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1.
An automatic sample changer based upon a commercially available 20-port rotary valve has been developed for use in automated seawater nutrient analyses. All parts exposed to seawater are of stainless steel, Teflon®, or Kel-F®. The sampler has proven to be rugged and efficient in both shore and shipboard laboratories. 相似文献
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The palaeoecological potential of fish scales was assessed by comparing contemporary population data with scale remains obtained from littoral (n = 10) and open water (n = 10) surface sediment samples in two English shallow lakes, Selbrigg Pond and Cockshoot Broad. Scales and/or scale fragments were present, in low numbers (<20 per 100 cm3 wet sediment) in 34 of 40 sediment samples. In accordance with fish population data, higher densities of scale remains were found in Selbrigg compared to Cockshoot, and in littoral compared to open water samples. Taxonomic difficulties, exacerbated by scale fragmentation, made it impossible to assign the majority of remains to individual species. Most remains could, however, be placed into one of two groups: (i) percids – represented by both scales and scale fragments; and (ii) cyprinids – largely represented by scale fragments. To allow comparison of fish population and sedimentary scale data, both were converted to percentages of the aggregate percid–cyprinid total. Whole scales recovered were almost exclusively percid (45 of 48), thus bore little resemblance to the contemporary fish data. Nevertheless, percentages of scale fragments (Selbrigg: 34 and 66%; Cockshoot: 13 and 87% percid and cyprinid, respectively) and of whole scales and fragments combined (Selbrigg: 54 and 46%; Cockshoot: 46 and 54% percid and cyprinid, respectively) reflected the presence of the numerically dominant fish groups and the broad inter-site differences in their relative abundance (Selbrigg: 36 and 64%; Cockshoot: 10 and 90% percid and cyprinid, respectively). A running mean of scales per sediment volume indicated that some 400 cm3 of sediment was required to accurately characterise the remains present. This study suggests that, with the appropriate methodological considerations (e.g., collection of large sediment samples), fish scale remains may be used to determine the past presence–absence and relative abundance of percid and cyprinid species. As such, this technique may be a valuable supplementary tool for establishing longer-term changes in the fish communities of shallow lakes. 相似文献
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High-pressure, high-temperature diamond growth experiments have been conducted in the system C–K2CO3–KCl at 1050–1420 °C, 7.0–7.7 GPa. KCl is of interest because of the strong effect of halogens on the phase relations of carbonate-rich systems [Geophys. Res. Lett. 30 (2003) 1022] and because of the occurrence of KCl coexisting with alkali silicate–carbonate fluids in natural-coated diamond [Geochim. Cosmochim. Acta 64 (2000) 717]. We have used system C–K2CO3–KCl as an analogue for these mantle fluids in diamond growth experiments. The presence of KCl reduces the potassium carbonate liquidus to ≤1000 °C at 7.7 GPa, allowing it to act as a solvent catalyst for diamond growth at temperatures below the continental geotherm. This is a reduction on the minimum diamond growth temperature reported in the alkali-carbonate–C–O–H system [Lithos 60 (2002) 145]. Diamond growth using carbonate solvent catalysts is characterised by a relatively long induction period. However, the addition of KCl also reduced the period for diamond growth in carbonate to 5 min; no such induction period appears to be necessary. It is suggested that KCl destabilises carbonate, allowing greater solubility and diffusion of carbon. 相似文献
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Emma Tomlinson Isabel De Schrijver Adrian P. Jones Frank Vanhaecke 《Geochimica et cosmochimica acta》2005,69(19):4719-4732
Trace element compositions of submicroscopic inclusions in both the core and the coat of five coated diamonds from the Democratic Republic of Congo (DRC, formerly Zaire) have been analyzed by Laser Ablation Inductively Coupled Mass Plasma Spectrometry (LA-ICP-MS). Both the diamond core and coat inclusions show a general 2-4-fold enrichment in incompatible elements relative to major elements. This level of enrichment is unlikely to be explained by the entrapment of silicate mantle minerals (olivine, garnet, clinopyroxene, phlogopite) alone and thus submicroscopic fluid or glass inclusions are inferred in both the diamond coat and in the gem quality diamond core. The diamond core fluids have elevated High Field Strength Element (Ti, Ta, Zr, Nb) concentrations and are enriched in U relative to inclusions in the diamond coats and relative to chondrite. The core fluids are also moderately enriched in LILE (Ba, Sr, K). Therefore, we suggest that the diamond cores contain inclusions of silicate melt. However, the Ni content and Ni/Fe ratio of the trapped fluid are very high for a silicate melt in equilibrium with mantle minerals; high Ni and Co concentrations in the diamond cores are attributed to the presence of a sulfide phase coexisting with silicate melt in the diamond core inclusions. Inclusions in the diamond coat are enriched in LILE (U, Ba, Sr, K) and La over the diamond core fluids and to chondrite. The coats have incompatible element ratios similar to natural carbonatite (coat fluid: Na/Ba ≈0.66, La/Ta≈130). The coat fluid is also moderately enriched in HFSE (Ta, Nb, Zr) when normalized to chondritic Al. LILE and La enrichment is related to the presence of a carbonatitic fluid in the diamond coat inclusions, which is mixed with a HFSE-rich hydrous silicate fluid similar to that in the core. The composition of the coat fluid is consistent with a genetic link to group 1 kimberlite. 相似文献
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Erosion of the southern Gold Coast beaches (SE Queensland, Australia) was exacerbated after the extension of the Tweed River training walls in the early 1960s. To achieve the objective of restoring and maintaining beach amenity, significant nourishment works have been undertaken in Coolangatta Bay over the past 30 years. Particularly, under the Tweed River Entrance Sand Bypassing Project (TRESBP) since 1995, a number of nourishment campaigns and the implementation of a permanent sand bypass system in 2001 have resulted in significant changes of Coolangatta Bay morphology. The present case study investigates the influence of both wave climate and nourishment works on the area extending from the updrift Snapper Rocks area to downdrift Kirra Beach. SWAN spectral wave model is implemented at Coolangatta Bay area and forced by the global wave model WW3 to estimate wave forcing and the potential natural longshore drift entering in Coolangatta. Specific transects extracted from accurate bathymetric surveys are used to investigate and quantify Coolangatta Bay sedimentation for the period 1987–2005. A network of Argus video stations provides high sample rate information on the shoreline evolution. Results show that, over the past 10 years, Coolangatta Bay has infilled rapidly. Sedimentation reached up to 6 m in some areas between 1995 and 2005, with beach width increasing by 200 m at Kirra Beach. Rapid seaward shoreline migration is consistent with the intense over-pumping of sand relative to the natural potential to move sand alongshore. The nourishment strategy used during this project has successfully delivered large amounts of sand to the southern Gold Coast embayment, although it has been up to now controversial from many community perspectives. The artificial sand bypassing process proved to be much more efficient than depositing the dredged sand in the nearshore area which requires a significant period of low energy condition in order for the deposited sediment to migrate shoreward and weld to the shore. This case study confirms that, when carefully undertaken, sand bypassing is a sustainable and flexible soft engineering approach which can work in concert with natural processes. 相似文献
6.
Eric Heinen De Carlo Michael S. Tomlinson Laura E. deGelleke Sara Thomas 《Aquatic Geochemistry》2014,20(2-3):87-113
Lack of high-spatial-resolution soil and sediment arsenic data for Hawai‘i has generated substantial disagreement between researchers and regulators regarding the magnitude of natural levels of arsenic in Hawai‘i and rendered difficult the defining of areas of anthropogenically elevated arsenic. Our earlier research into the occurrence of arsenic in terrestrial and marine environments revealed widely disparate concentrations of arsenic with no apparent spatial pattern. To better understand the distribution and abundance of arsenic in soils and sediments of O‘ahu, we collected an additional 64 samples at locations chosen to represent different environments with varying degrees of human impact. We found surface arsenic values that ranged from 0.28 to 740 ppm with a median concentration of 8.1 ppm, which is above the global median of 5 ppm and US soil median of 5.2 ppm. Higher concentrations of arsenic (up to 913 ppm) were encountered at depth in soil cores. The median arsenic in streambed sediments from one of our earlier studies of 6.1 ppm was comparable to the conterminous US median of 6.3 ppm; however, we encountered arsenic concentrations as high as 43.9 ppm (median = 8.60 ppm, n = 75) in marine sediments in recent work off the leeward coast of O‘ahu. Overall, arsenic in the soils and sediments of O‘ahu is elevated relative to world and national values, but there still is no readily discernible pattern in the distribution of arsenic to explain these elevated values. 相似文献
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Barney Rickett Simon Johnston Taryn Tomlinson † John Reynolds 《Monthly notices of the Royal Astronomical Society》2009,395(3):1391-1402
By measuring the decaying shape of the scatter-broadened pulse from the bright distant pulsar PSR J1644−4559, we probe waves scattered at relatively high angles by very small spatial scales in the interstellar plasma, which allows us to test for a wavenumber cutoff in the plasma density spectrum. Under the hypothesis that the density spectrum is due to plasma turbulence, we can thus investigate the (inner) scale at which the turbulence is dissipated. We report observations carried out with the Parkes radio telescope at 660 MHz from which we find strong evidence for an inner scale in the range 70–100 km, assuming an isotropic Kolmogorov spectrum. By identifying the inner scale with the ion inertial scale, we can also estimate the mean electron density of the scattering region to be 5–10 cm−3 . This is comparable with the electron density of H ii region G339.1−0.4, which lies in front of the pulsar, and so confirms that this region dominates the scattering. We conclude that the plasma inside the region is characterized by fully developed turbulence with an outer scale in the range 1–20 pc and an inner scale of 70–100 km. The shape of the rising edge of the pulse constrains the distribution of the strongly scattering plasma to be spread over about 20 per cent of the 4.6 kpc path from the pulsar, but with similarly high electron densities in two or more thin layers, their thicknesses can only be 10–20 pc. 相似文献
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Catherine Martin-Jones Christine Lane Maarten Van Daele Thijs Van Der Meeren Christian Wolff Heather Moorhouse Emma Tomlinson Dirk Verschuren 《第四纪科学杂志》2020,35(1-2):245-255
Reconstructions of the timing and frequency of past eruptions are important to assess the propensity for future volcanic activity, yet in volcanic areas such as the East African Rift only piecemeal eruption histories exist. Understanding the volcanic history of scoria-cone fields, where eruptions are often infrequent and deposits strongly weathered, is particularly challenging. Here we reconstruct a history of volcanism from scoria cones situated along the eastern shoulders of the Kenya–Tanzania Rift, using a sequence of tephra (volcanic ash) layers preserved in the ~250-ka sediment record of Lake Chala near Mount Kilimanjaro. Seven visible and two non-visible (crypto-) tephra layers in the Lake Chala sequence are attributed to activity from the Mt Kilimanjaro (northern Tanzania) and the Chyulu Hills (southern Kenya) volcanic fields, on the basis of their glass chemistry, textural characteristics and known eruption chronology. The Lake Chala record of eruptions from scoria cones in the Chyulu Hills volcanic field confirms geological and historical evidence of its recent activity, and provides first-order age estimates for seven previously unknown eruptions. Long and well-resolved sedimentary records such as that of Lake Chala have significant potential for resolving regional eruption chronologies spanning hundreds of thousands of years. 相似文献
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