REE Abundance and REE Minerals in Granitic Rocks in the Nanling Range,Jiangxi Province,Southern China,and Generation of the REE‐rich Weathered Crust Deposits     

Shunso Ishihara  Renmin Hua  Mihoko Hoshino  Hiroyasu Murakami 《Resource Geology》2008,58(4):355-372

Studies of Mesozoic granites associated with rare earth element (REE)‐rich weathered crust deposits in southernmost Jiangxi Province indicate that they have high‐K to shoshonite compositions and belong to ilmenite‐series I‐type granites. Of the studied rocks at 59–292 ppm of bulk REE content, the highest are seen in the biotite granites of Dingnan (358, 429 ppm) and mafic biotite granite of the Wuliting Granite (344 ppm) near the Dajishan tungsten mine, both areas where weathered‐crust REE deposits occur. REE‐bearing accessory minerals in these granites are mainly zircon, apatite and allanite, and REE‐fluorocarbonates are common. REE enrichment occurs in the rims of apatite crystals, and in fluorocarbonates that occur along grain boundaries of and cracks in major silicate minerals, and in fluorocarbonates that replaced altered biotite. It is therefore thought that a major part of the REE content of these granites was concentrated during deuteric activity, rather than during magmatic crystallization. The crack‐filling REE‐fluorocarbonates could subsequently have been easily leached out and deposited in weathered crust developed during a long period of exposure.  相似文献   

Genesis of the Jinchuan PGE deposit, China: evidence from fluid inclusions, mineralogy and geochemistry of precious elements   总被引：3，自引：0，他引：3  

X.-Z. Yang  S. Ishihara  D.-H. Zhao 《Mineralogy and Petrology》2006,86(1-2):109-128

Summary The Jinchuan deposit is a platinum group element (PGE)-rich sulfide deposit in China. Drilling and surface sampling show that three categories of platinum group element (PGE) mineralization occur; type I formed at magmatic temperatures, type II occurs in hydrothermally altered zones of the intrusion, and type III in sheared dunite and lherzolite. All ore types were analyzed for Os, Ir, Ru, Rh, Pd, Pt and Au, as well as for Cu, Ni, Co and S. Type I ore has (Pt + Pd)/(Os + Ir + Ru + Rh) ratios of <7 and relatively flat chondrite-normalized noble metal patterns; the platinum group minerals (PGM) are dominated by sperrylite and moncheite associated with chalcopyrite, pyrrhotite and pentlandite. Type II has (Pt + Pd)/(Os + Ir + Ru + Rh) ratios from 40 to 330 and noble metal distribution patterns with a positive slope; the most common PGM are sperrylite and Pd bismuthotelluride phases concentrated mostly at the margins of base metal sulfides. Type III ores have the highest (Pt + Pd)/(Os + Ir + Ru + Rh) ratios from 240 to 710; the most abundant PGM are sperrylite and phases of the Pt–Pd–Te–Bi–As–Cl system. It is concluded that the Jinchuan deposit formed as a result of primary magmatic crystallization followed by hydrothermal remobilization, transport, and deposition of the PGE.  相似文献   

Accretion, dispersal, and reaccumulation of the Bishunpur (LL3.1) brecciated chondrite: Evidence from troilite-silicate-metal inclusions and chondrule rims     

Tomoko Kojima  Dante S. Lauretta 《Geochimica et cosmochimica acta》2003,67(16):3065-3078

A set of troilite-silicate-metal (TSM) inclusions and chondrule rims in the Bishunpur (LL3.1) chondrite provide information regarding impact brecciation of small bodies in the early solar system. The TSM inclusions and chondrule rims consist of numerous angular to subrounded silicate grains that are individually enclosed by fine networks of troilite. FeNi metal also occurs in the troilite matrix. The silicates include olivine (Fo_55-98), low-Ca pyroxene (En_78-98), and high-Ca pyroxene (En_48-68Wo_11-32). Al- and Si-rich glass coexists with the silicates. Relatively coarse silicate grains are apparently fragments of chondrules typical of petrologic type-3 chondrites. Troilite fills all available cracks and pores in the silicate grains. Some of the TSM inclusions and rims are themselves surrounded by fine-grained silicate-rich rims (FGR).The TSM inclusions and rims texturally resemble the troilite-rich regions in the Smyer H-chondrite breccia. They probably formed by shock-induced mobilization of troilite during an impact event on a primitive asteroidal body. Because silicates in the TSM inclusions and rims have highly unequilibrated compositions, their precursor was presumably type-3 chondritic material like Bishunpur itself. The TSM inclusions and the chondrules with the TSM rims were fragmented and dispersed after the impact-induced compaction, then reaccreted onto the Bishunpur parent body. FGR probably formed around the TSM inclusions and rims, as well as around some chondrules, during the reaccumulation process. Components of most type-2 and 3 chondrites probably experienced similar processing, i.e., dispersal of unconsolidated materials and subsequent reaccumulation.  相似文献   

K-Ar Ages of Granitic Magmatism and Related Pegmatite Formation at the Umanotani-Shiroyama Mine, Shimane Prefecture, SW Japan and Their Bearings on Cooling History     

Shouji Kihara    Kenichi Hoshino    Makoto Watanabe    Hirotsugu Nishido  Shunso Ishihara 《Resource Geology》2005,55(2):123-129

Abstract. The Umanotani-Shiroyama pegmatite deposits, the largest producer of K-feldspar and quartz in Japan, are of typical granitic pegmatite. Ilmenite-series biotite granite and granite porphyry, hosting the ore deposits, and biotites separated from these rocks yielded K-Ar ages ranging from 89.0 to 81.4 Ma and 95.2 to 93.7 Ma, respectively. Muscovite and K-feldspar separated from the ore zone yielded K-Ar ages with the range of 96.2 to 93.1 Ma and 87.3 to 80.7 Ma, respectively. Muscovites from quartz-muscovite veins in the ore zone and in the granite porphyry yielded K-Ar ages of 90.4 and 76.3 Ma, respectively. K-feldspar is much younger in age than coexisting muscovite. It is noted that the K-Ar ages of biotite separates and the whole-rock ages are identical to those of muscovite and K-feldspar in the ore zone, respectively. These time relations, as well as field occurrence, indicate that the formation of the pegmatite deposits at the Umanotani-Shiroyama mine is closely related in space and time to a series of granitic magmatism of ilmenite-series nature. Using closure temperatures of the K-Ar system for biotite and K-feldspar (microcline), cooling rate of the pegmatite deposits is estimated to be about 82C/m.y. at the beginning, but slowed down to about 15C/m.y. in the later period.  相似文献   

Apatite Composition of Representative Magnetite‐series and Ilmenite‐series Granitoids in Japan          下载免费PDF全文

Shunso Ishihara  Takeru Moriyama 《Resource Geology》2016,66(1):55-62

Apatites of representative magnetite‐series and ilmenite‐series granitoids were studied in the Japanese Islands. Concentrations of the volatile components F, Cl and SO₃ are differently distributed in apatites of these granitoid series. Apatites are always fluoroapatite. They have weakly higher F content in the ilmenite series than in the magnetite series. In contrast, Cl and SO₃, are significantly concentrated in apatites of the magnetite series compared to the ilmenite series. These characteristics reflect the original concentrations of these components in the host granitic magmas. A high fO₂ seems most important for the S‐concentration as sulfate in apatite of the magnetite series. REE and Y are only erratically high in the studied apatites.  相似文献   

Recycling of Organic Matter in the Sediments of Santa Monica Basin,California Borderland     

Tomoko Komada  David J. Burdige  Cédric Magen  Huan-Lei Li  Jeffrey Chanton 《Aquatic Geochemistry》2016,22(5-6):593-618

Geochemical and isotopic data for the uppermost 1.2 m of the sediments of the central Santa Monica Basin plain were examined to better understand organic matter deposition and recycling at this site. Isotopic signatures (Δ¹⁴C and δ¹³C) of methane (CH₄) and dissolved inorganic carbon (DIC) indicate the occurrence of anaerobic oxidation of CH₄ that is fueled by CH₄ supplied from a relict reservoir that is decoupled from local organic carbon (C_org) degradation and methanogenesis. This finding was corroborated by a flux budget of pore-water solutes across the basal horizon of the profile. Together these results provide a plausible explanation for the anomalously low ratio between alkalinity production and sulfate consumption reported for these sediments over two decades ago. Shifts in Δ¹⁴C and δ¹³C signatures of C_org have previously been reported across the 20-cm depth horizon for this site and attributed to a transition from oxic to anoxic bottom water that occurred ~350 years BP. However, we show that this horizon also coincides with a boundary between the base of a hemipelagic mud section and the top of a turbidite interval, complicating the interpretation of organic geochemical data across this boundary. Radiocarbon signatures of DIC diffusing upward into surface sediments indicate that remineralization at depth is supported by relatively ¹⁴C-enriched C_org within the sedimentary matrix. While the exact nature of this C_org is unclear, possible sources are hemipelagic mud sections that were buried rapidly under thick turbidites, and ¹⁴C-rich moieties dispersed within C_org-poor turbidite sections.  相似文献   

Half-life of 92Nb     

Tomoko Makino  Masatake Honda 《Geochimica et cosmochimica acta》1977,41(10):1521-1523

The long-lived nuclide ⁹²Nb together with ⁹¹Nb and ⁹⁴Nb were produced from Mo by neutron irradiation. The activities of the nuclides were determined by γ spectroscopy and the atomic abundances were determined by mass spectrometry. Intercomparison of ⁹²Nb and ⁹⁴Nb activities and abundances yielded a value for half-life $\text{(}{}^{92}\text{Nb) = (3.3 ± 0.5) × 10}{}^7$ yr based on a value for half-life $\text{(}{}^{94}\text{Nb) = 2.0 × 10}{}^4$ yr. The same value was obtained within errors from absolute counting data and dilution analysis.  相似文献   

Lunar meteorite Queen Alexandra Range 94281: Glass compositions and other evidence for launch pairing with Yamato 793274     

Tomoko ARAI  Paul H. WARREN 《Meteoritics & planetary science》1999,34(2):209-234

Abstract— Lunar meteorite Queen Alexandra Range 94281 is remarkably similar to Yamato 793274. Pairing in the conventional Earth-entry sense is difficult to reconcile with the 2500 km separation between the find locations for these two samples. Nonetheless, both of these regolith breccias are dominated by very-low-Ti (VLT) mare basalt, the pyroxenes of which feature exsolution lamellae on a remarkably coarse scale (typical lamella width = 0.5–1 μm) by mare standards. The pyroxenes also show similar compositional variations (e.g., Fe# vs. Ti# trends, which confirm parentage from VLT mare basalt). Plots using Al₂O₃ or FeO as a tracer of the highland component indicate indistinguishable internal mare-highland geochemical mixing trends. The same two distinctive glass types dominate the mare glass populations of both breccias. Glass type YQ1 features 0.37–0.63 wt% TiO₂, 10–17 wt% MgO, and 9–11 wt% Al₂O₃. Glass type YQ2 features higher TiO₂ (0.99–1.22 wt%), which is inversely correlated with MgO (12.6–13.8 wt%), and nearly constant (8.8 wt%) Al₂O₃. All of these similarities suggest that Y-793274 and QUE 94281 are a launch pair, which we designate YQ. Most of these similarities also extend to another mare-breccia meteorite, Elephant Moraine 87521. However, the EET 87521 mare basalt is unusually V-poor (～88 μg/g), whereas the YQ mare component contains ～166 μg/g. Queen Alexandra Range 94281 features a variety of textural domains. Discrete patches of dark matrix material appear to represent clods of mature regolith that have been mixed with a coarser, relatively immature material. Interior to a frothy fusion crust are areas of massive glass that probably formed as a splash coating on QUE 94281 when it was still on the Moon. The coarse YQ and EET 87521 pyroxene exsolution features imply relatively slow cooling in either a very shallow sill or an unusually thick (ponded) lava and/or later annealing within a cryptomare. Mare pyroclastic glasses, including the two YQ varieties, are systematically MgO-rich compared to crystalline mare basalts. This disparity may be a consequence of limited survival of graphite—the main fuel for explosive volcanism—during formation of the mare source regions as magma ocean cumulates. Graphite (2.2 g/cm³) survived preferentially in regions that avoided extensive early melting and thus remained MgO-rich. An apparent bimodality in the TiO₂ contents of mare volcanics, especially the pyroclastic glasses, also seems a plausible consequence of petrogenesis by remelting of magma ocean cumulates. Cumulates deposited after the magma ocean evolved to ilmenite saturation had vastly higher TiO₂ contents than cumulates deposited shortly before. The YQ regolith's subequal proportions of mare and highland matter are consistent with derivation from a terrain close to a mare-highland boundary. However, a similar mixture might also develop through vertical mixing in a cryptomare or a region of thin mare coverage. Thus, unfortunately, the YQ bulk composition is not a very useful clue to the identity of the source crater.  相似文献   

Organohalogen compounds in deep-sea fishes from the western North Pacific, off-Tohoku, Japan: Contamination status and bioaccumulation profiles     

Shin Takahashi  Tomoko Oshihoi  Tomohiko Isobe  Tsunemi Kubodera 《Marine pollution bulletin》2010,60(2):187-196

Twelve species of deep-sea fishes collected in 2005 from the western North Pacific, off-Tohoku, Japan were analyzed for organohalogen compounds. Among the compounds analyzed, concentrations of DDTs and PCBs (up to 23,000 and 12,400 ng/g lipid wt, respectively) were the highest. The present study is the foremost to report the occurrence of brominated flame retardants such as PBDEs and HBCDs in deep-sea organisms from the North Pacific region. Significant positive correlations found between δ¹⁵N (‰) and PCBs, DDTs and PBDEs suggest the high biomagnification potential of these contaminants in food web. The large variation in δ¹³C (‰) values observed between the species indicate multiple sources of carbon in the food web and specific accumulation of hydrophobic organohalogen compounds in benthic dwelling carnivore species like snubnosed eel. The results obtained in this study highlight the usefulness of deep-sea fishes as sentinel species to monitor the deep-sea environment.  相似文献   

Holocene paleolimnological changes in Lake Skallen Oike in the Syowa Station area of Antarctica inferred from organic components in a sediment core (Sk4C-02)     

Genki I. Matsumoto  Yukinori Tani  Koji Seto  Tomoko Tazawa  Masumi Yamamuro  Takahiro Watanabe  Toshio Nakamura  Tetsuo Takemura  Satoshi Imura  Hiroshi Kanda 《Journal of Paleolimnology》2010,44(2):677-693

Antarctic climate changes influence environmental changes at both regional and local scales. Here we report Holocene paleolimnological changes in lake sediment core Sk4C-02 (length 378.0 cm) from Lake Skallen Oike in the Soya Kaigan region of East Antarctica inferred from analyses of sedimentary facies, a range of organic components, isotope ratios of organic carbon and nitrogen, and carbon-14 dating by Tandetron accelerator mass spectrometry. The sediment core was composed of clayish mud (378.0–152.5 cm) overlain by organic sediments (152.5 cm-surface). The age of the surface and the core bottom were 150 (AD1950-1640) and ca. 7,030 ± 73 calibrated years before present (cal BP), respectively, and the mean sedimentation rate was estimated to be 0.55 mm/year. Multi-proxy analyses revealed that the principal environmental change in the core is a transition from marine to lacustrine environments which occurred at a depth of 152.5 cm (ca. 3,590 cal BP). This was caused by relative sea level change brought about by ongoing retreat of glaciers during the mid-Holocene warming of Antarctica, and ongoing isostatic uplift which outpaced changes in global (eustatic) sea level. The mean isostatic uplift rate was calculated to be 2.8 mm/year. The coastal marine period (378.0–152.5 cm, ca. 7,030–3,590 cal BP) was characterized by low biological production with the predominance of diatoms. During the transition period from marine to freshwater conditions (152.5-approximately 135 cm, ca. 3,590–3,290 cal BP) the lake was stratified with marine water overlain by freshwater, with a chemocline and an anoxic (sulfidic) layer in the bottom of the photic zone. Green sulfur bacteria and Cryptophyta were the major photosynthetic organisms. The Cryptophyta appeared to be tolerant of the moderate salinity and stratified water conditions. The lacustrine period (approximately 135 cm-surface, ca. 3,290 cal BP-present) was characterized by high biological production by green algae (e.g. Comarium clepsydra and Oedegonium spp.) with some contributions from cyanobacteria and diatoms. Biological production during this period was 8.7 times higher than during the coastal marine period.  相似文献