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1.
Surface modification of two algal biomasses, Nizimuddinia zanardini and Stoechospermum marginatum, using 4-phenyl-3-thiosemicarbazide ligand was performed to investigate the consequences on the adsorption of heavy metals from aqueous solution. Stabilization of amino group of 4-phenyl-3-thiosemicarbazide on the surface of biomasses was confirmed using Fourier transform infrared spectroscopy. Chemical modification was found to exert significant positive effects on biosorption. Adsorption capacities for Pb(II), Cd(II) and Cr(VI) using modified N. zanardini were observed to be 19.3, 16.75 and 15.75 mg/g, respectively, compared to 17.48, 14.18 and 11.85 mg/g for raw N. zanardini biomass. Also, adsorption of Pb(II), Cd(II) and Cr(VI) by the modified S. Marginatum was found to be 17.54, 15.62 and 14.77 mg/g, respectively, in comparison with that of the raw biomass which were 16.86, 12.9 and 11.2 mg/g. The obtained results of the equilibrium adsorption were studied through different isotherm models of Langmuir, Freundlich and Temkin, where the Langmuir model was observed to agree well with the results. Prevalent kinetic models including pseudo-second order and intra-particle diffusion were applied, and the pseudo-second order was found to describe the adsorption kinetics data adequately. Intra-particle model was also utilized in order to show penetration of metal ions, where it was realized that the biosorption took place in two or three steps including film diffusion, molecular diffusion and chemical reaction.  相似文献   
2.
Using methods to estimate the value of environmental goods seems to be essential for economic planning and moving toward development. In this paper, using methods of discrete payment vehicle (dichotomous choice), i.e., single-bounded and Double-Bounded Dichotomous Choice, the value of air pollution in Tehran and households’ willingness to pay to improve air quality, in four selected regions (Shahr-e-Ray, Shoosh, Haft-e-Tir and Tajrish) is estimated and the corresponding results of these two techniques were compared. The results showed that the total value of air quality improvement, calculated through two techniques of Double-Bounded and Single-Bounded Dichotomous Choice were, respectively, 2,398,657,500 and 1,492,566,000 thousands Rials (1USD = 35,000R) in a year and weighted mean of each citizen’s willingness to pay to improve air quality, calculated through these two methods was estimated to be 282,192 and 175,596 Rials in a year, respectively. Considering the annual damage to health, for any 1% increase in pollutants and yearly cost of pollution reduction which are, respectively, 1,199,000,000 and 7,336,000,000 thousands Rials, it was determined that citizens’ willingness to pay through two methods includes 20 and 30% of the cost of pollution control, respectively, while 70% of pollution is due to mobile sources. However, citizens’ low willingness to pay is attributed to citizens’ distrust of government policies as well as their ignorance of the harmful effects of air pollution. In general, the results of this study, with regard to the cost of pollution from Single-Bounded Dichotomous Choice are closer to actual market conditions.  相似文献   
3.
New empirical models were developed to predict the soil deformation moduli using gene expression programming (GEP). The principal soil deformation parameters formulated were secant (Es) and reloading (Er) moduli. The proposed models relate Es and Er obtained from plate load-settlement curves to the basic soil physical properties. The best GEP models were selected after developing and controlling several models with different combinations of the influencing parameters. The experimental database used for developing the models was established upon a series of plate load tests conducted on different soil types at depths of 1–24 m. To verify the applicability of the derived models, they were employed to estimate the soil moduli of a part of test results that were not included in the analysis. The external validation of the models was further verified using several statistical criteria recommended by researchers. A sensitivity analysis was carried out to determine the contributions of the parameters affecting Es and Er. The proposed models give precise estimates of the soil deformation moduli. The Es prediction model provides considerably better results in comparison with the model developed for Er. The simplified formulation for Es significantly outperforms the empirical equations found in the literature. The derived models can reliably be employed for pre-design purposes.  相似文献   
4.
In this study, new empirical equations were developed to predict the soil deformation moduli utilizing a hybrid method coupling genetic programming and simulated annealing, called GP/SA. The proposed models relate secant (Es), unloading (Eu) and reloading (Er) moduli obtained from plate load–settlement curves to the basic soil physical properties. Several models with different combinations of the influencing parameters were developed and checked to select the best GP/SA models. The database used for developing the models was established upon a series of plate load tests (PLT) conducted on different soil types at various depths. The validity of the models was tested using parts of the test results that were not included in the analysis. The validation of the models was further verified using several statistical criteria. A traditional GP analysis was performed to benchmark the GP/SA models. The contributions of the parameters affecting Es, Eu and Er were analyzed through a sensitivity analysis. The proposed models are able to estimate the soil deformation moduli with an acceptable degree of accuracy. The Es prediction model has a remarkably better performance than the models developed for predicting Eu and Er. The simplified formulations for Es, Eu and Er provide significantly better results than the GP-based models and empirical models found in the literature.  相似文献   
5.
Superficial sediments (top Im) of the Eastern Mediterranean Basin, Sea of Marmara, Turkey accumulated rapidly (0.087 ± 0.012 g/cm2 · y) by hemipelagic sedimentation with only limited amounts of gravity flow or bottom current action under low oxygenated but not anoxic conditions. They have restricted faunas, relatively higher organic carbon (1–1.8%) and lower calcium carbonate (14–20%) contents than other Eastern Mediterranean Basin sediments. Sedimentation shows little change over the last millenium except for an increase in Cu, Zn, Pb, Cr, and P over the last few centuries. The increase was most likely caused by increased metallurgical activities since the eighteenth century but are not at sufficient levels for the area to be regarded as polluted.  相似文献   
6.
Near‐fault ground motions with forward directivity are characterized by a large pulse. This pulse‐like motion may cause a highly non‐uniform distribution of story ductility demands for code‐compliant frame structures, with maximum demands that may considerably exceed the level of code expectations. Strengthening techniques for multi‐story frame structures are explored with the objective of reducing maximum drift demands. One option is to modify the code‐based SRSS distribution of story shear strength over the height by strengthening of the lower stories of the frame. The modified distribution reduces the maximum story ductility demand, particularly for weak and flexible structures. However, this strengthening technique is less effective for stiff structures, and is almost ineffective in cases in which the maximum demand occurs in the upper stories, i.e. strong and flexible structures. As an alternative, the benefits of strengthening frames with elastic and inelastic walls are evaluated. The effects of adding walls that are either fixed or hinged at the base are investigated. It is demonstrated that strengthening with hinged walls is very effective in reducing drift demands for structures with a wide range of periods and at various performance levels. Wall inelastic behavior only slightly reduces the benefits of strengthening with hinged walls.Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
7.
Study of Dominant Factors Affecting Cerchar Abrasivity Index   总被引:2,自引:1,他引:1  
The Cerchar abrasion index is commonly used to represent rock abrasion for estimation of bit life and wear in various mining and tunneling applications. Although the test is simple and fast, there are some discrepancies in the test results related to the equipment used, condition of the rock surface, operator skills, and procedures used in conducting and measuring the wear surface. This paper focuses on the background of the test and examines the influence of various parameters on Cerchar testing including pin hardness, surface condition of specimens, petrographical and geomechanical properties, test speed, applied load, and method of measuring wear surface. Results of Cerchar tests on a set of rock specimens performed at different laboratories are presented to examine repeatability of the tests. In addition, the preliminary results of testing with a new device as a potential alternative testing system for rock abrasivity measurement are discussed.  相似文献   
8.
This study presents new attenuation models for the estimation of peak ground acceleration (PGA), peak ground velocity (PGV), and peak ground displacement (PGD) using a hybrid method coupling genetic programming and simulated annealing, called GP/SA. The PGA, PGV, and PGD were formulated in terms of earthquake magnitude, earthquake source to site distance, average shear-wave velocity, and faulting mechanisms. A worldwide database of strong ground motions released by Pacific Earthquake Engineering Research Center (PEER) was employed to establish the models. A traditional genetic programming analysis was performed to benchmark the proposed models. For more validity verification, the GP/SA models were employed to predict the ground-motion parameters of the Iranian plateau earthquakes. Sensitivity and parametric analyses were carried out and discussed. The results show that the GP/SA attenuation models can offer precise and efficient solutions for the prediction of estimates of the peak time-domain characteristics of strong ground motions. The performance of the proposed models is better than or comparable with the attenuation relationships found in the literature.  相似文献   
9.
The paper studied by Daga and Deo (2008) considers the feasibility of using genetic programming (GP) for estimating wind from waves by inverse modeling. The paper includes some problems about the fundamental aspects and use of the proposed GP approach for the aim of their study. In this discussion, some controversial points of the paper are given.  相似文献   
10.
Soil salinity is a major environmental hazard. The global extent of primary and secondary salt affected soils is about 955 and 77 M?ha, respectively. Soil salinity tends to increase in spite of considerable effort dedicated to land reclamation. This requires careful monitoring of the soil salinity status. The objectives of this study were: (a) to evaluate the capability of thematic mapper (TM) and multispectral scanner (MSS) imagery for mapping land cover types, (b) to analyse the spectral features of sail crusts relative to bare soil and gravely soil surface conditions, and (c) to detect the soil salinity changes during the period 1975–2004 in the Ardakan area located in the central Iranian Deserts. The Landsat MSS and TM on two different dates of September 14, 1975 and September 11, 2004, respectively, were used. Due to great confusion between some classes, the TM 6 was included in the band combination. The result of the image classification based on the combination of TM bands 3, 4, 5, and 6 showed of the classification results. For multi-temporal analysis, both TM and MSS images were classified with the same method but with a different number of training classes. The TM-classified image was regrouped to make it comparable with MSS regrouped classified image. The comparison between the classified images showed about 39% of the total area had changed in 29 years. The result of this study revealed the possibility of detecting important soil salinity changes by using Landsat satellite data  相似文献   
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