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1.
Ricard A Cernogora G Fitaire M Hochard L Kouassi N Speller C Vacher JR 《Planetary and Space Science》1995,43(1-2):41-46
The kinetic reactions in N2-xCH4(C2H2) gas discharges with x less than 1% have been studied by emission spectroscopy in the afterglow of D.C. discharges and by mass spectroscopy from radiolysis ionization using alpha particles. The pressure range is from several Torr to 100 Torr. At the end of N2 D.C. discharges at room temperature, for a residence time of about 10(-2) s, the dominant active species are the N atoms with density of 10(14)-10(15) cm-3 for N2 density of about 10(17) cm-3 (3 Torr), the N2(X,V) vibrational molecules with for example [N2(X,V = 10)] approximately 10(14) cm-3 and the electronic metastable molecules N2(A 3 sigma u +) with a density of 10(12) cm-3. In such conditions, the following kinetic reactions have been studied: N2(A) + N2(A) --> N2(C,B,V') + N2(X), N2(A) + N2(X,V>5) --> N2(X) + N2(B,V') in pure N2 post-discharges and N2(A) + CH4 --> products, C + N + M2 --> CN(B,V') + M2, N2(X,V>4) + CN --> N2(X) + CN(B,A,V'), in N2-1% CH4 post-discharges. The clustering reactions of N2-(1-5%)CH4(C2H2) gas mixtures after radiolysis ionization have been studied for the H2CN+ nN2 ions and the equilibrium constants have been determined in the temperature range T = 140-300 K. 相似文献
2.
Upscaling is a major issue regarding mechanical and transport properties of rocks. This paper examines three issues relative
to upscaling. The first one is a brief overview of Effective Medium Theory (EMT), which is a key tool to predict average rock
properties at a macroscopic scale in the case of a statistically homogeneous medium. EMT is of particular interest in the
calculation of elastic properties. As discussed in this paper, EMT can thus provide a possible way to perform upscaling, although
it is by no means the only one, and in particular it is irrelevant if the medium does not adhere to statistical homogeneity.
This last circumstance is examined in part two of the paper. We focus on the example of constructing a hydrocarbon reservoir
model. Such a construction is a required step in the process of making reasonable predictions for oil production. Taking into
account rock permeability, lithological units and various structural discontinuities at different scales is part of this construction.
The result is that stochastic reservoir models are built that rely on various numerical upscaling methods. These methods are
reviewed. They provide techniques which make it possible to deal with upscaling on a general basis. Finally, a last case in
which upscaling is trivial is considered in the third part of the paper. This is the fractal case. Fractal models have become
popular precisely because they are free of the assumption of statistical homogeneity and yet do not involve numerical methods.
It is suggested that using a physical criterion as a means to discriminate whether fractality is a dream or reality would
be more satisfactory than relying on a limited data set alone. 相似文献
3.
A87Rb-87Sr analysis of some enstatite meteorites has been made. Whole rocks plot on an isochron of age 4.508 ± 0.037b.y. and strontium initial ratio 0.69880 ± 0.00044 (2σ errors; λ87Rb= 1.42 × 10?11yr?1) . If the Norton County results are joined, we get an age of 4.516 ± 0.029b.y. and initial ratio of 0.69874 ± 0.00022. This result is indistinguishable from the whole rock isochron for H chondrites. It is interpreted as the age of condensation from the solar nebula. The identity of the87Sr/86Sr initial ratio with the ones for Allende white inclusions shows that this ratio was homogeneous in the solar nebula, and that the Rb-Sr fractionations observed between the different chondrite groups appeared only shortly before or during condensation accretion.Internal studies of the type-I enstatite chondrites Abee and Indarch and the intermediate-type Saint Mark's and Saint Sauveur have been done.Abee data scatter in the87Rb-87Sr diagram. For Indarch, Saint Mark's and Saint Sauveur, we obtained well-defined straight lines of “age” (T) and “initial ratio” (I): Indarch,T = 4.393 ± 0.043b.y.I = 0.7005 ± 0.0009; Saint Mark's,T = 4.335 ± 0.050b.y.I = 0.69979 ± 0.00022; Saint Sauveur,T = 4.457 ± 0.047b.y.I = 0.6993 ± 0.0014. Our result on Indarch agrees with the former result of Gopalan and Wetherill [5].A careful examination of the data shows that these straight lines are neither due to leaching effects by heavy liquids, nor result from terrestrial weathering. The “isochrons” for Indarch and Saint Sauveur can be mixing lines between enstatite and feldspar. The results are interpreted in terms of cosmochemical secondary effects: type-I and intermediate-type enstatite chondrites have been shocked 60–200 m.y. after their formation. This agrees with the idea of an early generalized bombardment of the inner solar system; this also indicates that type-I enstatite chondrites were rather situated in the outershells of their parent body and might be at the origin of the scatter of I-Xe ages of enstatite meteorites.Whole rock and enstatite from Bishopville, Cumberland Falls and Mayo Belwa have also been analysed. In these three aubrites, the87Rb-87Sr system is perturbed. Our Bishopsville sample might not be fresh and this makes the significance of our results uncertain. Cumberland Falls and Mayo Belwa probably suffered relatively recent shocks and open-system redistribution of Rb and Sr. 相似文献
4.
The formation of narrow, rapidly deforming plate boundaries separating strong plate interiors are integral components of the generation of plate tectonics from mantle convection. The development of narrow plate boundaries requires the interaction of a non-linear rheology and convection. One such non-linear rheology is two-phase damage theory which employs a non-equilibrium relation between interfacial surface energy, pressure and viscous deformation, thereby forming a theoretical model for void generation. Two-phase damage theory was recently extended to allow for deformational work to increase the fineness (reduce the grain size) of the matrix phase. We present results testing two-phase damage theory in a 2-D convectively driven system where we allow for (1) pure void-generating damage, (2) pure fineness-generating damage and (3) combined void- and fineness-generating damage. Pure void-generating damage is found to be unsuccessful at producing plate-like features. Fineness-generating damage is successful at inducing plate-like behaviour in certain circumstances, including increasing viscosity sensitivity to fineness and certain regimes of damage input and healing rate. Cases with combined void- and fineness-generating damage produce significantly more localization than the end-members due to the apparent increase of deformational work input into fineness generation. The interaction of microcracks and grain size reduction in two-phase damage theory suggests a rheological model for shear localization necessary for the formation of plate tectonic boundaries. 相似文献
5.
Heather A. Sheldon Brendan Florio Michael G. Trefry Lynn B. Reid Ludovic P. Ricard K. Ameed R. Ghori 《Hydrogeology Journal》2012,20(7):1251-1268
Convection of groundwater in aquifers can create areas of anomalously high temperature at shallow depths which could be exploited for geothermal energy. Temperature measurements in the Perth Basin (Western Australia) reveal thermal patterns that are consistent with convection in the Yarragadee Aquifer. This observation is supported by Rayleigh number calculations, which show that convection is possible within the range of aquifer thickness, geothermal gradient, salinity gradient and permeability encountered in the Yarragadee Aquifer, assuming that the aquifer can be treated as a homogeneous anisotropic layer. Numerical simulations of convection in a simplified model of the Yarragadee Aquifer show that: (1) the spacing of convective upwellings can be predicted from aquifer thickness and permeability anisotropy; (2) convective upwellings may be circular or elongate in plan view; (3) convective upwellings create significant temperature enhancements relative to the conductive profile; (4) convective flow rates are similar to regional groundwater flow rates; and (5) convection homogenises salinity within the aquifer. Further work is required to constrain the average horizontal and vertical permeability of the Yarragadee Aquifer, to assess the validity of treating the aquifer as a homogeneous anisotropic layer, and to determine the impact of realistic aquifer geometry and advection on convection. 相似文献
6.
L.B. Reid G. Bloomfield L.P. Ricard C. Botman P. Wilkes 《Australian Journal of Earth Sciences》2013,60(7):1033-1048
Exploration of Perth's geothermal potential has been performed by the Western Australian Geothermal Centre of Excellence (WAGCoE). Detailed vertical temperature and gamma ray logging of 17 Western Australia Department of Water's (DoW) Artesian Monitoring (AM) wells was completed throughout the Perth Metropolitan Area (PMA). In addition, temperature logs from 53 DoW AM wells measured in the 1980s were digitised into LAS format. The logged data are available in the WAGCoE Data Catalogue. Analysis of the gamma ray logs yielded the first estimates of radiogenic heat production in Perth Basin formations. Values by formation ranged between 0.24 and 1.065 μW m?3. The temperature logs provide a picture of true formation temperatures within shallow sediments in the Perth Basin. A three-dimensional model of the temperature distribution was used to produce maps of temperature at depth and on the top of the Yarragadee aquifer. The temperature data were interpreted with a one-dimensional conductive heat model. Significant differences between the model and the observations was indicative of heat moving via non-conductive mechanisms, such as advection or convection. Evidence of non-conductive or advective heat flow is demonstrated in most formations in the region, with significant effects in the aquifers. Average conductive geothermal gradients range from 13°C km?1 to 39°C km?1, with sandstone formations exhibiting average gradients of approximately 25°C km?1, while insulating silt/shale formations show higher average gradients of over 30°C km?1. To produce preliminary heat flow estimates, temperature gradients were combined with thermal conductivities measured elsewhere. The geometric mean heat flow estimates range between 64 mW m?2 to 91 mW m?2, with the standard deviation of the arithmetic mean heat flow ranging between 15 and 23 mW m?2. The study characterises the shallow temperature regime in the Perth Metropolitan Area, which is of direct relevance towards developing commercial geothermal projects. 相似文献
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Topography and geoid due to lithospheric mass anomalies 总被引：3，自引：0，他引：3
10.
Jean-François Royer Daniel Cariolle Fabrice Chauvin Michel Déqué Hervé Douville Rong-Ming Hu Serge Planton Annie Rascol Jean-Louis Ricard David Salas Y Melia Florence Sevault Pascal Simon Samuel Somot Sophie Tyteca Laurent Terray Sophie Valcke 《Comptes Rendus Geoscience》2002,334(3):147-154
Two climate simulations of 150 years, performed with a coupled ocean/sea-ice/atmosphere model including stratospheric ozone, respectively with and without heterogeneous chemistry, simulate the tropospheric warming associated with an increase of the greenhouse effect of carbon dioxide and other trace gases since 1950 and their impact on sea–ice extent, as well as the stratospheric cooling and its impact on ozone concentration. The scenario with heterogeneous chemistry reproduces the formation of the ozone hole over the South Pole from the 1970s and its deepening until the present time, and shows that the ozone hole should progressively fill during the coming decades. To cite this article: J.-F. Royer et al., C. R. Geoscience 334 (2002) 147–154. 相似文献