Sediment Trend Analysis through the variation of granulometric parameters: A review of theories and applications     

Emmanuel Poizot  Yann Méar  Laurie Biscara 《Earth》2008,86(1-4):15-41

Spatial variations in grain-size parameters (i.e. grain-size trends) contain information on sediment transport patterns. Analytical procedures have been proposed using the grain-size trend to determine net sediment transport pathways. In the first part of this study, the fundamentals of the theory are presented through methods for analysing 1D and 2D variations. The methods used are critically discussed, while pointing out some severe problems. So far, these methods suffer from limitations leading to serious interpretational errors, making it necessary to take account of two kinds of uncertainties. Inputs uncertainties are linked to the physical sediment properties as well as procedures of sampling and analysis. Model uncertainties are then discussed for each step of the grain-size trend analysis. The validity of Sediment Trend Analysis under natural conditions is tested against published field studies to determine the most appropriate variation trend to use in a specific environment. Proposals are given for each step of the procedure for optimal use of the method using a Quality Assurance (QA) approach. Further developments are proposed, such as integration into a Geographic Information System.  相似文献   

Fractionation of Cu and Zn isotopes during adsorption onto amorphous Fe(III) oxyhydroxide: Experimental mixing of acid rock drainage and ambient river water     

Laurie S. Balistrieri  David M. Borrok  W. Ian Ridley 《Geochimica et cosmochimica acta》2008,72(2):311-328

Fractionation of Cu and Zn isotopes during adsorption onto amorphous ferric oxyhydroxide is examined in experimental mixtures of metal-rich acid rock drainage and relatively pure river water and during batch adsorption experiments using synthetic ferrihydrite. A diverse set of Cu- and Zn-bearing solutions was examined, including natural waters, complex synthetic acid rock drainage, and simple NaNO₃ electrolyte. Metal adsorption data are combined with isotopic measurements of dissolved Cu (⁶⁵Cu/⁶³Cu) and Zn (⁶⁶Zn/⁶⁴Zn) in each of the experiments. Fractionation of Cu and Zn isotopes occurs during adsorption of the metal onto amorphous ferric oxyhydroxide. The adsorption data are modeled successfully using the diffuse double layer model in PHREEQC. The isotopic data are best described by a closed system, equilibrium exchange model. The fractionation factors (α_soln-solid) are 0.99927 ± 0.00008 for Cu and 0.99948 ± 0.00004 for Zn or, alternately, the separation factors (Δ_soln-solid) are −0.73 ± 0.08‰ for Cu and −0.52 ± 0.04‰ for Zn. These factors indicate that the heavier isotope preferentially adsorbs onto the oxyhydroxide surface, which is consistent with shorter metal-oxygen bonds and lower coordination number for the metal at the surface relative to the aqueous ion. Fractionation of Cu isotopes also is greater than that for Zn isotopes. Limited isotopic data for adsorption of Cu, Fe(II), and Zn onto amorphous ferric oxyhydroxide suggest that isotopic fractionation is related to the intrinsic equilibrium constants that define aqueous metal interactions with oxyhydroxide surface sites. Greater isotopic fractionation occurs with stronger metal binding by the oxyhydroxide with Cu > Zn > Fe(II).  相似文献   

Dissolved and labile concentrations of Cd, Cu, Pb, and Zn in the South Fork Coeur d’Alene River, Idaho: Comparisons among chemical equilibrium models and implications for biotic ligand models     

Laurie S. Balistrieri  Richard G. Blank 《Applied Geochemistry》2008,23(12):3355-3371

In order to evaluate thermodynamic speciation calculations inherent in biotic ligand models, the speciation of dissolved Cd, Cu, Pb, and Zn in aquatic systems influenced by historical mining activities is examined using equilibrium computer models and the diffusive gradients in thin films (DGT) technique. Several metal/organic-matter complexation models, including WHAM VI, NICA-Donnan, and Stockholm Humic model (SHM), are used in combination with inorganic speciation models to calculate the thermodynamic speciation of dissolved metals and concentrations of metal associated with biotic ligands (e.g., fish gills). Maximum dynamic metal concentrations, determined from total dissolved metal concentrations and thermodynamic speciation calculations, are compared with labile metal concentrations measured by DGT to assess which metal/organic-matter complexation model best describes metal speciation and, thereby, biotic ligand speciation, in the studied systems. Results indicate that the choice of model that defines metal/organic-matter interactions does not affect calculated concentrations of Cd and Zn associated with biotic ligands for geochemical conditions in the study area, whereas concentrations of Cu and Pb associated with biotic ligands depend on whether the speciation calculations use WHAM VI, NICA-Donnan, or SHM. Agreement between labile metal concentrations and dynamic metal concentrations occurs when WHAM VI is used to calculate Cu speciation and SHM is used to calculate Pb speciation. Additional work in systems that contain wide ranges in concentrations of multiple metals should incorporate analytical speciation methods, such as DGT, to constrain the speciation component of biotic ligand models.  相似文献   

Carbon dioxide partial pressures in North Pacific surface waters — Time variations     

Louis I. Gordon  P. Kilho Park  Stephen W. Hager  Timothy R. Parsons 《Journal of Oceanography》1971,27(3):81-90

Observations were made of time variations of the carbon dioxide partial pressures (Pco₂) of the atmosphere and surface sea waters in the Pacific subarctic region. Data were obtained on a cruise of the USC & GSSSURVEYOR in October, 1968 and on the TRANSPAC expedition of the CNAVENDEAVOUR in March–April, 1969. A rise in surface water Pco₂ of 18×10^–6 atm occurred in a period of 30–45 days in March–April due principally to spring warming of surface waters. An average increase of 60×10^–6 atm occurred between October, 1968 and March, 1969 as a result mainly of cessation of summer phytoplankton production and the onset of winter-storm-driven vertical mixing. Because the air-sea Pco₂ gradient not only changed appreciably in magnitude but also changed sign, there are important implications for calculations of air-sea exchange of carbon dioxide on the ocean wide scale.Data contained in this paper comprise part of a dissertation to be submitted by Louis I. Gordon in partial fulfillment of the requirements for the Ph. D. at Oregon State University.  相似文献   

Trophodynamic phasing in theoretical,experimental aud natural pelagic ecosystems     

Timothy R. Parsons 《Journal of Oceanography》1988,44(2):94-101

It is a great honour to be awarded the Oceanographical Society of Japan Prize for 1988 and to be provided with this opportunity to review our work on trophic relations in the pelagic environment of the sea. Many Japanese colleagues have participated in Canada on our experiments. These persons include Drs. H. Seki, M. Takahashi, A. Hattori, T. Ikeda, I. Koike, M. Ohtsu, S. Ichimura, K. Iseki, E. Matsumoto, N. Handa, Y. Maita, and others without whom our work on marine ecosystems would have assumed much less importance. In addition, the visit of Professor M. Uda to Nanaimo in 1959, and his lectures on fisheries oceanography, have always been an inspiration to me in the practical application of oceanography. For me, work on trophodynamic relationships grew out of my early association with Dr. J.D.H. Strickland who initiated some ecosystem studies using large plastic bags in the 1960s (Strickland and Terhune, 1961; Strickland, 1967). The CEPEX program (e.g. Parsons, 1978), which was started about a decade later, gave us the first real opportunity to break away from laboratory studies, where only species which generally grew best were studied, and to perform studies under near natural conditions on multiorganism communities. The purpose of this program was to provide some answers to practical problems as well as to gain a fundamental understanding of biological oceanographic processes. This program was started at a time when a large number of stories were circulating (e.g. Heyerdahl, 1975) that man was about to kill life in the oceans through pollution. In a practical sense what I believe that the CEPEX program showed was that the oceans were much more resilient than had been supposed. The effect of many kinds of pollutants tested during this program was to change the course of ecosystem interactions but not to cause the elimination of life. The scientific value of these experiments went much further in giving us time series data about how the physical/chemical environment interacts with different trophic levels. For the first time, the biological oceanographer was liberated from the hopeless entanglement of time and space in the sea, and it was now possible to follow population dynamics of planktonic organisms (Mullin, 1982). Presented at the annual meeting, Tokyo, 4 April 1988.  相似文献   

The use of controlled experimental ecosystems: A review     

T. R. Parsons 《Journal of Oceanography》1981,37(5):294-298

During the past 20 years, the controlled experimental ecosystem has found wide-spread use in marine sciences. Uses have included the study of natural ecology, environmental pollution and computer model analysis. In all these roles, the experimental ecosystem serves as a model of nature and results can be used to obtain greater insight into the oceanography of the sea. Four different types of experimental apparatus are described, and experimental procedures and results are reviewed and discussed.  相似文献   

The Dahuiyeh (Zarand) earthquake of 2005 February 22 in central Iran: reactivation of an intramountain reverse fault   总被引：3，自引：0，他引：3  

M. Talebian  J. Biggs  M. Bolourchi  A. Copley  A. Ghassemi  M. Ghorashi  J. Hollingsworth  J. Jackson  E. Nissen  B. Oveisi  B. Parsons  K. Priestley  A. Saiidi 《Geophysical Journal International》2006,164(1):137-148

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Responses of interrill runoff and erosion rates to vegetation change in southern Arizona   总被引：1，自引：0，他引：1  

Anthony J. Parsons  Athol D. Abrahams  John Wainwright 《Geomorphology》1996,14(4):311-317

Vegetation change, fi-om grassland to shrubland, has occurred over much of the Sonoran and Chihuahuan Deserts during the past century. The effect of this vegetation change on interrill runoff and erosion was examined by conducting rainfall-simulation experiments on large runoff plots on contemporary grassland and shrubland hillslopes. These experiments show that, compared to the grassland, the interrill portions of shrubland hillslopes (1) have higher runoff rates, (2) experience equilibrium runoff conditions much more frequently, (3) exhibit higher overland flow velocities, and (4) are subject to greater rates of erosion. The environmental change that has led to the vegetation change has been relatively minor, but its geomorphic impact has been substantial.  相似文献   

Oxygen isotope heterogeneity in chondrules from the Mokoia CV3 carbonaceous chondrite     

Rhian H Jones  Laurie A Leshin  Zachary D Sharp  Alan J Schilk 《Geochimica et cosmochimica acta》2004,68(16):3423-3438

We report a study of the oxygen isotope ratios of chondrules and their constituent mineral grains from the Mokoia, oxidized CV3 chondrite. Bulk oxygen isotope ratios of 23 individual chondrules were determined by laser ablation fluorination, and oxygen isotope ratios of individual grains, mostly olivine, were obtained in situ on polished mounts using secondary ion mass spectrometry (SIMS). Our results can be compared with data obtained previously for the oxidized CV3 chondrite, Allende. Bulk oxygen isotope ratios of Mokoia chondrules form an array on an oxygen three-isotope plot that is subparallel to, and slightly displaced from, the CCAM (carbonaceous chondrite anhydrous minerals) line. The best-fit line for all CV3 chondrite chondrules has a slope of 0.99, and is displaced significantly (by δ¹⁷O ∼ −2.5‰) from the Young and Russell slope-one line for unaltered calcium-aluminum-rich inclusion (CAI) minerals. Oxygen isotope ratios of many bulk CAIs also lie on the CV-chondrule line, which is the most relevant oxygen isotope array for most CV chondrite components. Bulk oxygen isotope ratios of most chondrules in Mokoia have δ¹⁸O values around 0‰, and olivine grains in these chondrules have similar oxygen isotope ratios to their bulk values. In general, it appears that chondrule mesostases have higher δ¹⁸O values than olivines in the same chondrules. Our bulk chondrule data spread to lower δ¹⁸O values than any ferromagnesian chondrules that have been measured previously. Two chondrules with the lowest bulk δ¹⁸O values (−7.5‰ and −11.7‰) contain olivine grains that display an extremely wide range of oxygen isotope ratios, down to δ¹⁷O, δ¹⁸O around -50‰ in one chondrule. In these chondrules, there are no apparent relict grains, and essentially no relationships between olivine compositions, which are homogeneous, and oxygen isotopic compositions of individual grains. Heterogeneity of oxygen isotope ratios within these chondrules may be the result of incorporation of relict grains from objects such as amoeboid olivine aggregates, followed by solid-state chemical diffusion without concomitant oxygen equilibration. Alternatively, oxygen isotope exchange between an ¹⁶O-rich precursor and an ¹⁶O-poor gas may have taken place during chondrule formation, and these chondrules may represent partially equilibrated systems in which isotopic heterogeneities became frozen into the crystallizing olivine grains. If this is the case, we can infer that the earliest nebular solids from which chondrules formed had δ¹⁷O and δ¹⁸O values around -50‰, similar to those observed in refractory inclusions.  相似文献   

PUTTING THE MESSINESS BACK IN: TOWARDS A GEOGRAPHY OF DEVELOPMENT AS CREATIVITY     

Nina D. Laurie 《Singapore journal of tropical geography》2005,26(1):32-35

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