Der Pyroxentuff vom Heilsberg im Hegau     

Dr. D. Knöfel  Prof. Dr. W. v. Engelhardt 《Contributions to Mineralogy and Petrology》1964,9(6):503-518

Zusammenfassung Das Tuffvorkommen vom Heilsberg bei Gottmadingen im Hegau wurde neu kartiert und mineralogisch untersucht. Die Korngrößenverteilung zeigt ein deutliches Maximum bei 0,6–1,2 mm. Der Tuff besteht aus 40% magmatogenem Material und 60% Bestandteilen des durchschlagenen Untergrundes. Die magmatogenen Komponenten sind 17% Einzehnineralien, 10% Grundmasse und 13 % Auswürflinge. Unter den Einzelmineralien wiegt der Pyroxen (Fassait) vor, daneben kommen Amphibol, Biotit und Magnetit, ferner Apatit und Analcim sowie einige seltenere Mineralien vor. Für Pyroxen, Amphibol, Biotit und Magnetit werden chemische Analyse und optische Eigenschaften mitgeteilt. Die größte Menge der magmatogenen Auswürflinge sind kugelförmige Lapilli, die hinsichtlich ihrer Entstehung genauer untersucht und chemisch analysiert wurden. Seltener sind grobkristalline, dunkle und belle Bomben, deren Mineralgehalt und chemische Zusammonsetzung genauer beschrieben werden. Sic stellen wahrscheinlich Differentiate des Heilsbergmagmas dar. Die ehemals glasige, magmatogene Grundmasse des Tuffs liegt heute als ein Gemenge von Montmorillonit und Calcit vor.Aus den nichtmagmatogenen Bestandteilen kann auf den Untergrund im Bereich des Heilsbergvulkans geschlossen werden. Aus dem Deckgebirge wurden Tertiär, Mahn, Dogger, Jura, Keuper und Muschelkalk nachgewiesen. Das Grund-gebirge besteht hauptsächlich aus granodioritischen bis granitischen Gesteinen und enthält auffallenderweise nur wenig Gneise. Der Herd der Eruption dürfte mindestens 4000 m tief liegen.Der Chemismus des Heilsbergmagmas ist hornblenditisch. Es ist dem Magma der Melilithite verwandt und leitet zu den Phonolithen des Hegau über. Das Gestein ist als hornblenditischer Pyroxen-Analcim-Tuff zu bezeichnen.Zwei unabhängige Bestimmungen nach der K-Ar-Methode ergaben für den Biotit des Tuffs ein obermiozänes Alter von 14,0 bzw. 14,5 Mill. Jahren.Mit 2 Textabbildungen  相似文献   

Changes in the winter precipitation in Romania and its relation to the large-scale circulation   总被引：1，自引：0，他引：1  

ARISTITA BUSUIOC  HANS VON STORCH 《地球，A辑:动力气象学与海洋学》1996,48(4):538-552

  相似文献   

A large-scale meandering submarine canyon: outcrop example from the late Proterozoic Adelaide Geosyncline, South Australia     

C.C. VON DER  BORCH  A. E. GRADY  R. ALDAM  D. MILLER  R. NEUMANN  A. ROVIRA  K. EICKHOFF 《Sedimentology》1985,32(4):507-518

The late Proterozoic Adelaide Geosyncline, along with overlying Cambrian strata, comprises a thick sequence of sediments and sparse volcanics which accumulated in a major rift and passive margin setting. During late syn-rift or early post-rift phases, large volumes of terrigenous and carbonate sediments of the late Proterozoic Umberatana and Wilpena Groups and Cambrian Hawker Group filled the rift. Submarine canyon development was related to at least four of these depositional cycles, the most notable of which resulted in incision and subsequent filling of the major (several kilometres in width and up to 1.5 km deep) submarine canyons by the Wonoka Formation. The Wonoka Formation canyons are not obviously fault controlled. They are interpreted to have been eroded by turbidity currents during a relative low-stand of sea-level. They were subsequently filled by a fining-upwards suite of sediments which reflects subsequent relative rise of sea-level and carbonate platform development. Ultimately the canyon complex was buried by north-westerly progradation of overlying fluvial and slope sequences (Billy Springs Beds and possibly correlative upper Pound Subgroup). It is considered likely that more distal elements of this prograding clastic wedge provided the necessary material for canyon erosion, prior to canyon filling and ultimate burial by what may have been elements of the same depositional cycle. It is considered possible that the series of isolated outcrops of canyon cross-sections within the Wonoka Formation are sections of a single canyon thalweg developed within a considerably broader zone of slope degradation. If this interpretation is correct, then the gorge-like Patsy Springs Canyon lies in more proximal regions of the basin-slope, whereas 40 km to the north-east the lower slope is cut by the Fortress Hill Canyon Complex. Palaeocurrent analyses of channel-fill turbidites within the canyons imply that the Fortress Hill Complex is in fact the outcropping western edge of a sinuous, incised canyon thalweg. The Wonoka Formation canyons, containing basal sedimentary breccias but only minor conglomerates, are considered typical of passive margin canyon development. They are contrasted with the generally highly conglomeratic channel-fills observed in outcropping Tertiary and Cretaceous examples of active margin canyons and upper fan valleys.  相似文献   

Suevite of the ries crater,Germany: Source rocks and implications for cratering mechanics     

Prof. Dr. Wolf von Engelhardt  Günther Graup 《International Journal of Earth Sciences》1984,73(2):447-481

Suevites are impact breccias with a montmorillonitic matrix that contains shocked and unshocked mineral and rock fragments from the crystalline basement, glass inclusions and a small amount of sedimentary clasts. Data are given of the modal composition of fall-out suevites (deposited at isolated points around the crater) and crater suevite (forming a layer below post-impact lake sediments in the crater cavity). Fall-out suevites contain aerodynamically shaped bombs which are absent in crater suevite. Taking into account not only large glass fragments and bombs, but also the finer fractions, the glass content of fall-out and crater suevites amounts to 47 and 29 vol%, respectively. Crystalline clasts in suevites consist of all igneous and metamorphic rock types that constitute the local basement which consists of an upper layer of igneous rocks (mainly granites) and a lower series of gneisses and amphibolite. Based on a collection of 1 200 clasts from 13 suevite occurrences the average crystalline clast population of suevites was determined. Suevites contain on the average 46 % igneous and 54 % metamorphic clasts. In constrast, weakly shocked and unshocked crystalline ejecta of the Ries structure consist of 82 % igneous and 18 % metamorphic rocks. From 138 analyses of crystalline rock samples average compositions of the major rock types were calculated. Comparison of these averages with the average glass composition leads to the conclusion that suevite glasses were formed by shock melting of gneisses in deeper levels of the basement. Suevite matrices consist in most cases of 80 to 90 % montmorillonite, in special cases of celadonite. Chemical analyses are given of some matrices and montmorillonite formulas calculated. It is supposed that montmorillonite was formed by early hydrothermal alteration of rock flour or fine glass particles. In the latter case the original glass content of suevites was higher than at present. Of all ejecta from the Ries crater only crystalline rocks contained in suevites occur in all stages of shock metamorphism up to complete fusion. The overwhelming majority of the ejecta from the sedimentary sequence (about 580 m) show no indications of shock pressures above 10 GPa. The same holds true for crystalline megablocks and breccias around the crater which consist mainly of granites from upper levels of the basement. We assume that the Ries impact can be approximated by a deep-burst model: The projectile penetrated through the sedimentary cover into the basement in such a way that the highest pressures and temperatures developed within the gneiss complex below the upper, predominately granitic layer and that rocks of the sedimentary sequence experienced weak shock compression. Numerical data are given for such a model of the Ries impact on transient crater geometry and volumes of vaporized, melted, shocked and excavated rocks. Fall-out suevites are supposed to have been lifted from the central zone by an expanding plume of vaporized rocks and deposited as fluidized turbulent masses outside the crater whereas the main mass of crater suevite was not removed from the crater cavity.  相似文献   

Stable isotope study of carbonate sediments from the Coorong Area, South Australia     

REINER W. BOTZ†  CHRISTOPHER C. VON DER  BORCH† 《Sedimentology》1984,31(6):837-849

ABSTRACT
The mineralogy and isotope geochemistry of carbonate minerals in the Coorong area are determined by the water chemistry of different depositional environments ranging from seawater to evaporitically modified continental water. The different isotopic compositions of coexisting calcite and dolomite suggest that each of the above two minerals was formed from water of composition and origin unique to that specific mineral. In addition, the dolomite was not formed by simple solid state cation exchange.
The occurrence of two types of dolomite was shown by isotope analysis and SEM observations. The dolomite, which is isotopically light (δ¹³C = -1 to -2% 0 ; δ¹⁸O=+3 to +5%₀) and of fine grain size (˜ 0·5 μm) probably precipitated under the influence of evaporitically modified continental water. Coarser grained dolomite (up to 4 μm) is isotopically heavier (δ¹³C=+3 to +4%₀; δ¹⁸O=+5 to + 6%₀) contains Mg in excess of Ca and was formed in or close to equilibrium with atmospheric CO² probably by the dolomitization of aragonite.  相似文献   

Trace analysis of quaternary aminoalcohols as degradation products from softeners in wastewater     

H. Engelhardt  W. Gtzinger  M. Krmer  R. Wintringer 《洁净——土壤、空气、水》1995,23(4):173-179

The sensitive and selective determination of polyalcohols without chromophores or fluorophores in the lower ppb-level is still an analytical task of high interest, especially in the field of environmental investigations. This paper describes a cation-exchange HPLC procedure for the separation and fluorescence detection of two quaternary ammonium compounds with polyalcoholic groups (degradation products of fabric softener) after derivatization with 9-fluorenylmethyl chloroformate (FMOC). Detailed experiments were carried out to determine optimum reaction conditions (pH, reaction time, temperature), linear range, detection limits, and kinetics of the reaction. The HPLC separation on a cation-exchange column includes a gradient program which provides complete separation from neutral compounds also reacting with FMOC and its hydrolysis products formed during the reaction in alkaline medium. High specificity for both investigated ammonium compounds with detection limits in the range of 1 ppb could be achieved.  相似文献   

The Zircon-Bearing Chromitites of the Phlogopite Peridotite of Finero (Ivrea Zone, Southern Alps): Evidence and Geochronology of a Metasomatized Mantle Slab   总被引：6，自引：0，他引：6  

GRIECO  G.; FERRARIO  A.; VON QUADT  A.; KOEPPEL  V.; MATHEZ  E. A. 《Journal of Petrology》2001,42(1):89-101

The phlogopite peridotite unit of the Finero Complex is a restiticharzburgite that records two metasomatic events. The first eventis related to the intrusion of basaltic magma, which reactedwith the pyroxene of the host harzburgite to produce chromititepods with dunite haloes. It also produced secondary clinopyroxeneand amphibole in the harzburgite and enriched harzburgite inNa and the light rare earth elements. The second metasomaticevent is related to the later intrusion of clinopyroxeniticdykes. During this event, water-rich vapour penetrated the harzburgitealong fractures and reacted with it to form phlogopite, thusenriching the rock in K. Chromitites host zircons that yieldan age for the first metasomatic event of 207·9 + 1·7/-1·3Ma, during which time extensional tectonics prevailed in theSouthern Alps. KEY WORDS: metasomatism; chromitite; zircon; geochronology; Finero  相似文献   

14C DATES OF CALCAREOUS SAMPLES,HERON ISLAND,GREAT BARRIER REEF1     

KARL H. WOLF  G TE STLUND 《Sedimentology》1967,8(3):249-251

Two samples of plant-rich limy sand collected from the 9- and 11-ft.-level of the Heron Island cay were subjected to ¹⁴C dating. Uncertainties related to secondary changes and contaminations, and the unknown transportation history of the woody material prior to accumulation at Heron Island, in combination with the relatively young age of the carbon, did not result in ¹⁴C values useful for correlation and absolute dating purposes.  相似文献   

Petrology,chemistry, and isotopic compositions of the lunar highland regolith breccia Dar al Gani 262     

A. BISCHOFF  D. WEBER  R. N. CLAYTON  T. FAESTERMANN  I. A. FRANCHI  U. HERPERS  K. KNIE  G. KORSCHINEK  P. W. KUBIK  T. K. MAYEDA  S. MERCHEL  R. MICHEL  S. NEUMANN  H. PALME  C. T. PILLINGER  L. SCHULTZ  A. S. SEXTON  B. SPETTEL  A. B. VERCHOVSKY  H. W. WEBER  G. WECKWERTH  D. WOLF 《Meteoritics & planetary science》1998,33(6):1243-1257

Abstract— Lunar meteorite Dar al Gani 262 (DG 262)—found in the Libyan part of the Sahara—is a mature, anorthositic regolith breccia with highland affinities. The origin from the Moon is undoubtedly indicated by its bulk chemical composition; radionuclide concentrations; noble gas, N, and O isotopic compositions; and petrographic features. Dar al Gani 262 is a typical anorthositic highland breccia similar in mineralogy and chemical composition to Queen Alexandra Range (QUE) 93069. About 52 vol% of the studied thin sections of Dar al Gani 262 consist of fine-grained(100 μm) constituents, and 48 vol% is mineral and lithic clasts and impact-melt veins. The most abundant clast types are feldspathic fine-grained to microporphyritic crystalline melt breccias (50.2 vol%; includes recrystallized melt breccias), whereas mafic crystalline melt breccias are extremely rare (1.4 vol%). Granulitic lithologies are 12.8 vol%, intragranularly recrystallized anorthosites and cataclastic anorthosites are 8.8 and 8.2 vol%, respectively, and (devitrified) glasses are 2.7 vol%. Impact-melt veins (5.5 vol% of the whole thin sections) cutting across the entire thin section were probably formed subsequent to the lithification process of the bulk rock at pressures below 20 GPa, because the bulk rock never experienced a higher peak shock pressure. Mafic crystalline melt breccias are very rare in Dar al Gani 262 and are similar in abundance to those in QUE 93069. The extremely low abundance of mafic components and the bulk composition may constrain possible areas of the Moon from which the breccia was derived. The source area of Dar al Gani 262 must be a highland terrain lacking significant mafic impact melts or mare components. On the basis of radionuclide activities, an irradiation position of DG 262 on the Moon at a depth of 55–85 g/cm³and a maximum transit time to Earth <0.15 Ma is suggested. Dar al Gani 262 contains high concentrations of solar-wind-implanted noble gases. The isotopic abundance ratio ⁴⁰Ar/³⁶Ar < 3 is characteristic of lunar soils. The terrestrial weathering of DG 262 is reflected by the occurrence of fractures filled with calcite and by high concentrations of Ca, Ba, Cs, Br, and As. There is also a large amount of terrestrial C and some N in the sample, which was released at low temperatures during stepped heating. High concentrations of Ni, Co, and Ir indicate a significant meteoritic component in the lunar surface regolith from which DG 262 was derived.  相似文献   

Geophysical profile of the Roter Kamm impact crater,Namibia     

DION BRANDT  WOLF UWE REMOLD  ALAN J. FRANZSEN  CHRISTIAN KOEBERL  LUTZ WENDORFF 《Meteoritics & planetary science》1998,33(3):447-453

Abstract— New gravity and magnetic data were obtained along ground profiles across the Roter Kamm impact crater in the southern Namib desert of Namibia. As the traverses of previous studies did not extend sufficiently beyond the crater rim, it had not been possible to adequately determine the regional background values. The gravity results of this study are similar to those obtained by Fudali in 1973, in that a negative, near-symmetrical anomaly was obtained over the crater center. This anomaly conforms to the results expected for a sediment and impact breccia-filled, simple bowl-shaped crater. The magnetic results of this study, however, are different to those previously reported, which is most probably as a result of the longer profiles used in this new study. A slight positive magnetic anomaly was obtained over the crater interior. Short-wavelength, high-amplitude anomalies observed in the vicinity of the crater rim reflect magnetization contrasts that are probably related to brecciation and block rotation. Modelling of the positive magnetic anomaly indicates the possibility of a small magnetic body or lining at the crater floor-breccia interface in the interior of the crater. Also presented is a 10 m contour digital elevation model of the crater and its environs.  相似文献