Laboratory measurement of the OI1173989 Å branching ratio     

M.D. Morrison 《Planetary and Space Science》1985,33(1):135-139

Laboratory measurements of the $\text{OI}\text{1173}\text{989}$ Å (3s' ³D° → 2p⁴¹D, 3s' ³D° → 2p⁴³P) branching ratio have been made with a value of 1.5 × 10^t-4 indicated. This value makes the branching transition at 1173 Å an order of magnitude stronger than the branch at 7990 Å (3s' 3D° → 3p ³P). The 1173 Å branching loss is still too weak a loss process for multiply scattered 989 Å photons to resolve the 989 Å intensity problem in the dayglow.  相似文献   

Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques     

Alan M Bond  Julie R Bradbury  Henry A Hudson  John S Garnham  Peter J Hanna  Stanley Strother 《Marine Chemistry》1985,16(1):1-9

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.  相似文献   

Loss of water from Mars:: Implications for the oxidation of the soil     

H. Lammer  H.I.M. Lichtenegger  I. Ribas  E.F. Guinan  S.J. Bauer 《Icarus》2003,165(1):9-25

The evolution of the martian atmosphere with regard to its H₂O inventory is influenced by thermal loss processes of H, H₂, nonthermal atmospheric loss processes of H⁺, H₂⁺, O, O⁺, CO₂, and O₂⁺ into space, as well as by chemical weathering of the surface soil. The evolution of thermal and nonthermal escape processes depend on the history of the intensity of the solar XUV radiation and the solar wind density. Thus, we use actual data from the observation of solar proxies with different ages from the Sun in Time program for reconstructing the Sun's radiation and particle environment from the present to 3.5 Gyr ago. The correlation between mass loss and X-ray surface flux of solar proxies follows a power law relationship, which indicates a solar wind density up to 1000 times higher at the beginning of the Sun's main sequence lifetime. For the study of various atmospheric escape processes we used a gas dynamic test particle model for the estimation of the pick up ion loss rates and considered pick up ion sputtering, as well as dissociative recombination. The loss of H₂O from Mars over the last 3.5 Gyr was estimated to be equivalent to a global martian H₂O ocean with a depth of about 12 m, which is smaller than the values reported by previous studies. If ion momentum transport, a process studied in detail by Mars Express is significant on Mars, the water loss may be enhanced by a factor of about 2. In our investigation we found that the sum of thermal and nonthermal atmospheric loss rates of H and all nonthermal escape processes of O to space are not compatible with a ratio of 2:1, and is currently close to about 20:1. Escape to space cannot therefore be the only sink for oxygen on Mars. Our results suggest that the missing oxygen (needed for the validation of the 2:1 ratio between H and O) can be explained by the incorporation into the martian surface by chemical weathering processes since the onset of intense oxidation about 2 Gyr ago. Based on the evolution of the atmosphere-surface-interaction on Mars, an overall global surface sink of about 2×10⁴² oxygen particles in the regolith can be expected. Because of the intense oxidation of inorganic matter, this process may have led to the formation of considerable amounts of sulfates and ferric oxides on Mars. To model this effect we consider several factors: (1) the amount of incorporated oxygen, (2) the inorganic composition of the martian soil and (3) meteoritic gardening. We show that the oxygen incorporation has also implications for the oxidant extinction depth, which is an important parameter to determine required sampling depths on Mars aimed at finding putative organic material. We found that the oxidant extinction depth is expected to lie in a range between 2 and 5 m for global mean values.  相似文献   

The unresolved hard X-ray background: the missing source population implied by the Chandra and XMM–Newton deep fields     

M. A. Worsley  A. C. Fabian  F. E. Bauer  D. M. Alexander  G. Hasinger  S. Mateos  H. Brunner  W. N. Brandt  D. P. Schneider 《Monthly notices of the Royal Astronomical Society》2005,357(4):1281-1287

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Fluid entrapment and reequilibration during subduction and exhumation: A case study from the high-grade Nestos shear zone, Central Rhodope, Greece     

Kurt Krenn  Christoph Bauer  Alexander Proyer  Evripidis Mposkos  Georg Hoinkes 《Lithos》2008,104(1-4):33-53

A fluid inclusion study on metamorphic minerals of successive growth stages was performed on highly deformed paragneisses from the Nestos Shear Zone at Xanthi (Central Rhodope), in which microdiamonds provide unequivocal evidence for ultrahigh-pressure (UHP) metamorphism. The correlation of fluid inclusion density isochores and fluid inclusion reequilibration textures with geothermobarometric data and the relative chronology of micro- and macro-scale deformation stages allow a better understanding of both the fluid and metamorphic evolution along the P–T–d path. Textural evidence for subduction towards the NE is recorded by the orientation of intragranular NE-oriented fluid inclusion planes and the presence of single, annular fluid inclusion decrepitation textures. These textures occur within quartz “foam” structures enclosed in an earlier generation of garnets with prolate geometries and rarely within recrystallized matrix quartz, and reequilibrated both in composition and density during later stages of exhumation. No fluid inclusions pertaining to the postulated ultrahigh-pressure stage for microdiamond-bearing garnet–kyanite–gneisses have yet been found. The prolate shape of garnets developed during the earliest stages of exhumation that is recorded structurally by (L  S) tectonites, which subsequently accommodated progressive ductile SW shearing and folding up to shallow crustal levels. The majority of matrix kyanite and a later generation of garnet were formed during SW-directed shear under plane-strain conditions. Fluid inclusions entrapped in quartz during this stage of deformation underwent density loss and transformed to almost pure CO₂ inclusions by preferential loss of H₂O. Those inclusions armoured within garnet retained their primary 3-phase H₂O–CO₂ compositions. Reequilibration of fluid inclusions in quartz aggregates is most likely the result of recrystallization along with stress-induced, preferential H₂O leakage along dislocations and planar lattice defects which results in the predominance of CO₂ inclusions with supercritical densities. Carbonic fluid inclusions from adjacent kyanite–corundum-bearing pegmatoids and, the presence of shear-plane-parallel fluid inclusion planes within late quartz boudin structures consisting of pure CO₂-fluid inclusions with negative crystal shapes, bear witness of the latest stage of deformation by NE-directed extensional shear.This study shows that the textures of early fluid inclusions that formed already during the prograde metamorphic path can be preserved and used to derive information about the kinematics of subduction that is difficult to obtain from other sources. The textures of early inclusions, together with later generations of unaltered primary and secondary inclusions in metamorphic index minerals that can be linked to specific deformation stages and even P–T conditions, are a welcome supplement for the reconstruction of a rather detailed P–T–d path.  相似文献   

Relationship between footwall composition,crustal contamination,and fluid–rock interaction in the Platreef,Bushveld Complex,South Africa     

Julie Pronost  Chris Harris  Christian Pin 《Mineralium Deposita》2008,43(8):825-848

In the northern limb of the 2.06-Ga Bushveld Complex, the Platreef is a platinum group elements (PGE)-, Cu-, and Ni-mineralized zone of pyroxenite that developed at the intrusion margin. From north to south, the footwall rocks of the Platreef change from Archaean granite to dolomite, hornfels, and quartzite. Where the footwall is granite, the Sr-isotope system is more strongly perturbed than where the footwall is Sr-poor dolomite, in which samples show an approximate isochron relationship. The Nd-isotope system for samples of pyroxenite and hanging wall norite shows an approximate isochron relationship with an implied age of 2.17 ± 0.2 Ga and initial Nd-isotope ratio of 0.5095. Assuming an age of 2.06 Ga, the ɛNd values range from −6.2 to −9.6 (ave. −7.8, n = 17) and on average are slightly more negative than the Main Zone of the Bushveld. These data are consistent with local contamination of an already contaminated magma of Main Zone composition. The similarity in isotope composition between the Platreef pyroxenites and the hanging wall norites suggests a common origin. Where the country rock is dolomite, the Platreef has generally higher plagioclase and pyroxene δ ¹⁸O values, and this indicates assimilation of the immediate footwall. Throughout the Platreef, there is considerable petrographic evidence for sub-solidus interaction with fluids, and the Δ _{plagioclase–pyroxene} values range from −2 to +6, which indicates interaction at both high and low temperatures. Whole-rock and mineral δD values suggest that the Platreef interacted with both magmatic and meteoric water, and the lack of disturbance to the Sr-isotope system suggests that fluid–rock interaction took place soon after emplacement. Where the footwall is granite, less negative δD values suggest a greater involvement of meteoric water. Consistently higher values of Δ _{plagioclase–pyroxene} in the Platreef pyroxenites and hanging wall norites in contact with dolomite suggest prolonged interaction with CO₂-rich fluid derived from decarbonation of the footwall rocks. The overprint of post crystallization fluid–rock interaction is the probable cause of the previously documented lack of correlation between PGE and sulfide content on the small scale. The Platreef in contact with dolomite is the focus of the highest PGE grades, and this suggests that dolomite contamination played a role in PGE concentration and deposition, but the exact link remains obscure. It is a possibility that the CO₂ produced by decarbonation of assimilated dolomite enhanced the process of PGE scavenging by sulfide precipitation.  相似文献   

Controlling geological and hydrogeological processes in an arsenic contaminated aquifer on the Red River flood plain,Vietnam   总被引：1，自引：0，他引：1  

Flemming Larsen  Nhan Quy Pham  Nhan Duc Dang  Dieke Postma  Søren Jessen  Viet Hung Pham  Thao Bach Nguyen  Huy Duc Trieu  Luu Thi Tran  Hoan Nguyen  Julie Chambon  Hoan Van Nguyen  Dang Hoang Ha  Nguyen Thi Hue  Mai Thanh Duc  Jens Christian Refsgaard 《Applied Geochemistry》2008

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Effects of cadmium on the induction and activities of enzymes of xenobiotic metabolism in plaice     

Stephen C. George  Peter Young  Helen Morrison 《Marine environmental research》1985,17(2-4)

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A new titanium-bearing calcium aluminosilicate phase: II. Crystallography and crystal chemistry of grains formed in slowly cooled melts with bulk compositions of calcium- aluminum-rich inclusions     

David J. Barber  John R. Beckett  Julie M. Paque  Edward Stolper 《Meteoritics & planetary science》1994,29(5):682-690

Abstract The crystallography and crystal chemistry of a new calcium-titanium-aluminosilicate mineral (UNK) observed in synthetic analogs to calcium-aluminum-rich inclusions (CAIs) from carbonaceous chondrites was studied by electron diffraction techniques. The unit cell is primitive hexagonal or trigonal, with a = 0.790 ± 0.002 nm and c = 0.492 ± 0.002 nm, similar to the lattice parameters of melilite and consistent with cell dimensions for crystals in a mixer furnace slag described by Barber and Agrell (1994). The phase frequently displays an epitactic relationship in which melilite acts as the host, with (0001)_UNK | (001)_mel and <10T0>_UNK | <100>_mel. If one of the two space groups determined by Barber and Agrell (1994) for their sample of UNK is applicable (P3ml or P31m), then the structure is probably characterized by puckered sheets of octahedra and tetrahedra perpendicular to the c-axis with successive sheets coordinated by planar arrays of Ca. In this likely structure, each unit cell contains three Ca sites located in mirror planes, one octahedrally coordinated cation located along a three-fold axis and five tetrahedrally coordinated cations, three in mirrors and two along triads. The octahedron contains Ti but, because there are 1.3–1.9 cations of Ti/formula unit, some of the Ti must also be in tetrahedral coordination, an unusual but not unprecedented situation for a silicate. Tetrahedral sites in mirror planes would contain mostly Si, with lesser amounts of Al while those along the triads correspondingly contain mostly Al with subordinate Ti. The structural formula, therefore, can be expressed as with Si + Ti = 4. Compositions of meteoritic and synthetic Ti-bearing samples of the phase can be described in terms of a binary solid solution between the end-members Ca₃TiAl₂Si₃O₁₄ and Ca₃Ti(AlTi)(AlSi₂)O₁₄. A Ti-free analog with a formula of Ca₃Al₂Si₄O₁₄ synthesized by Paque et al. (1994) is thought to be related structurally but with the octahedral site being occupied by Al, that is   相似文献   

Petrology of ultramafic and mafic xenoliths in picrite of Kahoolawe Island,Hawaii     

E A Rudek  R V Fodor  G R Bauer 《Bulletin of Volcanology》1992,55(1-2):74-84

A picrite lava (22 wt% MgO; 35 vol.% ol) along the western shore of the1.3–1.4 Ma Kahoolawe tholeiitic shield, Hawaii, contains small xenoliths of harzburgite, lherzolite, norite, and wehrlite. The various rock types have textures where either orthopyroxene, clinopyroxene, or plagioclase is in a poikilitic relationship with olivine. The Mg#s of the olivine, orthopyroxene, and clinopyroxene in this xenolith suite range between 86 and 82; spinel Mg#s range from 60 to 49, and plagioclase is An_75–80. A ⁸⁷Sr/⁸⁶Sr ratio for one ol-norite xenolith is 0.70444. In comparison, the host picrite has olivine phenocrysts with an average Mg# of 86.2 (range 87.5–84.5), and a whole-rock ⁸⁷Sr/⁸⁶Sr ratio of 0.70426. Textural and isotopic information together with mineral compositions indicate that the xenoliths are related to Kahoolawe tholeiitic magmatism, but are not crystallization products of the magma represented by their host picrite. Rather, the xenoliths are crystalline products of earlier primitive liquids (FeO/MgO ranging 1 to 1.3) at 5–9 kbar in the cumulate environment of a magma reservoir or conduit system. The presence of ultramafic xenoliths in picrite but not in typical Kahoolawe tholeiitic lava (6–9 wt% MgO) is consistent with replenishment of reservoirs by dense Mg-rich magma emplaced beneath resident, less dense tholeiitic magma. Mg-rich magmas have proximity to reservoir cumulate zones and are therefore more likely than fractionated residual liquids to entrain fragments of cumulate rock.  相似文献