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Various reanalyses have been utilized in numerous climate related researches around the globe, however, there exists considerable biasedness in these products, especially in precipitation and temperature data. The ability of these reanalysis products to simulate the precipitation and temperature patterns is observed to be satisfactory at global scale, while it differs significantly at regional scale, especially over regions of high spatio-temporal heterogeneity such as India. Therefore, it is essential to evaluate the applicability and robustness of reanalyses in climate related research. The annual and seasonal variability in spatio-temporal patterns and trends of precipitation and temperature data, with respect to the IMD gridded data over 34 yrs, are evaluated for six global reanalyses namely, NCEP/NCAR Reanalysis (NCEP R1), NCEP-DOE AMIP-2 Reanalysis (NCEP R2), Climate Forecast System Reanalysis (CFSR), ECMWF Interim Reanalysis (ERA-Interim), Modern Era Retrospective Analysis for Research and Application Land only model (MERRA-Land) and JMA 55-year Reanalysis (JRA-55). The ability of the reanalyses was tested based on several factors such as statistical and categorical indices, spells and trends, for annual and seasonal daily values. Several regional and seasonal differences were observed, particularly over high rainfall regions such as Western Ghats and northeastern India. MERRA-Land is found to give the best results for precipitation over India, which is attributed to the updated forcing data using gauge-based precipitation observations. Similarly, ERA-Interim and JRA-55 exhibit better performance for temperature than other datasets. All reanalyses failed to correctly reproduce the trends in IMD data, for both precipitation and temperature. These observations will provide a better perception on the reliability and applicability of reanalyses for climate and hydrological studies over India.  相似文献   
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Summary Crystallographic intergrowths of jacobsite and hausmannite (vredenburgite) occur in association with braunite in the Precambrian Sausar Group of rocks, India, that were metamorphosed under 600-700°C and P 6 kb. Quartz, hematite, rhodochrosite and a later hausmannite may occasionally occur as minor associates. Detailed characterization of the intergrown phases reveals that hausmannite lamellae, oriented in 4 or 5 crystallographic directions in the jacobsite host, show a wide variation in thickness and tapered intersections at low angles. The lamellae may be locally deformed. Analytical data reveal that the composition of natural hausmannite and jacobsite in the intergrowths cannot be approximated within the system Fe3O4 -Mn3O4, as has been conventionally done. These really belong to the Fe2O3-Mn3O4 subsystem. In the two phase intergrowths, hausmannite is depleted and the jacobsite is enriched in Fe in higher grade rocks. Mineral associations and petrographic considerations suggest that the jacobsite-hausmannite intergrowth originated through prograde decarbonation-oxidation reactions of a carbonatic precursor in an unbuffered X CO2 situation, but f O2 was held between hematite-magnetite and bixbyite-hausmannite buffers at the ambient physical conditions of metamorphism. Subsequent oxidation yielded a strong oxygenbuffering assemblage jacobsite, hausmannite, braunite, hematite and quartz. This study negates the commonly held idea that hausmannite jacobsite crystallographic intergrowth (vredenburgite) originates through unmixing of a high ([ldvredenburgite) originates through unmixing of a high temperature spinelss temperature spinelss during cooling.
Genetische Reinterpretation der kristallographischen Verwachsungen von Jakobsit und Hausmannit in natürlichen Vorkommen
Zusammenfassung Kristallographische Verwachsungen von Jakobsit und Hausmannit (Vredenburgit) treten in Verbindung mit Braunit in Gesteinen der präkambrischen Sausargruppe in Indien auf. Die Gesteine wurden bei Drucken von ca. 6 kbar und Termperaturen von 600–700°C metamorphosiert. Quarz, Hämatit, Rhodochrosit, und Hausmannit als Spätphase treten gelegentlich als untergeordnete Gemengteile auf. Hausmannit-Lamellen, die in vier oder fünf kristallographischen Richtungen in Jakobsit orientiert sind, haben sehr unterschiedliche Durchmesser und bilden versetzte Zwickel in kleinem Winkel mit dem Jakobsit. Die Lamellen können lokal deformiert sein. Analytische Daten zeigen, daß die Zusammensetzung von natürlichem Hausmannit und Jakobsit in Verwachsungen nicht, wie bisher angenommen, in dem System Fe3O4-Mn3O4 dargestellt werden kann. Diese Verwachsungen gehören vielmehr in das Fe2O3-Mn3O4 System. In höher-gradigen metamorphen Gesteinen ist Fe in zwei-phasigen Verwachsungen im Hausmannit ab- und im Jakobsit angereichert. Die Mineralzusammensetzung und petrographische Gesichtspunkte lassen darauf schließen, daß die Jakobsit/Hausmannit Verwachsung durch prograde Dekarbonatisierung/Oxydationsreaktion eines karbonatischen Vorläufers in einem nicht gepufferten X CO2 Milieu entstanden ist. F O2 wurde durch Hämatit-Magnetit und Bixbyit-Hausmannit Puffer unter den gegebenen physikalischen Bedingungen der Metamorphose stabil gehalten. Eine nachfolgende Oxydation führte zu einer starken Sauerstoff-puffernden Assoziation von Jakobsit, Hausmannit, Braunit, Hämatit und Quarz. Diese Untersuchungen widerlegen die allgemein verbreitete Ansicht, daß die kristallographische Verwachsung von Hausmannit und Jakobsit (Vredenburgit) durch Entmischung eines Hochtemperatur-Spinells während der Abkühlung entstanden ist.


With 1 figure  相似文献   
4.
The present study is confined to the northern part of the Khetri copper belt that extends for about 100 km in northern Rajasthan. Mineralization is more or less strata-bound and is confined to the garnetiferous chlorite schist and banded amphibolite quartzite, occurring towards the middle of the Proterozoic Delhi Supergroup. Preserved sedimentary features and re-estimation of the composition of the pre-metamorphic rocks suggest that the latter were deposited in shallow marine environment characterized by tidal activity. Cordierite-orthoamphibole-cummingtonite rock occurring in the neighbourhood of the ores is discussed, and is suggested to be isochemically metamorphosed sediment. The rocks together with the ores were deformed in two phases and metamorphosed in two progressive and one retrogressive events of metamorphism. Study of the host rocks suggests that the maximum temperature and pressure attained during metamorphism are respectively 550–600°C and < 5.5 kb. Principal ore minerals in Madan Kudan are chalcopyrite, pyrrhotite, pyrite and locally magnetite. In Kolihan these are chalcophyrite, pyrrhotite and cubanite. Subordinate phases are sphalerite, ilmenite, arsenopyrite, mackinawite, molybdenite, cobaltite and pentlandite. The last two are very rare. Gangue minerals comprise quartz, chlorite, garnet, amphiboles, biotite, scapolite, plagioclase and graphite. The ores are metamorphosed at temperatures > 491°C. Sulfide assemblages are explained in terms of fS 2 during metamorphism. Co-folding of the ore zone with the host rocks, confinement of the ores to the carbonaceous pelites or semi-pelitic rocks, strata-bound and locally even stratiform nature of the orebodies, lack of finite wall rock alteration, metamorphism of the ores in the thermal range similar to that for the host rocks, absence of spatial and temporal relationship with the granitic rocks of the region led the authors to conclude that the entire mineralization was originally sedimentary-diagenetic. Any loss of primitive features and development of incongruency are due to subsequent deformation and metamorphism to which the ores and their hosts were together subjected.  相似文献   
5.
The line-of-sight direction in the redshifted 21-cm signal coming from the cosmic dawn and the epoch of reionization is quite unique in many ways compared to any other cosmological signal. Different unique effects, such as the evolution history of the signal, non-linear peculiar velocities of the matter etc. will imprint their signature along the line-of-sight axis of the observed signal. One of the major goals of the future SKA-LOW radio interferometer is to observe the cosmic dawn and the epoch of reionization through this 21-cm signal. It is thus important to understand how these various effects affect the signal for its actual detection and proper interpretation. For more than one and half decades, various groups in India have been actively trying to understand and quantify the different line-of-sight effects that are present in this signal through analytical models and simulations. In many ways the importance of this sub-field under 21-cm cosmology have been identified, highlighted and pushed forward by the Indian community. In this article, we briefly describe their contribution and implication of these effects in the context of the future surveys of the cosmic dawn and the epoch of reionization that will be conducted by the SKA-LOW.  相似文献   
6.
Studying the cosmic dawn and the epoch of reionization through the redshifted 21-cm line are among the major science goals of the SKA1. Their significance lies in the fact that they are closely related to the very first stars in the Universe. Interpreting the upcoming data would require detailed modelling of the relevant physical processes. In this article, we focus on the theoretical models of reionization that have been worked out by various groups working in India with the upcoming SKA in mind. These models include purely analytical and semi-numerical calculations as well as fully numerical radiative transfer simulations. The predictions of the 21-cm signal from these models would be useful in constraining the properties of the early galaxies using the SKA data.  相似文献   
7.
Detection of individual luminous sources during the reionization epoch and cosmic dawn through their signatures in the HI 21-cm signal is one of the direct approaches to probe the epoch. Here, we summarize our previous works on this and present preliminary results on the prospects of detecting such sources using the SKA1-low experiment. We first discuss the expected HI 21-cm signal around luminous sources at different stages of reionization and cosmic dawn. We then introduce two visibility based estimators for detecting such signals: one based on the matched filtering technique and the other relies on simply combing the visibility signal from different baselines and frequency channels. We find that the SKA1-low should be able to detect ionized bubbles of radius \(R_{\mathrm {b}} \gtrsim 10\) Mpc with ~100 h of observations at redshift z~8 provided that the mean outside neutral hydrogen fraction \(\mathrm {x}_{\text {HI}} \gtrsim 0.5\). We also investigate the possibility of detecting HII regions around known bright QSOs such as around ULASJ1120+0641 discovered by Mortlock et al. (Nature 474, 7353 (2011)). We find that a 5σ detection is possible with 600 h of SKA1-low observations if the QSO age and the outside xHI are at least ~2×107 Myr and ~0.2 respectively. Finally, we investigate the possibility of detecting the very first X-ray and Ly- α sources during the cosmic dawn. We consider mini-QSOs like sources which emits in X-ray frequency band. We find that with a total ~ 1000 h of observations, SKA1-low should be able to detect those sources individually with a ~ 9σ significance at redshift z=15. We summarize how the SNR changes with various parameters related to the source properties.  相似文献   
8.
Nonlinear kinetic analysis of phenol adsorption onto peat soil   总被引:1,自引:0,他引:1  
Phenolic compounds are considered as a serious organic pollutant containing in many industrial effluents particularly vulnerable when the plant discharge is disposed on land. In the present study, the phenol removal potential of peat soil as adsorption media was investigated as the adsorption process are gaining popular for polishing treatment of toxic materials in industrial wastewater. Batch experiments were performed in the laboratory to determine the adsorption isotherms of initial concentrations for 5, 8, 10, 15, and 20 mg/L and predetermined quantity of peat soil with size ranges between 425 and 200 μm poured into different containers. The effects of various parameters like initial phenol concentration, adsorbent quantity, pH, and contact time were also investigated. From experimental results, it was found that 42 % of phenol removal took place with optimized initial phenol concentration of 10 mg/L, adsorbent dose of 200 g/L, solution pH 6.0 for the equilibrium contact time of 6 h. The result exhibits that pseudo-first-order (R 2 = 0.99) and Langmuir isotherm models are fitted reasonably (R 2 = 0.91). Adams–Bohart, Thomas, Yoon–Nelson, and Wolborska models were also investigated to the column experimental data of different bed heights to predict the breakthrough curves and to determine the kinetic coefficient of the models using nonlinear regression analysis. It was found that the Thomas model is the best fitted model to predict the experimental breakthrough curves with the highest coefficient of determination, R 2 = 0.99 and lowest root mean square error and mean absolute performance error values.  相似文献   
9.
We use the Fisher matrix formalism to predict the prospects of measuring the redshifted 21-cm power spectrum in different k-bins using observations with the upcoming Ooty Wide Field Array (OWFA) which will operate at 326.5 MHz. This corresponds to neutral hydrogen (HI) at z = 3.35, and a measurement of the 21-cm power spectrum provides a unique method to probe the large-scale structures at this redshift. Our analysis indicates that a 5σ detection of the binned power spectrum is possible in the k range 0.05 ≤ k ≤ 0.3 Mpc?1 with 1000 hours of observation. We find that the signal- to-noise ratio (SNR) peaks in the k range 0.1?0.2 Mpc?1 where a 10σ detection is possible with 2000 hours of observations. Our analysis also indicates that it is not very advantageous to observe beyond 1000 h in a single field-of-view as the SNR increases rather slowly beyond this in many of the small k-bins. The entire analysis reported here assumes that the foregrounds have been completely removed.  相似文献   
10.
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