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1.
The diffusion in a shearing oscillatory flow from an instantaneous surface point source is considered. An analytical solution is obtained by Fourier transform. The results show that, for three dimensional diffusion in an oscillatory flow with constant shear, the distribution of the contaminant follows the multivariate Gaussian distribution rule. When the frequency is very high, or the time very short, the shear does not influence the diffusion. For moderate values of time, there are fluctuations with longitudinal variance. For large values of time the longitudinal variance increases as t, and the peak concentration decreases as t−1.5, which are faster than those in a flow without shear, but much slower than those in a steady flow, where the longitudinal variance increases as t3 and the peak concentration decreases as t−2.5. The contaminant patch is elongated in the longitudinal direction of the shear flow and moves back and forth with the water motion. Contribution No. 1306 from the Institute of Oceanology, Academia Sinica. Received July 12, 1985  相似文献   
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We review the main characteristics of the symbiotic system AG Draconis, with special emphasis on its optical and X-ray variations. We also discuss the X-ray to visual energy distribution during quiescence and outburst and describe our spectroscopic and X-ray observations during the 2003 outburst. Based on X-ray observations collected with the XMM–Newton Observatory, on INES data from the IUE satellite, and on optical spectra collected with the Asiago–Cima Ekar, Bologna–Loiano and La Palma–Galileo Italian telescopes.  相似文献   
4.
We report the astronomical identification of the cyanomethyl radical, CH2CN, the heaviest nonlinear molecular radical to be identified in interstellar clouds. The complex fine and hyperfine structures of the lowest rotational transitions at about 20.12 and 40.24 GHz are resolved in TMC-1, where the abundance appears to be about 5 x 10(-9) relative to that of H2. This is significantly greater than the observed abundance of CH3CN (methyl cyanide) in TMC-1. In Sgr B2 the hyperfine structure is blended in the higher frequency transitions at 40, 80, and 100 GHz, although the spin-rotation doubling is clearly evident. Preliminary searches in other sources indicate that the distribution of CH2CN is similar to that for such carbon chain species as HC3N or C4H.  相似文献   
5.
We report the mineral compositions and micro-texture of the isotopically anomalous (δ17,18OSMOW ∼ +180‰) Fe-S-Ni-O material recently discovered in matrix of the primitive carbonaceous chondrite Acfer 094 [Sakamoto N., Seto Y., Itoh S., Kuramoto K., Fujino K., Nagashima K., Krot A. N. and Yurimoto H. (2007) Oxygen isotope evidence for remnants of the early solar system primordial water. Science317, 231-233]. Synchrotron radiation X-ray diffraction and transmission electron microscopy studies indicate that this material consists of the symplectitically intergrown magnetite (Fe3O4) and pentlandite (Fe5.7Ni3.3S8) with magnetite/pentlandite volume ratio of ∼2.3. Magnetite forms column-shaped grains (10-30 nm in diameter and 100-200 nm in length); pentlandite occurs as worm-shaped grains or aggregates of grains 100-300 nm in size between magnetite crystals. Although both the X-ray diffraction and electron energy loss spectra support identification of iron oxide as magnetite, the electron diffraction patterns show that magnetite has a weak 3-fold superstructure, possibly due to ordering of vacancies. We infer that the isotopically anomalous symplectite formed by sulfurization and oxidization of metal grains either in the solar nebula or on an icy planetesimal. The intersite cation distribution of pentlandite suggests that timescale of oxidation was no longer than 1000 years.  相似文献   
6.
The uranium LIII-edge XANES spectra for natural rocks at the concentration range of 0.96–124 mg kg−1 were measured using a log spiral bent crystal Laue analyzer (BCLA) combined with a multi-element Ge detector. It was found that the quality of the XANES spectra using the BCLA was greatly improved due to a reduction of interfering fluorescence from major components such as Rb and Sr. The ratio of signal to background intensities in the U LIII-edge XANES spectra increased by a factor of 2.9–17 with the use of the BCLA, which greatly enhanced the detection limit for the speciation of the oxidation states of U or the U(IV)/U(VI) ratio of natural samples. In addition, it was demonstrated that the fluorescence XANES method coupled with the BCLA enable determination of the speciation of U for various natural samples such as acidic igneous rocks, ferromanganese nodules, sediments, and some sedimentary rocks such as shale and limestone.  相似文献   
7.
In situ strength measurements on natural upper-mantle minerals   总被引:1,自引:0,他引:1  
Using in situ strength measurements at pressures up to 10 GPa and at room temperature, 400, 600, and 700°C, we examined rheological properties of olivine, orthopyroxene, and chromian-spinel contained in a mantle-derived xenolith. Mineral strengths were estimated using widths of X-ray diffraction peaks as a function of pressure, temperature, and time. Differential stresses of all minerals increase with increasing pressure, but they decrease with increasing temperature because of elastic strain on compression and stress relaxation during heating. During compression at room temperature, all minerals deform plastically at differential stress of 4–6 GPa. During subsequent heating, thermally induced yielding is observed in olivine at 600°C. Neither orthopyroxene nor spinel shows complete stress relaxation, but both retain some stress even at 700°C. The strength of the minerals decreases in the order of chromian-spinel ≈ orthopyroxene > olivine for these conditions. This order of strength is consistent with the residual pressure of fluid inclusions in mantle xenoliths.  相似文献   
8.
Sedimentation process of fine-grained terrigenous red soils was observed on the seafloor by coral reefs near an estuary using a paired mooring of turbidity meter and sediment trap or a mooring of sediment trap and current meter. Silty clays contained in the bottom calcareous sands were mainly resuspended and trapped in both surface and bottom layer traps, at noncatastrophic normal sedimentation periods. In addition, silty clays were supplied to this mooring site by inflowing river. Turbidity and the flux rate determined by sediment traps show certain relationship accompanied with the coefficient, which is changed by precipitation, current, and other conditions. Resuspension process caused by a typhoon was recorded as both core sequence of sediment trap and time-series data of bottom current. Maximum velocity of 49.5 cm/s was recorded from bottom currents resulting from the passing of attyphoon at the mooring site. A graded sand layer is interbedded in dark-gray, silty clay and considered to be a resuspended sediment resulting from the passing of the typhoon. Flux of the resuspended sediments by the typhoon was estimated from this core sequence and compared to the flux observed at the normal sedimentation.  相似文献   
9.
Decadal variability of subsurface temperature in the North Pacific has been investigated. Two dominant regions were found; the central subarctic region (CSa) and the north-eastern subtropical region (NESt). In CSa, cooling (warming) of wintertime subsurface temperature corresponds to the large (small) temperature gradient and southward (northward) shift of subsurface temperature front, associated with the increase (decrease) of positive wind stress curl and the southward (northward) shift of curl τ zero line with 2 years delay. It is suggested that the relocation of subtropical-subarctic boundary plays an important role. In NESt, importance of heat flux through the sea surface and heat divergence in the Ekman layer is also discussed. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
10.
The presence of organic ligands (L) whose conditional stability constants (KML) are strong enough to allow them to form complexes with copper has been reported in oceanic waters. However, there is no general agreement on the distributional characteristics of such strong ligands in the water column. We present that these inconsistencies are derived from not only different analytical methods employed for their detection but also different oceanographic conditions. In particular, the nature and quantities of detectable natural ligands are affected by what kind of form the ligands are presentin situ in different marine environments, that is, chemical speciation of natural ligands (ligand speciation), which depends strongly on the variations in concentrations of coexisting trace metals. Using published data from observations in the laboratory and the field, we provide limits to the ranges of conditional stability constants of organic ligands for copper, zinc and cadmium that are detectable by the extensively used direct metal-titration method. For example, our model indicates that organic ligands for copper with log KCuL(Cu)>12.4 in surface water and with log KCuL(Cu)>9.9 in deep water might not have been detected because stronger ligands had formed complexes with ambient metalsin situ at a station in the North Pacific. The estimation suggests that there is a basinscale difference in speciation of natural organic ligands and, moreover, that this difference influences metal speciation. It is postulated that comparisons of the occurrence and levels of organic ligands might not be possible among spatially and temporally different observations without reconciliation of the effects of speciation of the ligands, even if an identical method is used in every case.  相似文献   
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