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1.
Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (pFe) is larger than the partial pressure at equilibrium (pFe(eq)). The supersaturation ratio S = pFe/pFe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H2O ? H2 + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.  相似文献   
2.
Abstract— We review the petrology of Baszkówka, present new microprobe data on mineral constituents, and propose a model for surface properties of the parent body consistent with these data. The low shock index and high porosity of the Baszkówka L5 chondrite mean that considerable primary textural and petrographic detail is preserved, allowing insight into the structure and evolution of the parent body. This meteorite formed in a sedimentary environment resembling that in which pyroclastic rocks are deposited. The origin of the component chondrules, achondritic fragments (mostly olivine and pyroxene aggregates), chondritic‐achondritic aggregates, and compound chondrules can be explained by invoking collision of 2 melted or partially melted planetesimals, each covered with a thin crust. This could have happened at an early stage in the evolution of the solar system, between 1 and 2 Myr after its origin. The collision resulted in the formation of a cloud containing products of earlier magmatic crystallization (chondrite and achondrite fragments) from which new chondrules were created. Particle collision in this cloud produced fragmented chondrules, chondritic‐achondritic aggregates, and compound chondrules. Within this low‐density medium, these particles were accreted on the surface of the larger of the planetesimals involved in the collision. The density of the medium was low enough to prevent grain‐size sorting of the components but high enough to prevent the total loss of heat and to enable the welding of fragments on the surface of the body. The rock material was homogenized within the cloud and, in particular, within the zone close to the planetesimal surface. The hot material settled on the surface and became welded as molten or plastic metal, and sulfide components cemented the grains together. The process resembled the formation of welded ignimbrites. Once these processes on the planetesimal surface were completed, no subsequent recrystallization occurred. The high porosity of the Baszkówka chondrite indicates that the meteorite comes from a near‐surface part of the parent body. Deeper parts of the planetesimal would have been more massive because of compaction.  相似文献   
3.
4.
The silicate carbon star V778 Cyg is a source of 22-GHz water maser emission which was recently resolved by MERLIN. Observations revealed an elongated     -like structure along which the velocities of the maser features show a linear dependence on the impact parameter. This is consistent with a doubly warped   m = 2  disc observed edge-on. Water masers and silicate dust emission (detected by the Infrared Astronomical Satellite and Infrared Space Observatory ) have a common origin in O-rich material and are likely to be co-located in the disc. We propose a detailed self-consistent model of a masing gas–dust disc around a companion to the carbon star in a binary system, which allows us to estimate the companion mass of  1.7 ± 0.1 M  , the disc radius of  40 ± 3  au and the distance between companions of ∼80 au. Using a dust–gas coupling model for water masing, we calculate the maser power self-consistently, accounting for both the gas and the dust energy balances. Comparing the simulation results with the observational data, we deduce the main physical parameters of the masing disc, such as the gas and dust temperatures and their densities. We also present an analysis of the stability of the disc.  相似文献   
5.
This is a critical assessment of the paper by Oszczypko et al. (2004: Cretaceous Research 25, 89–113), in which they tried to prove a mid-Cretaceous age for the Szlachtowa (“black flysch”) and Opaleniec Formations, in the Pieniny Klippen Belt, West Carpathians, both of which had previously been shown to be of Jurassic age. We argue that the mid-Cretaceous age assignment is a misinterpretation, primarily resulting from their field samples having been collected from some Cretaceous lithostratigraphic units, tectonically associated with the Jurassic formations, and/or from tectonic contact-breccias involving Jurassic and Cretaceous strata. In addition, we suggest that they have overlooked a number of significant palaeontological papers, published since 1962, which record the presence of in situ ammonites, aptychi, belemnites, thin-shelled bivalves (Bositra), gryphaeids, foraminifera, and ostracod assemblages, all indicating a Jurassic (mainly Aalenian), and not a Cretaceous, age for the Szlachtowa Formation, and also the in situ Jurassic (Bajocian) ammonites and thin-shelled bivalves (Bositra), Bositra-microfacies, and age-diagnostic foraminiferal assemblages of the Opaleniec Formation.Our presentation here of recently published dinocyst data from well-preserved assemblages further supports the Jurassic ages for the Szlachtowa (“black flysch”) and Opaleniec Formations.  相似文献   
6.
The determination of the bottom of a subfossil meandering palaeochannel is important for investigations of the palaeohydrology of valley bottoms, and crucial for the quantitative estimation of past river discharges. The authors present a procedure on the basis of which the bottom of a palaeochannel can be precisely determined. It is based on an analysis of the stratigraphic variability of such features of deposits as: mean diameter, standard deviation of the grain-size composition, the percentage of sand, and ignition loss.  相似文献   
7.
Fluorine content has been determined non destructively in eighty international geochemical reference samples (GRS) including rocks, soils, sediments, minerals and ores, by proton induced gamma ray emission spectrometry (PIGE) using the nuclear reaction 19F(p,αγ) 16O. Under our operating conditions, the detection limit is around 25 ppm. Our analytical results are compared with the presently preferred values when available or with other published data. The general agreement between this work and reported values is reasonably good. The present paper includes results on several GRS for which existing data are rather scarce or even inexistant.  相似文献   
8.
Abstract— Lunar meteorite Dar al Gani 262 (DG 262)—found in the Libyan part of the Sahara—is a mature, anorthositic regolith breccia with highland affinities. The origin from the Moon is undoubtedly indicated by its bulk chemical composition; radionuclide concentrations; noble gas, N, and O isotopic compositions; and petrographic features. Dar al Gani 262 is a typical anorthositic highland breccia similar in mineralogy and chemical composition to Queen Alexandra Range (QUE) 93069. About 52 vol% of the studied thin sections of Dar al Gani 262 consist of fine-grained(100 μm) constituents, and 48 vol% is mineral and lithic clasts and impact-melt veins. The most abundant clast types are feldspathic fine-grained to microporphyritic crystalline melt breccias (50.2 vol%; includes recrystallized melt breccias), whereas mafic crystalline melt breccias are extremely rare (1.4 vol%). Granulitic lithologies are 12.8 vol%, intragranularly recrystallized anorthosites and cataclastic anorthosites are 8.8 and 8.2 vol%, respectively, and (devitrified) glasses are 2.7 vol%. Impact-melt veins (5.5 vol% of the whole thin sections) cutting across the entire thin section were probably formed subsequent to the lithification process of the bulk rock at pressures below 20 GPa, because the bulk rock never experienced a higher peak shock pressure. Mafic crystalline melt breccias are very rare in Dar al Gani 262 and are similar in abundance to those in QUE 93069. The extremely low abundance of mafic components and the bulk composition may constrain possible areas of the Moon from which the breccia was derived. The source area of Dar al Gani 262 must be a highland terrain lacking significant mafic impact melts or mare components. On the basis of radionuclide activities, an irradiation position of DG 262 on the Moon at a depth of 55–85 g/cm3and a maximum transit time to Earth <0.15 Ma is suggested. Dar al Gani 262 contains high concentrations of solar-wind-implanted noble gases. The isotopic abundance ratio 40Ar/36Ar < 3 is characteristic of lunar soils. The terrestrial weathering of DG 262 is reflected by the occurrence of fractures filled with calcite and by high concentrations of Ca, Ba, Cs, Br, and As. There is also a large amount of terrestrial C and some N in the sample, which was released at low temperatures during stepped heating. High concentrations of Ni, Co, and Ir indicate a significant meteoritic component in the lunar surface regolith from which DG 262 was derived.  相似文献   
9.
An underground gravity study was carried out under extreme conditions of the Alpine regions. The lead–zinc mine Bleiberg, Carinthia, was selected as an example to show the possibilities and limitations of the subsurface gravity method. For in situ density determinations, gravity measurements were made in two vertical mine shafts passing through Triassic sedimentary rocks of the Bleiberg Unit. The main prblem in gravity data reduction in extremely rugged topography is the accurate calculation of the terrain effect on underground stations. A general discussion of the various corrections required for the gravity measurements in the mine is presented. The mean interval densities in the two shafts, in limestone, dolomite, and schists formations, were determined as 2.76 and 2.77 g/cm3, respectively, with an accuracy of better than 0.01 g/cm3 for a depth interval of 50 m. The interval densities provide valuable information about the lithological and structural changes in the shaft surroundings and also agree well with the representative hand sample densities. In the second part, the applications of subsurface horizontal gravity surveys in exploration are discussed. Since the influence of topography is less underground because of the greater distance to the surface, subsurface surveys have definite advantages over surface surveys and can be very helpful in locating anomalous density zones in the mines. An example of gravity survey with a station spacing of 10 m at a depth of about 540 m is presented.  相似文献   
10.
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