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Edmundo Placencia-Gómez Annika Parviainen Tero Hokkanen Kirsti Loukola-Ruskeeniemi 《Environmental Earth Sciences》2010,61(7):1435-1447
The Haveri tailings area contains 1.5 Mt of sulfide-bearing waste from the Au–Cu mine that operated during 1942–1961. Geophysical
and geochemical methods were used to evaluate and characterize the generation of acid mine drainage (AMD). Correlations were
examined among the electrical resistivity tomography (ERT) data, the total sulfide content and concentrations of sulfide-bound
metals (Cu, Co, Fe, Mn, Ni, Pb and Zn) of tailings samples, and the resistivity and geochemistry of surface water. The resulting
geophysical–geochemical model defines an area in the vadose tailings, where a low resistivity anomaly (<10 Ohm m) is correlated
with the highest sulfide content, extensive sulfide oxidation and low pH (average 3.1). The physical and geochemical conditions,
resulting from the oxidation of the sulfide minerals, suggest that the low resistivity anomaly is associated with acidic and
metal-rich porewater (i.e., AMD). The lower resistivity values in the saturated zone of the central impoundment suggest the
formation of a plume of AMD. The natural subsoil layer (silt and clay) and the bedrock surface below the tailings area were
well mapped from the ERT data. The detected fracture zones of the bedrock that could work as leakage pathways for AMD were
consistent with previous geological studies. The integrated methodology of the study offers a promising approach to fast and
reliable monitoring of areas of potential AMD generation and its subsurface movement over large areas (ca. 9 ha). This methodology
could be helpful in planning drill core sampling locations for geochemical and mineralogical analysis, groundwater sampling,
and choosing and monitoring remedial programs. 相似文献
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K. Kauristie T. I. Pulkkinen R. J. Pellinen H. J. Opgenoorth 《Annales Geophysicae》1997,14(11):1177-1185
The AE indices are generally used for monitoring the level of magnetic activity in the auroral oval region. In some cases, however, the oval is either so expanded or contracted that the latitudinal coverage of the AE magnetometer chain is not adequate. Then, a longitudinal chain in the key region would give more information of the real situation, but, of course, only during some limited UT-period. In order to find out the UT coverage of a single meridional chain, we have compared the global AL and AU indices with corresponding local indices determined using data from the meridional part of the EISCAT Magnetometer Cross during the years 1985–1987. A statistical study shows that the local indices are close (within relative error of 0.2) to the global AU and AL during periods 1500–2000 UT ( 1730–2230 MLT) and 2130–0130 UT (000–0400 MLT), respectively. In the middle of these optimal MLT-sectors the EISCAT Cross sees more than 70% of the cases when the global AE chain records activity. Then, also the correlation between the local and global indices is generally good (>0.7). Thus we conclude that five to six evenly located meridional chains are needed for covering all the UT-periods. On the other hand, already the combination of IMAGE, CANOPUS, and the Greenland chains catches 50% of the substorms. Case-studies show that usually during 2130 – 1100 UT the AL achieved from these chains reproduces the real AL with good timing, although it does not follow all transient variations. 相似文献
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Annika Parviainen Matthew B.J. Lindsay Rafael Pérez-López Blair D. Gibson Carol J. Ptacek David W. Blowes Kirsti Loukola-Ruskeeniemi 《Applied Geochemistry》2012
Nearly half a century after mine closure, release of As from the Ylöjärvi Cu–W–As mine tailings in groundwater and surface water run-off was observed. Investigations by scanning electron microscopy (SEM), electron microprobe analysis (EMPA), synchrotron-based micro-X-ray diffraction (μ-XRD), micro-X-ray absorption near edge structure (μ-XANES) and micro-extended X-ray absorption fine structure (μ-EXAFS) spectroscopy, and a sequential extraction procedure were performed to assess As attenuation mechanisms in the vadose zone of this tailings deposit. Results of SEM, EMPA, and sequential extractions indicated that the precipitation of As bearing Fe(III) (oxy)hydroxides (up to 18.4 wt.% As2O5) and Fe(III) arsenates were important secondary controls on As mobility. The μ-XRD, μ-XANES and μ-EXAFS analyses suggested that these phases correspond to poorly crystalline and disordered As-bearing precipitates, including arsenical ferrihydrite, scorodite, kaňkite, and hydrous ferric arsenate (HFA). The pH within 200 cm of the tailings surface averaged 5.7, conditions which favor the precipitation of ferrihydrite. Poorly crystalline Fe(III) arsenates are potentially unstable over time, and their transformation to ferrihydrite, which contributes to As uptake, has potential to increase the As adsorption capacity of the tailings. Arsenic mobility in tailings pore water at the Ylöjärvi mine will depend on continued arsenopyrite oxidation, dissolution or transformation of secondary Fe(III) arsenates, and the As adsorption capacity of Fe(III) (oxy)hydroxides within this tailings deposit. 相似文献
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While the plasma convection in the Earth's magnetosphere was for a long timeconsidered to consist mostly of laminar flows with wide spatial extents, about adecade ago the phenomenon of bursty bulk flows (BBFs), which now could beunderstood as long, but narrow channels of fast earthward plasma flow in thecentral plasma sheet of the magnetospheric tail, was discovered. Soon after thisit became clear that such events are not exceptional, but a large portion of theearthward plasma flow in the inner part of the magnetospheric tail is organisedin this bursty, intermittent mode. Since the Earth's magnetosphere is connectedby highly conducting magnetic field lines with its ionosphere, the next logicalstep was the search for the ionospheric signatures of BBFs. We review the resultsobtained so far in this young field of Space Physics, in terms of theauroral and ground magnetic signatures caused by BBFs, the particle precipitationto the ionosphere, as well as of the ionospheric electrodynamics of the processesassociated with the BBFs in the magnetosphere. Finally, we briefly review somemodels of ionosphere-magnetosphere coupling with respect to their ability to explainthe ionospheric signatures observed. 相似文献
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Seasonal GCM-based temperature and precipitation projections for the end of the 21st century are presented for five European regions; projections are compared with corresponding estimates given by the PRUDENCE RCMs. For most of the six global GCMs studied, only responses to the SRES A2 and B2 forcing scenarios are available. To formulate projections for the A1FI and B1 forcing scenarios, a super-ensemble pattern-scaling technique has been developed. This method uses linear regression to represent the relationship between the local GCM-simulated response and the global mean temperature change simulated by a simple climate model. The method has several advantages: e.g., the noise caused by internal variability is reduced, and the information provided by GCM runs performed with various forcing scenarios is utilized effectively. The super-ensemble method proved especially useful when only one A2 and one B2 simulation is available for an individual GCM. Next, 95% probability intervals were constructed for regional temperature and precipitation change, separately for the four forcing scenarios, by fitting a normal distribution to the set of projections calculated by the GCMs. For the high-end of the A1FI uncertainty interval, temperature increases close to 10°C could be expected in the southern European summer and northern European winter. Conversely, the low-end warming estimates for the B1 scenario are ~ 1°C. The uncertainty intervals of precipitation change are quite broad, but the mean estimate is one of a marked increase in the north in winter and a drastic reduction in the south in summer. In the RCM simulations driven by a single global model, the spread of the temperature and precipitation projections tends to be smaller than that in the GCM simulations, but it is possible to reduce this disparity by employing several driving models for all RCMs. In the present suite of simulations, the difference between the mean GCM and RCM projections is fairly small, regardless of the number or driving models applied. 相似文献
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K. Kauristie M. V. Uspensky N. G. Kleimenova O. V. Kozyreva S. V. Dubyagin A. A. Vlasov 《Geomagnetism and Aeronomy》2013,53(5):613-625
The analysis results of a complex of phenomena that were developing in the evening and morning magnetospheric and ionospheric sectors during two events (January 18 and February 19, 2008) are presented. The analysis is based on the observation data in the magnetotail from the THEMIS satellites and ground-based observations in the morning (MIRACLE network) and nighttime (THEMIS ground-based network) sectors. The events with moderate substorms in the nighttime sector were preceded by strong geomagnetic Pc5 pulsations in the morning sector, the regime of which changed during the development of auroral disturbances. The substorms were accompanied by dipolizations in the magnetotail at distances of ~10 Re and unexpected jump-like fluxes of ～200-keV electrons. The fluxes appeared within several minutes after a breakup at three central THEMIS satellites simultaneously spaced up to 1.7 Re. According with the ASC data at the NAL observatory (3 frames/min) and with the THEMIS network of ASC data, onset of auroral activations in the night and morning sectors occurred simultaneously. Probable reasons for the sudden suppression or intensification of Pc5 pulsations are discussed. 相似文献
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Andreï Lecomte Michel Cathelineau Etienne Deloule Marc Brouand Chantal Peiffert Kirsti Loukola-Ruskeeniemi Esa Pohjolainen Hannu Lahtinen 《Mineralium Deposita》2014,49(4):513-533
In the central part of the Fennoscandian Shield, the Talvivaara Ni–Zn–Cu–Co deposit, hosted by Palaeoproterozoic metamorphosed black schists, contains low uranium concentrations ranging from 10 to 30 ppm. The Talvivaara black schists were deposited 2.0–1.9 Ga ago and underwent subsequent metamorphism during the 1.9–1.79 Ga Svecofennian orogeny. Anhedral uraninite crystals rimmed by bitumen constitute the main host of uranium. U–Pb secondary ion mass spectrometry dating indicates that uraninite crystals were formed between 1,878?±?17 and 1,871?±?43 Ma, during peak metamorphism. Rare earth element patterns and high Th content (average 6.38 wt%) in disseminated uraninite crystals indicate that U was concentrated during high temperature metamorphism (>400 °C). The formation of bitumen rims around uraninite may be explained by two distinct scenarios: (a) a transport of U coincident with the migration of hydrocarbons or (b) post-metamorphic formation of bitumen rims, through radiolytic polymerization of gaseous hydrocarbons at the contact with uraninite. 相似文献
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James M. Weygand R.L McPherron K. Kauristie H.U. Frey T.-S. Hsu 《Journal of Atmospheric and Solar》2008,70(18):2336-2345
In this study, we investigate the relation of auroral substorm onset to the sharp decrease in the local AL index (IL) during substorms. With a database of over 4200 onsets determined from auroral images, we have statistically examined the timing between the auroral substorm onset and the sharp decrease in the IL index, as determined with data from the IMAGE magnetometer network. From the database of onsets, 54 substorms were determined to be within 6° of the central meridian of the IMAGE ground array. Our superposed epoch median curve shows that the IL index begins to sharply decrease 3 min before the auroral onset, which is twice the 2 min resolution of the auroral imager. However, the mean difference determined by measuring the time between the start of the IL decrease and the auroral substorm onset is about 1.1±0.6 min. An analysis of the superposed epoch median curves of the SOPA particle data for the LANL spacecraft closest to the auroral onset meridian indicates that both the electron and proton injections begin about 3 min before the auroral onset. However, the mean time of the difference between the minimum of the particle dispersionless injection and the auroral onset is simultaneous within the uncertainty of the auroral onset and the error of the mean for the injection. The location of the electron injection relative to the IMAGE ground array seems to be 01–04 MLT, while the proton injection appears to be in the 22–01 MLT sector. These statistical results support the idea that the field aligned and ionospheric currents of the substorm current wedge begin to flow before the auroral onset. 相似文献