Temperature effects on non-bridging oxygen and aluminum coordination number in calcium aluminosilicate glasses and melts     

Jonathan F. Stebbins  Emily V. Dubinsky  Koji Kanehashi  Kimberly E. Kelsey 《Geochimica et cosmochimica acta》2008,72(3):910-925

Configurational changes with temperature are important for the thermodynamic and transport properties of most aluminosilicate melts, but in general are not well understood. Here, we present high-resolution ²⁷Al and ¹⁷O NMR data on several calcium aluminosilicate glasses prepared with varying quench rates and thus with fictive temperatures that span ranges up to about 200 K. In all compositions the content of five-coordinated aluminum increases with fictive temperature, in agreement with recent high temperature NMR data on melts. In a glass of CaAl₂Si₂O₈ (“anorthite”) composition, the content of non-bridging oxygens also increases with temperature; however this effect was not observed in a sample with a much higher CaO/Al₂O₃ ratio. We present a consistent notation for reactions among structural species in these systems that clarify why in some cases, high-coordinated network cations may appear on the same side of the reaction, while in others they occur on the opposite sides: the key difference is in accounting for all coordination changes for oxygens. Mixing of non-bridging oxygens and of high-coordinated aluminum make significant contributions to the overall configurational entropy and heat capacity of the melts, as does the mixing of various bridging oxygens and of tetrahedral network cations. Other, less well known, types of increase in disorder with temperature may be important as well.  相似文献   

Growing up green on serpentine soils: Biogeochemistry of serpentine vegetation in the Central Coast Range of California     

Christopher Oze  Catherine Skinner  Andrew W. Schroth  Robert G. Coleman 《Applied Geochemistry》2008,23(12):3391-3403

Serpentine soils derived from the weathering of ultramafic rocks and their metamorphic derivatives (serpentinites) are chemically prohibitive for vegetative growth. Evaluating how serpentine vegetation is able to persist under these chemical conditions is difficult to ascertain due to the numerous factors (climate, relief, time, water availability, etc.) controlling and affecting plant growth. Here, the uptake, incorporation, and distribution of a wide variety of elements into the biomass of serpentine vegetation has been investigated relative to vegetation growing on an adjacent chert-derived soil. Soil pH, electrical conductivity, organic C, total N, soil extractable elements, total soil elemental compositions and plant digestions in conjunction with spider diagrams are utilized to determine the chemical relationships of these soil and plant systems. Plant available Mg and Ca in serpentine soils exceed values assessed in chert soils. Magnesium is nearly 3 times more abundant than Ca in the serpentine soils; however, the serpentine soils are not Ca deficient with Ca concentrations as high as 2235 mg kg⁻¹. Calcium to Mg ratios (Ca:Mg) in both serpentine and chert vegetation are greater than one in both below and above ground tissues. Soil and plant chemistry analyses support that Ca is not a limiting factor for plant growth and that serpentine vegetation is actively moderating Mg uptake as well as tolerating elevated concentrations of bioavailable Mg. Additionally, results demonstrate that serpentine vegetation suppresses the uptake of Fe, Cr, Ni, Mn and Co into its biomass. The suppressed uptake of these metals mainly occurs in the plants’ roots as evident by the comparatively lower metal concentrations present in above ground tissues (twigs, leaves and shoots). This research supports earlier studies that have suggested that ion uptake discrimination and ion suppression in the roots are major mechanisms for serpentine vegetation to tolerate the chemistry of serpentine soils.  相似文献   

Sedimentary development of the Louisiana continental shelf related to sea level cycles: Part II—seismic response     

James M. Coleman  Harry H. Roberts 《Geo-Marine Letters》1988,8(2):109-119

Cyclic sequences occur worldwide in nearly every stratigraphic sequence; they are particularly well-developed in fluvial and deltaic sediments that have been influenced by high-frequency eustatic sea-level fluctuations. The large data base for this study (including 471 deep foundation borings, thousands of line kilometers of high-resolution seismic, and sedimentological and dating analyses) represents the most complete information on high-resolution chronostratigraphy and lithostratigraphy that is available on any modern continental shelf/upper slope. These data are used to document sedimentological characteristics and high-resolution seismic responses during three complete sea-level cycles over the entire continental shelf/upper slope of offshore Louisiana. Examination of high-resolution seismic records indicates that well-defined, high-amplitude, laterally continuous reflectors correlate with rising and high stand condensed sedimentary sequences and that the deposits laid down during falling and low-stand periods (expanded sections) are characterized by a wide range of acoustic responses. Discontinuous reflectors with high-amplitude variability, continuous parallel reflectors, and chaotic and amorphous zones are common acoustic responses. The association between a particular lithofacies and a specific acoustic response on 3.5-kHz records was found to be very poor.  相似文献   

Influence of relative sea level changes on the construction of the Mississippi Fan     

Arnold H. Bouma  James M. Coleman  Charles E. Stelting  Barry Kohl 《Geo-Marine Letters》1989,9(3):161-170

A conceptual sea-level-driven depositional model for individual fanlobes (channel-overbank systems) of the Mississippi Fan does not permit direct application of the sequence stratigraphic principles of Vail and colleagues. Deep Sea Drilling Project Leg 96 results suggest that, during initial relative lowering of sea level, the canyon and upper fan channel were formed; excavated fine-grained slope sediments may have formed a debris flow deposit base for the fanlobe. Continued lowering produced constructional channel-levee-overbank deposits. Rising relative sea level inhibited input of coarse clastics, and channel depressions filled with muds. A blanket of (hemi)pelagics represents relative high sea level stand.  相似文献   

Multiple outlier detection by evaluating redundancy contributions of observations   总被引：3，自引：0，他引：3  

X. Ding  R. Coleman 《Journal of Geodesy》1996,70(8):489-498

When applying single outlier detection techniques, such as the Tau () test, to examine the residuals of observations for outliers, the number of detected observations in any iteration of adjustment is most often more numerous than the actual number of true outliers. A new technique is proposed which estimates the number of outliers in a network by evaluating the redundancy contributions of the detected observations. In this way, a number of potential outliers can be identified and eliminated in each iteration of an adjustment. This leads to higher efficiency in data snooping of geodetic networks. The technique is illustrated with some numerical examples.  相似文献   

The American whale oil industry: A look back to the future of the American petroleum industry?     

James L. Coleman Jr. 《Natural Resources Research》1995,4(3):273-288

The American whaling industry rose from humble beginnings off Long island to become an international giant. In its peak year, 1846, 735 ships and 70,000 people served the industry. As whale stocks and reserves decreased, whalers were forced to go farther and farther from their New England home ports. Voyages became longer, and risks on required return-on-investment became higher. The easy money of Atlantic and Pacific whaling was no more: the only remaining profitable ventures were to Arctic and Antarctic waters. Many ships returned empty, if at all. in 1871, most of the Arctic whaling fleet was crushed by early winter ice and lost. This calamity, in conjunction with the long-term diminishing whale stocks, the diversion of investment capital to more profitable ventures, and the discovery, development, and refinement of abundant petroleum crude oil, struck the death blow to the American whaling industry. By 1890, only 200 whaling vessels were at work, and by 1971, no American commercial whaling ship sailed the world's oceans.It is apparent that no single event caused the final, rapid decline. However, a single calamity, in an already stressed industry, that was self-insured and commercially interlinked, precipitated the end. Today's American petroleum industry, although adopting some principles of the American whaling industry, also has embraced other activities such as work process reengineering and customer alliances, which may preempt, or postpone, a similar catastrophic demise.  相似文献   

Diurnal variation in rates of calcification and carbonate sediment dissolution in Florida Bay   总被引：2，自引：0，他引：2  

Kimberly K. Yates  Robert B. Halley 《Estuaries and Coasts》2006,29(1):24-39

Water quality and criculation in Florida Bay (a shallow, subtropical estuary in south Florida) are highly dependent upon the development and evolution of carbonate mud banks distributed throughout the Bay. Predicting the effect of natural and anthropogenic perturbations on carbonate sedimentation requires an understanding of annual, seasonal, and daily variations in the biogenic and inorganic processes affecting carbonate sediment precipitation and dissolution. In this study, net calcification rates were measured over diurnal cycles on 27 d during summer and winter from 1999 to 2003 on mud banks and four representative substrate types located within basins between mud banks. Substrate types that were measured in basins include seagrass beds of sparse and intermediate densityThalassia sp., mud bottom, and hard bottom communities. Changes in total alkalinity were used as a proxy for calcification and dissolution. On 22 d (81%), diurnal variation in rates of net calcification was observed. The highest rates of net carbonate sediment production (or lowest rates of net dissolution) generally occurred during daylight hours and ranged from 2.900 to −0.410 g CaCO₃ m⁻²d⁻¹. The lowest rates of carbonate sediment production (or net sediment dissolution) occurred at night and ranged from 0.210 to −1.900 g CaCO₃ m⁻² night⁻¹. During typical diurnal cycles, dissolution during the night consumed an average of 29% of sediment produced during the day on banks and 68% of sediment produced during the day in basins. Net sediment dissolution also occurred during daylight, but only when there was total cloud cover, high turbidity, or hypersalinity. Diurnal variation in calcification and dissolution in surface waters and surface sediments of Florida Bay is linked to cycling of carbon dioxide through photosynthesis and respiration. Estimation of long-term sediment accumulation rates from diurnal rates of carbonate sediment production measured in this study indicates an overall average accumulation rate for Florida Bay of 8.7 cm 1000 yr⁻¹ and suggests that sediment dissolution plays a more important role than sediment transport in loss of sediment from Florida Bay.  相似文献   

The thermodynamic influence of subgrid orography in a global climate model     

S. Ghan  X. Bian  A. Hunt  A. Coleman 《Climate Dynamics》2002,20(1):31-44

Assessments of the impacts of climate change typically require information at scales of 10 km or less. Such a resolution in global climate simulations is unlikely for at least two decades. We have developed an alternative to explicit resolution that provides a framework for meeting the needs of climate change impact assessment much sooner. We have applied to a global climate model a physically based subgrid-scale treatment of the influence of orography on temperature, clouds, precipitation, and land surface hydrology. The treatment represents subgrid variations in surface elevation in terms of fractional area distributions of discrete elevation classes. For each class it calculates the height rise/descent of air parcels traveling through the grid cell, and applies the influence of the rise/descent to the temperature and humidity profiles of the elevation class. Cloud, radiative, and surface processes are calculated separately for each elevation class using the same physical parametrizations used by the model without the subgrid orography parametrization. The simulated climate fields for each elevation class can then be distributed in post-processing according to the spatial distribution of surface elevation within each grid cell. Parallel 10-year simulations with and without the subgrid treatment have been performed. The simulated temperature, precipitation and snow water are mapped to 2.5-minute (~5 km) resolution and compared with gridded analyses of station measurements. The simulation with the subgrid scheme produces a much more realistic distribution of snow water and significantly more realistic distributions of temperature and precipitation than the simulation without the subgrid scheme. Moreover, the 250-km grid cell means of most other fields are virtually unchanged by the subgrid scheme. This suggests that the tuning of the climate model without the subgrid scheme is also applicable to the model with the scheme.  相似文献   

Assessing the effects of catchment‐scale urban green infrastructure retrofits on hydrograph characteristics          下载免费PDF全文

Kimberly M. Jarden  Anne J. Jefferson  Jennifer M. Grieser 《水文研究》2016,30(10):1536-1550

Run‐off from impervious surfaces has pervasive and serious consequences for urban streams, but the detrimental effects of urban stormwater can be lessened by disconnecting impervious surfaces and redirecting run‐off to decentralized green infrastructure. This study used a before–after‐control‐impact design, in which streets served as subcatchments, to quantify hydrologic effectiveness of street‐scale investments in green infrastructure, such as street‐connected bioretention cells, rain gardens and rain barrels. On the two residential treatment streets, voluntary participation resulted in 32.2% and 13.5% of parcels having green infrastructure installed over a 2‐year period. Storm sewer discharge was measured before and after green infrastructure implementation, and peak discharge, total run‐off volume and hydrograph lags were analysed. On the street with smaller lots and lower participation, green infrastructure installation succeeded in reducing peak discharge by up to 33% and total storm run‐off by up to 40%. On the street with larger lots and higher participation, there was no significant reduction in peak or total stormflows, but on this street, contemporaneous street repairs may have offset improvements. On the street with smaller lots, lag times increased following the first phase of green infrastructure construction, in which streetside bioretention cells were built with underdrains. In the second phase, lag times did not change further, because bioretention cells were built without underdrains and water was removed from the system, rather than just delayed. We conclude that voluntary green infrastructure retrofits that include treatment of street run‐off can be effective for substantially reducing stormwater but that small differences in design and construction can be important for determining the level of the benefit. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

A new type of article for Terra Nova          下载免费PDF全文

Max Coleman  Jean Braun  Georges Calas  Carlo Doglioni  Klaus Mezger  Jason Phipps Morgan 《地学学报》2015,27(6):399-399

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