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1.
Philippe E. Raison Regis Jardin Daniel Bouëxière Rudy J. M. Konings Thorsten Geisler Claudiu C. Pavel Jean Rebizant Karin Popa 《Physics and Chemistry of Minerals》2008,35(10):603-609
The crystallographic structures of the synthetic cheralite, CaTh(PO4)2, and its homolog CaNp(PO4)2 have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO4 (Ln = La to Gd). The space group is P21/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO4)2 are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R wp = 4.87%, R p = 3.69% and R B = 3.99%. For CaNp(PO4)2, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R wp = 6.74%, R p = 5.23%, and R B = 6.05%. The results indicate significant distortions of bond length and angles of the PO4 tetrahedra in CaTh(PO4)2 and to a lesser extent in CaNp(PO4)2. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO4)2. A comparison with the isostructural compounds LnPO4 (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca2+ and Th4+ introduces a distortion of the PO4 tetrahedra. 相似文献
2.
Seasonal DOC accumulation in the Black Sea: a regional explanation for a general mechanism 总被引：2，自引：0，他引：2
Gustave Cauwet Gaëlle Dliat Anton Krastev Galina Shtereva Sylvie Becquevort Christiane Lancelot Andr Momzikoff Alain Saliot Adriana Cociasu Lucia Popa 《Marine Chemistry》2002,79(3-4)
During three cruises in the Black Sea, organised in July 1995 and April–May 1997, biological and chemical parameters that can influence the carbon budget were measured in the water column on the NW shelf, particularly in the mixing zone with Danube River waters. We observed in early spring (end of April–May) conditions an important input of freshwater organisms that enhanced the microbial activity in the low salinity range. High bacterial activity regenerates nitrogen in the form of nitrates, but is also responsible for an important consumption of ammonium and phosphate, leading to a high N/P ratio and a strong deficit in phosphorus. The consequence is a limitation of phytoplankton development but also a production of carbohydrates that accumulate all along the salinity gradient. These mechanisms are responsible for a seasonal accumulation of dissolved organic carbon (DOC) that increases from 210 μM in winter to about 280 μM in summer. All this excess DOC disappears during winter, probably degraded by bacterial activity. The degradation of carbon-rich organic matter increases the phosphorus demand by bacteria bringing limitation to phytoplankton primary production. 相似文献
3.
V. Popa 《Astrophysics and Space Science》2000,273(1-4):305-312
We discuss the searches for massive magnetic monopoles and for nuclearitesin the penetrating cosmic radiation performed with the MACRO detector. Independent monopole analysis were carried out using the scintillator, streamer tubes and nuclear track sub-detectors in different ranges of velocity. No candidates were found in several years of data taking; present upper flux limits are well below the Parker bound in a wide velocity range. For nuclearites only the scintillator and nuclear track sub-detectors were used. 相似文献
4.
Calcic skarns and transversal zoning in the Banat mountains, Romania: indicators of an Andean-type setting 总被引：1，自引：1，他引：0
Ş. N. Vlad 《Mineralium Deposita》1997,32(5):446-451
Calcic skarn deposits related to Upper Cretaceous – Paleocene banatitic intrusions are widely developed in the Banat Mountains
(southwestern Romanian Carpathians). There is a spatial distribution of banatitic igneous rocks and associated ore deposits
in parallel zones, due to subduction beneath the southwest Carpathians. As a result three distinct petro-metallogenetic units
developed, i.e. marginal unit: Moldova Nouă– Sasca; median unit: Ciclova – Oravita; and the inner unit: Dognecea – Ocna de
Fier. The magmatism changed inland from monzonite and diorite → granodiorite occurrences to granodiorite → granite plutons.
The related mineralization shifted simultaneously from Cu (Mo) to Cu-Mo (W) and eventually Fe(Cu)/Pb-Zn. The distribution
of both magmatism and related ore deposits in parallel petro-metallogenetic zones is considered similar to that in the Andes.
In particular, calcic skarns and related ore deposits that occur in these units show a transversal zonal variation represented
by compositional features of pyroxene and granat, sequence of mineralization and metallogenetic environment. Such zonal characteristics
represent an additional but nonetheless significant indicator for an Andean-type subduction-related setting.
Received: 3 June 1996 / Accepted: 10 January 1997 相似文献
5.
The first 1,000 year long Carpathian tree-ring width chronology was established based on living and subfossil stone pine (Pinus cembra L.) samples from an upper timberline forest located in Calimani Mts. (Romania). Tree-ring data were standardized using the regional curve standardization method in order to preserve the low and medium frequency climate signals. The de-trended index strongly correlates with summer mean temperature both at annual and decadal scales. The Calimani summer mean temperature anomalies were reconstructed for the period ad 1163-2005 applying the rescaling method. This new climate proxy from the Carpathians shows similar fluctuations to other North Hemispheric temperature reconstructions, but with periods of distinct differences. The fingerprint of Little Ice Age in the Calimani area is visible between ad 1370 and 1630 followed by lagged cold decades in ad 1820 and 1840. The recent warming is evident only after the 1980s in our reconstruction. 相似文献
6.
Aurelian Andrei Radu Tatiana Angelescu Valentin Curtef Florin Delia Daniel Felea Ioana Goia Dumitru Ha?egan Bogdan Lucaschi Ancuta Manea Vlad Popa Ioan Rali?? Radu V?c?reanu 《Experimental Astronomy》2012,34(1):31-42
Around the world, several scientific projects share the interest of a global network of small Cherenkov telescopes for monitoring observations of the brightest blazars??the DWARF network. A small, ground based, imaging atmospheric Cherenkov telescope of last generation is intended to be installed and operated in Romania as a component of the DWARF network. To prepare the construction of the observatory, two support projects have been initiated. Within the framework of these projects, we have assessed a number of possible sites where to settle the observatory. In this paper we submit a brief report on the general characteristics of the best four sites selected after the local infrastructure, the nearby facilities and the social impact criteria have been applied. 相似文献
7.
8.
The orbital period variation of the oEA system Y Leo is revised by taking into account new times of minimum light covering
an extended time base of 101.8 yr. A multiperiodic ephemeris was finally established by carefully approaching the problem of periodicity detection for the considered periodic
components. A method relying on Monte Carlo simulations was applied. The problem of the long-term behaviour of the O–C curve was taken into account using parabolic, and parabolic + periodic ephemerides. The physical interpretation of the mathematical models describing both long- and short-term behaviour of the
O–C curve was performed by considering different mechanisms: the conservative mass transfer, the light-time effect, and the orbital
period modulation through the cyclic magnetic activity of the late spectral type secondary component in the system. The consequences
of these interpretations are rather intriguing and emphasize the need of new and detailed observational studies on Y Leo. 相似文献
9.
The aim of this paper is to describe a managing system for a unique Romanian database of historical seismograms and complementary documentation (metadata) and its dissemination and analysis procedure. For this study, 5188 historical seismograms recorded between 1903 and 1957 by the Romanian seismological observatories (Bucharest-Filaret, Foc?ani, Bac?u, Vrincioaia, Câmpulung-Muscel, Ia?i) were used. In order to reconsider the historical instrumental data, the analog seismograms are converted to digital images and digital waveforms (digitization/ vectorialisation). First, we applied a careful scanning procedure of the seismograms and related material (seismic bulletins, station books, etc.). In a next step, the high resolution scanned seismograms will be processed to obtain the digital/numeric waveforms. We used a Colortrac Smartlf Cx40 scanner which provides images in TIFF or JPG format. For digitization the algorithm Teseo2 developed by the National Institute of Geophysics and Volcanology in Rome (Italy), within the framework of the SISMOS Project, will be used. 相似文献
10.
Philippe E. Raison Stephen Heathman Gilles Wallez Carmen E. Zvoriste Denis Bykov Ga?l Ménard Emmanuelle Suard Karin Popa Nicolas Dacheux Rudy J. M. Konings Roberto Caciuffo 《Physics and Chemistry of Minerals》2012,39(8):685-692
The crystal structure of the cheralite—CaTh(PO4)2—has been revisited by neutron diffraction and its behaviour under high pressure investigated by X-ray diffraction up to 36?GPa. The neutron diffraction data at ambient pressure gave a more accurate determination of the Ca/Th cation position than previous XRD data, taking advantage that the neutron scattering lengths of calcium and thorium are of same order of magnitude. The nuclear density distribution was also determined using the maximum entropy method (MEM) confirming that the two cations are not located at the same position in the unit cell but are slightly displaced from one another along a specific direction in order to minimize the electrostatic repulsion with the surrounding phosphorus atoms. At high pressure, the compound did not show any phase transition or amorphization. From the evolution of the unit-cell volume as a function of the pressure, the zero-pressure bulk modulus B0 and its pressure derivative B0 ′ have been determined by fitting the experimental compressibility curve to the Birch–Murnaghan equation of state. The results are B0?=?140(2) GPa and B 0 ′ ?=?4.4(4) GPa. 相似文献