-day configuration of Subarnarekha river. Identification of different geomorphological units is perhaps best done on imagery. Several geomorphic units like structural Hill, Denudational Hill, Pediment, Buried Pediment, Lateritic Clay Plain, Laterite upland, Terrace Plain etc have been mapped. Valley fills are wellpicked up from imagery. Hydrogeological potentiality of the different geologic and geomorphic units have been evaluated qualitatively. Ground water occurrence, movement and potentiality are mainly controlled by structural, geological and geomorphological set-up of the area. Buried Pediment, Laterite upland, Laterite clay plain and alluvial fills are the potential zones from the view point of ground water occurrences. Comparative study of the different Landsat bands and band-filter combinations under Additive Colour Viewer has been undertaken to find out the enhancement capability in delineating features. It is found that small scale geological and geomorphological maps can be prepared from Landsat imagery. 相似文献