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To determine the estrogenicity of effluents from sewage treatment plants (STPs) to larval fish, 2-day-old sunshine bass were exposed to effluents from three STPs serving New York City (NYC), varying in size and treatment level. Estrogenic response was evaluated by measuring vitellogenin (VTG) and estrogen receptor (ER) expression in cytosolic fractions of whole body homogenates. Concentrations of the presumptive endocrine disruptors in the effluents were also measured. VTG and ER levels in sewage-exposed fish were 3-5 times that observed in controls. Combined concentrations of estradiol and estrone ranged from 5 to 13 ng/l and nonylphenol-ethoxylate metabolites (NPEOs: 4-nonylphenol, and 1-, 2-, and 3-nonylphenol-ethoxylates) ranged from 180 to 470 microg/l in chlorinated effluent. Results indicate that both ER and VTG can be used as biomarkers for endocrine disruption in larval fish, and that 4-day exposure to sewage effluent is sufficient to elicit significant expression of these markers in sunshine bass larvae. The extremely higher concentrations of NPEOs found in effluent relative to hormones (approximately 40,000-fold) indicates that surfactant metabolites may be contributing significantly to the estrogenic effects observed.  相似文献   
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The abundance and 13C/12C ratios of carbon were analyzed in basaltic glass from twenty locations along the Juan de Fuca Ridge using a 3-step combustion/extraction technique. Carbon released during the first two combustion steps at 400-500 degrees C and 600-650 degrees C is interpreted to be secondary, and only the carbon recovered during a final combustion step at approximately 1200 degrees C is thought to be indigenous to the samples. For carbon released at approximately 1200 degrees C, glasses analyzed as 1-2 mm chips contained 23-146 ppm C with delta 13C values of -4.8 to -9.3%, whereas samples crushed to 38-63 microns or 63-90 microns yielded 56-103 ppm C with delta 13C values of -6.1 to -9.2%. The concentrations and isotopic compositions of the primary carbon dissolved in the glasses and present in the vesicles are similar to those previously reported for other ocean-ridge basalts. The Juan de Fuca basaltic magmas were not in equilibrium with respect to carbon when they erupted and quenched on the sea floor. Evidence of disequilibrium includes (1) a large range of carbon contents among glasses collected at similar depths, (2) a highly variable calculated carbon isotopic fractionation between melt and vapor determined by comparing crushed and uncrushed splits of the same sample, and (3) a lack of correlation between vesicle abundance, carbon concentration, and depth of eruption. Variations in carbon concentration and delta 13C ratios along the ridge do not correlate with major element chemistry. The observed relationship between carbon concentrations and delta 13C values may be explained by late-stage, variable degrees of open-system (Rayleigh-like) degassing.  相似文献   
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The kinetic reactions in N2-xCH4(C2H2) gas discharges with x less than 1% have been studied by emission spectroscopy in the afterglow of D.C. discharges and by mass spectroscopy from radiolysis ionization using alpha particles. The pressure range is from several Torr to 100 Torr. At the end of N2 D.C. discharges at room temperature, for a residence time of about 10(-2) s, the dominant active species are the N atoms with density of 10(14)-10(15) cm-3 for N2 density of about 10(17) cm-3 (3 Torr), the N2(X,V) vibrational molecules with for example [N2(X,V = 10)] approximately 10(14) cm-3 and the electronic metastable molecules N2(A 3 sigma u +) with a density of 10(12) cm-3. In such conditions, the following kinetic reactions have been studied: N2(A) + N2(A) --> N2(C,B,V') + N2(X), N2(A) + N2(X,V>5) --> N2(X) + N2(B,V') in pure N2 post-discharges and N2(A) + CH4 --> products, C + N + M2 --> CN(B,V') + M2, N2(X,V>4) + CN --> N2(X) + CN(B,A,V'), in N2-1% CH4 post-discharges. The clustering reactions of N2-(1-5%)CH4(C2H2) gas mixtures after radiolysis ionization have been studied for the H2CN+ nN2 ions and the equilibrium constants have been determined in the temperature range T = 140-300 K.  相似文献   
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塔里木盆地西部古盐岩同位素地球化学与成钾预测研究   总被引:5,自引:0,他引:5  
我国钾盐资源紧缺,寻找优质大型钾盐矿床一直是国家资源普查的重要目标这一。塔里木盆地在其地史发展过程中,曾与广海相通,多期海水的侵入和间断,以及适宜的构造、古地里环境具备成钾的基本地质条件,因此一直被列为我国寻找古钾矿的重点地区。为了更准备地判断其成盐的海陆相特征,即成盐物质的主要来源,以及岩盐沉积之前的古卤水蒸发浓缩阶段,预测更有前景的成钾远景区,论文选择了蒸发岩沉积序列中的石膏及石盐矿物,分别分析了其硫同位素及氯同位素分布特征。结果表明,非还原环境下沉积的石膏硫同位素可以准确判断盐岩沉积的海相、陆相和海陆交互沉积特征,氯同位素可以判断岩盐的沉积阶段。应用这两个同位素新指标分析,塔里木盆地西部喀什次级构造凹陷晚白垩世盐岩沉积接近海相沉积类型,而且岩盐沉积阶段较晚,是一最有利成钾远景区。  相似文献   
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自1978年3月,在Fresmout谷(F谷)一口井中连续记录到水位资料.其靠近Garlock断裂带(G带)上的数条断层显示出有左旋位移和倾滑位移.水位差表明有断层从观测井和灌溉井间通过.4年间,记录到6次急剧的水位变化(脉冲),这些发生在2—4天以上的水位变化,幅度为15—30厘米,似断层蠕动的结果.在观测井南300米处的G带上可能有两种蠕动:(1)阶梯状的倾滑位移;(2)左旋位移.利用指数函数、反正切函数和斜余弦函数变化的位错模型分析了水位变化、压力分布和断层位移.结果表明,该断层上的单个蠕动事件的位移量在1厘米以内.1978—1982年期间,累计蠕变值为20-50毫米,这取决于使用模型的特殊性.  相似文献   
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