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1.
Estimation of the degree of local seismic wave amplification (site effects) requires precise information about the local site conditions. In many regions of the world, local geologic information is either sparse or is not readily available. Because of this, seismic hazard maps for countries such as Mozambique, Pakistan and Turkey are developed without consideration of site factors and, therefore, do not provide a complete assessment of future hazards. Where local geologic information is available, details on the traditional maps often lack the precision (better than 1:10,000 scale) or the level of information required for modern seismic microzonation requirements. We use high-resolution (1:50,000) satellite imagery and newly developed image analysis methods to begin addressing this problem. Our imagery, consisting of optical data and digital elevation models (DEMs), is recorded from the ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer) sensor system. We apply a semi-automated, object-oriented, multi-resolution feature segmentation method to identify and extract local terrain features. Then we classify the terrain types into mountain, piedmont and basin units using geomorphometry (topographic slope) as our parameter. Next, on the basis of the site classification schemes from the Wills and Silva (1998) study and the Wills et al (2000) and Wills and Clahan (2006) maps of California, we assign the local terrain units with V s 30 (the average seismic shear-wave velocity through the upper 30m of the subsurface) ranges for selected regions in Mozambique, Pakistan and Turkey. We find that the applicability of our site class assignments in each region is a good first-approximation for quantifying local site conditions and that additional work, such as the verification of the terrain’s compositional rigidity, is needed.  相似文献   
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Unlike the majority of the water in the flooded mine complex of Butte Montana, which includes the highly acidic Berkeley pit lake, groundwater in the flooded West Camp underground mine workings has a circum-neutral pH and contains at least 8 μM aqueous sulfide. This article examines the geochemistry and stable isotope composition of this unusual H2S-rich mine water, and also discusses problems related to the colorimetric analysis of sulfide in waters that contain FeS(aq) cluster compounds. The West Camp mine pool is maintained at a constant elevation by continuous pumping, with discharge water that contains elevated Mn (90 μM), Fe (16 μM), and As (1.3 μM) but otherwise low metal concentrations. Dissolved inorganic carbon in the mine water is in chemical and isotopic equilibrium with rhodochrosite in the mineralized veins. The mine water is under-saturated with mackinawite and amorphous FeS, but is supersaturated with Cu- and Zn-sulfides. However, voltammetry studies show that much of the dissolved sulfide and ferrous iron are present as FeS(aq) cluster molecules: as a result, the free concentration of the West Camp water is poorly constrained. Concentrations of dissolved sulfide determined by colorimetry were lower than gravimetric assays obtained by AgNO3 addition, implying that the FeS(aq) clusters are not completely extracted by the Methylene Blue reagent. In contrast, the clusters are quantitatively extracted as Ag2S after addition of AgNO3. Isotopic analysis of co-existing aqueous sulfide and sulfate confirms that the sulfide was produced by sulfate-reducing bacteria (SRB). The H2S-rich mine water is not confined to the immediate vicinity of the extraction well, but is also present in flooded mine shafts up to 3 km away, and in samples bailed from mine shafts at depths up to 300 m below static water level. This illustrates that SRB are well established throughout the southwestern portion of the extensive (>15 km3) Butte flooded mine complex.  相似文献   
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The objective of in situ thermal treatment is typically to reduce the contaminant mass or average soil concentration below a specified value. Evaluation of whether the objective has been met is usually made by averaging soil concentrations from a limited number of soil samples. Results from several field sites indicate large performance uncertainty using this approach, even when the number of samples is large. We propose a method to estimate average soil concentration by fitting a log normal probability model to thermal mass recovery data. A statistical approach is presented for making termination decisions from mass recovery data, soil sample data, or both for an entire treatment volume or for subregions that explicitly considers estimation uncertainty which is coupled to a stochastic optimization algorithm to identify monitoring strategies to meet objectives with minimum expected cost. Early termination of heating in regions that reach cleanup targets sooner enables operating costs to be reduced while ensuring a high likelihood of meeting remediation objectives. Results for an example problem demonstrate that significant performance improvement and cost reductions can be achieved using this approach.  相似文献   
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This work is the sixth in a series of papers on the thermodynamically constrained averaging theory (TCAT) approach for modeling flow and transport phenomena in multiscale porous medium systems. Building upon the general TCAT framework and the mathematical foundation presented in previous works, the limiting case of connected two-fluid-phase flow is considered. A constrained entropy inequality is developed based upon a set of primary restrictions. Formal approximations are introduced to deduce a general simplified entropy inequality (SEI). The SEI is used along with secondary restrictions and closure approximations consistent with the SEI to produce a general functional form of a two-phase-flow model. The general model is in turn simplified to yield a hierarchy of models by neglecting common curves and by neglecting both common curves and interfaces. The simplest case considered corresponds to a traditional two-phase-flow model. The more sophisticated models including interfaces and common curves are more physically realistic than traditional models. All models in the hierarchy are posed in terms of precisely defined variables that allow for a rigorous connection with the microscale. The explicit nature of the restrictions and approximations used in developing this hierarchy of models provides a clear means to both understand the limitations of traditional models and to build upon this work to produce more realistic models.  相似文献   
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Groundwater contamination due to accidental releases of mono- and polycyclic aromatic compounds (MAHs and PAHs) from decommissioned manufactured-gas plants is an ongoing and litigious problem. The MAHs and PAHs are derived from coal tar, which was a by-product of the gas-manufacturing process. While originally designed to contain coal tar, the manufactured-gas plant structures that remain today have often degraded over time and are not completely leak-proof. Over a period of many years, subsurface water has seeped into and out of the structures, resulting in groundwater contamination. This was particularly true once the tops of the structures were removed. In this study, process-based simulations were conducted to estimate the groundwater-quality impacts of accidental releases of dissolved naphthalene (C10H8) from the sites of three former manufactured-gas plants. The results from one-dimensional, transient, unsaturated, near-surface fluid-flow and solute-transport simulations served as input to three-dimensional saturated subsurface fluid-flow and solute-transport simulations. The simulation results and sensitivity analysis reported here indicate that accidental releases of naphthalene had significant, negative impacts on groundwater quality at each of the three sites. Electronic Publication  相似文献   
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The Beetaloo Sub-basin, northern Australia, is considered the main depocentre of the 1,000-km scale Mesoproterozoic Wilton package of the greater McArthur Basin – the host to one of the oldest hydrocarbon global resources. The ca. 1.40–1.31 Ga upper Roper Group and the latest Mesoproterozoic to early Neoproterozoic unnamed group of the Beetaloo Sub-basin, together, record ca. 500 million years of depositional history within the North Australia Craton. Whole-rock shale Sm–Nd and Pb isotope data from these sediments reveal sedimentary provenance and their evolution from ca. 1.35 to 0.85 Ga. Furthermore, these data, together with shale major/trace elements data from this study and pyrolysis data from previous publications, are used to develop a dynamic tectonic geography model that links the organic carbon production and burial to an enhanced weathering of nutrients from a large igneous province. The ca. 1.35–1.31 Ga Kyalla Formation of the upper Roper Group is composed of isotopically evolved sedimentary detritus that passes up, into more isotopically juvenile Pb values towards the top of the formation. The increase in juvenile compositions coincides with elevated total organic carbon (TOC) contents of these sediments. The coherently enriched juvenile compositions and TOC the upper portions of the Kyalla Formation are interpreted to reflect an increase in nutrient supply associated with the weathering of basaltic sources (e.g. phosphorous). Possible, relatively juvenile, basaltic sources include the Wankanki Supersuite in the western Musgraves and the Derim Derim–Galiwinku large igneous province (LIP). The transition into juvenile, basaltic sources directly before a supersequence-bounding unconformity is here interpreted to reflect uplift and erosion of the Derim Derim–Galiwinku LIP, rather than an influx of southern Musgrave sources. A new baddeleyite crystallisation age of 1,312.9 ± 0.7 Ma provides both a tight constraint on the age of this LIP, along with its associated magmatic uplift, as well as providing a minimum age constraint for Roper Group deposition. The unconformably overlying lower and upper Jamison sandstones are at least 300 million years younger than the Kyalla Formation and were sourced from the Musgrave Province. An up-section increase in isotopically juvenile compositions seen in these rocks is interpreted to document the progressive exhumation of the western Musgrave Province. The overlying Hayfield mudstone received detritus from both the Musgrave and Arunta regions, and its isotopic geochemistry reveals affinities with other early Neoproterozoic basins (e.g. Amadeus, Victoria and Officer basins), indicating the potential for inter-basin correlations.  相似文献   
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Deep basin aquifers are increasingly used in water‐stressed areas, though their potential for sustainable development is inhibited by overlying aquitards and limited recharge rates. Long open interval wells (LOIWs)—wells uncased through multiple hydrostratigraphic units—are present in many confined aquifer systems and can be an important mechanism for deep basin aquifers to receive flow across aquitards. LOIWs are a major control on flow in the deep Cambrian–Ordovician sandstone aquifers of the upper Midwest, USA, providing a source of artificial leakage from shallow bedrock aquifers and equilibrating head within the sandstone aquifers despite differential pumpage. Conceptualizing and quantifying this anthropogenic flow has long been a challenge for groundwater flow modellers, particularly on a regional scale. Synoptic measurements of active production wells and well completion data for northeast Illinois form the basis for a transient, head‐specified MODFLOW model that determines mass balance contributions to the region and estimates LOIW leakage to the aquifers. Using this insight, transient LOIW leakage was simulated using transiently changing KV zones in a traditional, Q‐specified MODFLOW‐USG model, a novel approach that allows the KV in a cell containing a LOIW to change transiently by use of the time‐variant materials (TVM) package. With this modification, we achieved a consistent calibration through time, averaging 19.9 m root mean squared error. This model indicates that artificial leakage via LOIWs contributed a minimum of 10–13% of total flow to the sandstone aquifers through the entire history of pumping, up to 50% of flow around 1930. Removal from storage exceeds 40% of flow during peak withdrawals, much of this flow sourced from units other than the primary sandstone aquifers via LOIWs. As such, understanding the timing and magnitude of LOIW leakage is essential for predicting future water availability in deep basin aquifers.  相似文献   
10.
For about three decades, there have been many predictions of the potential ecological response in boreal regions to the currently warmer conditions. In essence, a widespread, naturally occurring experiment has been conducted over time. In this paper, we describe previously modeled predictions of ecological change in boreal Alaska, Canada and Russia, and then we investigate potential evidence of current climate-induced change. For instance, ecological models have suggested that warming will induce the northern and upslope migration of the treeline and an alteration in the current mosaic structure of boreal forests. We present evidence of the migration of keystone ecosystems in the upland and lowland treeline of mountainous regions across southern Siberia. Ecological models have also predicted a moisture-stress-related dieback in white spruce trees in Alaska, and current investigations show that as temperatures increase, white spruce tree growth is declining. Additionally, it was suggested that increases in infestation and wildfire disturbance would be catalysts that precipitate the alteration of the current mosaic forest composition. In Siberia, 7 of the last 9 yr have resulted in extreme fire seasons, and extreme fire years have also been more frequent in both Alaska and Canada. In addition, Alaska has experienced extreme and geographically expansive multi-year outbreaks of the spruce beetle, which had been previously limited by the cold, moist environment. We suggest that there is substantial evidence throughout the circumboreal region to conclude that the biosphere within the boreal terrestrial environment has already responded to the transient effects of climate change. Additionally, temperature increases and warming-induced change are progressing faster than had been predicted in some regions, suggesting a potential non-linear rapid response to changes in climate, as opposed to the predicted slow linear response to climate change.  相似文献   
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