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The speciation of Nd(III), Sm(III), and Er(III) in sulfate-bearing solutions has been determined spectrophotometrically at temperatures from 25 to 250 °C and a pressure of 100 bars. The data obtained earlier on the speciation of Nd in sulfate-bearing solutions (Migdisov et al., 2006) have been re-evaluated and corrected using a more appropriate activity model and are compared with the corresponding data for Sm(III) and Er(III) and new data for Nd(III). Based on this comparison, the dominant species in the solution are interpreted to be and , with the latter complex increasing in importance at higher temperature. Equilibrium constants were calculated for the following reactions:
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Recent drilling and sampling of hydrothermal fluids from Long Valley permit an accurate characterization of chemical concentrations and equilibrium conditions in the hydrothermal reservoir. Hydrothermal fluids are thermodynamically saturated with secondary quartz, calcite, and pyrite but are in disequilibrium with respect to aqueous sulfide-sulfate speciation. Hydrothermal fluids are enriched in 18O by approximately 1‰ relative to recharge waters. 18O and Cl concentrations in well cuttings and core from high-temperature zones of the reservoir are extensively depleted relative to fresh rhyolitic tuff compositions. Approximately 80% of the Li and 50% of the B are retained in the altered reservoir rock. Cl mass balance and open-system 18O fractionation models produce similar water-rock ratios of between 1.0 and 2.5 kg kg−1. These water-rock ratios coupled with estimates of reservoir porosity and density produce a minimum fluid residence time of 1.3 ka. The low fluid Cl concentrations in Long Valley correlate with corresponding low rock concentrations. Mass balance calculations indicate that leaching of these reservoir rocks accounts for Cl losses during hydrothermal activity over the last 40 ka. 相似文献
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Art R. T. Jonkers 《Geophysical Journal International》2007,169(2):646-658
The technique of bootstrapped discrete scale invariance allows multiple time-series of different observables to be normalized in terms of observed and predicted characteristic timescales. A case study is presented using the SINT2000 time-series of virtual axial dipole moment, which spans the past 2 Myr. It is shown that this sequence not only bears a clear signature of a preferred timescale of about 55.6 Ka, but additionally predicts similar features (of shorter and longer duration) that are actually observed on the timescales of historical secular variation and dipole reversals, respectively. In turn, the latter two empirical sources both predict the characteristic timescale found in the dipole intensity sequence. These communal scaling characteristics suggest that a single underlying process could be driving dynamo fluctuations across all three observed timescales, from years to millions of years. 相似文献
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Art F White 《Geochimica et cosmochimica acta》1977,41(5):613-625
The coprecipitation of Na and K was experimentally investigated in aragonite. The distribution functions were determined at pH 6.8 and 8.8 over aqueous Na and K concentrations of between 5 × 10?4and 2.0 M and temperatures of between 25 and 75°C.The mole fractions of Na and K in aragonite are related to the aqueous ratios of Na and Ca by a function of the form where C0 and C1 are constants at a given temperature. This equation was derived by a statistical model assuming a heterogeneous energy distribution for the sites of incorporation. The independence of the coprecipitation process from aqueous anion activities suggests that carbonate is the only anionic species in the solid solution. 相似文献
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Art. A. Migdisov A.E. Williams-Jones T. Wagner 《Geochimica et cosmochimica acta》2009,73(23):7087-7109
The solubility of REE(III) fluoride solids was determined in fluoride- and chloride-bearing solutions at 150, 200 and 250 °C and saturated water vapor pressure. These experimental data, together with experimental data from previously published studies, were used to evaluate formation constants for chloride- and fluoride-bearing aqueous species of the entire REE(III) group at temperatures up to 300 °C. The data show that the stability of these species differs significantly from that predicted theoretically. For example, contrary to the theoretical predictions, LREEF2+ species are more stable than HREEF2+ species at elevated temperature. The behavior of the chloride-bearing species is similar. Parameters for the Helgeson–Kirkham–Flowers (HKF) equation of state were determined for REEF2+, REECl2+ and REECl2+ complexes using these experimental data and permit calculation of formation constants of these species at conditions not investigated experimentally. These data now permit the mobility of all REE in fluoride- and chloride-bearing hydrothermal systems to be reliably evaluated at intermediate temperatures and pressures. 相似文献
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A. Goineau C. Fontanier F.J. Jorissen B. Lansard R. Buscail A. Mouret P. Kerhervé S. Zaragosi E. Ernoult C. Artéro P. Anschutz E. Metzger C. Rabouille 《Journal of Sea Research》2011,65(1):58-75
In this paper, we investigate the ecology of live (rose Bengal stained) benthic foraminifera collected at 20 stations ranging from 15 to 100 m depth in the Rhône prodelta (Gulf of Lions, NW Mediterranean). These sites were sampled in September 2006, five months after the Rhône River annual flood. Statistical analyses based on foraminiferal communities (> 150 μm) divide our study area into six main biofacies directly related to environmental conditions. Miliolid species are abundant in the relict prodeltaic lobe which is characterised by sand with low organic matter content. Close to the river mouth, the limited oxygen penetration in the sediment combined with important hydro-sedimentary processes constitute stressful conditions for foraminiferal faunas dominated by opportunistic species (e.g. Leptohalysis scottii). With increasing distance from the river mouth, foraminiferal faunas (e.g. Nonionella turgida, Eggerella scabra) adapted to thrive in sediments enriched in Rhône-derived organic matter under more stable hydro-sedimentary conditions appear. In the distal part of the Rhône River influence, benthic species (e.g. Valvulineria bradyana, Textularia agglutinans) living in fine sediment enriched in both continental and marine organic compounds emerge. At the deepest stations located in the south-eastern part of our study area, benthic foraminiferal faunas (e.g. Bulimina aculeata, Melonis barleeanus, Bigenerina nodosaria) are highly diverse, underlining stable environmental conditions characterised by marine-derived organic matter supplies and relatively deep oxygen penetration depth in the sediment. We also compare foraminiferal faunas sampled in September 2006 with communities sampled in June 2005, one month after the Rhône River annual flood (Mojtahid et al., 2009). This comparison suggests that opportunistic species (e.g. B. aculeata, Cassidulina carinata, V. bradyana) have responded to organic matter inputs related to marine primary production in June 2005. 相似文献
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Tomàs Artés Andrés Cencerrado Ana Cortés Tomàs Margalef 《International journal of geographical information science》2016,30(3):594-611
AbstractForest fires are a kind of natural hazard with a high number of occurrences in southern European countries. To avoid major damages and to improve forest fire management, one can use forest fire spread simulators to predict fire behavior. When providing forest fire predictions, there are two main considerations: accuracy and computation time. In the context of natural hazards simulation, it is well known that part of the final forecast error comes from uncertainty in the input data. These data typically consist of a set of GIS files, which should be appropriately conflated. For this reason, several input data calibration methods have been developed by the scientific community. In this work, the Two-Stage calibration methodology, which has been shown to provide good results, is used. This calibration strategy is computationally intensive and time-consuming because it uses a Genetic Algorithm as a solution. Taking into account the aspect of urgency in forest fire spread prediction, it is necessary to maintain a balance between accuracy and the time needed to calibrate the input parameters. In order to take advantage of this technique, one must deal with the problem that some of the obtained solutions are impractical, since they involve simulation times that are too long, preventing the prediction system from being deployed at an operational level. A new method which finds the minimum resolution reduction for such long simulations, keeping accuracy loss to a known interval, is proposed. The proposed improvement is based on a time-aware core allocation policy that enables real-time forest fire spread forecasting. The final prediction system is a cyberinfrastructure, which enables forest fire spread prediction at real time. 相似文献
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Art F. White Marjorie S. Schulz Davison V. Vivit Alex E. Blum David A. Stonestrom 《Journal of Geochemical Exploration》2006,88(1-3):363
Spatial and temporal variations in pore water compositions are characterized for a deep regolith profile developed on a marine terrace chronosequence near Santa Cruz California. Variations are resolved in terms of the dominance of either a lithogenic process, i.e. chemical weathering, or a biogenic process, i.e. plant nutrient cycling. The concept of elemental fractionation is introduced describing the extent that specific elements are mobilized and cycled as a result of these processes. 相似文献
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An Integral Equation Approach to Three-Dimensional Modelling 总被引：2，自引：0，他引：2
A. P. Raiche 《Geophysical Journal International》1974,36(2):363-376