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In the Carajás District, the Bahia Prospect and Grão Pará volcanosedimentary sequences, both of Archean age, have been the object of extensive petrochemical studies for major, trace, and rare earth elements. In spite of the widespread spilitization that affected the volcanic mafic rocks, the petrochemical nature of the mafic volcanism may still be assessed on the basis of the less mobile elements like P, Cr, Zr, Nb, Ti, and REE. The Bahia Prospect basalts have a petrochemical affinity with Phanerozoic island-arc calc-alkaline basalts. The Grão Pará basalts and basaltic andesites, on the other hand, have a petrochemical affinity with Phanerozoic basalts of a mature island arc environment. The petrochemical data presented here lead to a new geotectonic interpretation of the area, where the volcanic sequences are genetically linked to Archean subduction processes.  相似文献   
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The main pioneer frontier considered by geographers is the Amazonian pioneer frontier. The occupation of the Brazilian territory has been carried out through successive economic cycles. Currently, the expansion of soybean crops in Amazonia is considered as the last economic cycle involving new migrations to still unexplored areas. Mapping this frontier is necessary in order to better understand its drivers and think about efficient land use policies to struggle its progress. In this paper, we propose an innovative methodology for mapping the agricultural frontier in the Amazonian state of Mato Grosso (Brazil) using satellite data acquired during the 2000–2006 period. We assume that the frontier evolves through successive land-use stages such as wildlands, non-croplands, extensive croplands and intensive croplands areas. The transitions between two stages can then be monitored through land-use change analysis. A particular emphasis is given on three land-use transitions named “deforestation”, “economic” and “intensification sub-frontiers”. In order to adapt this model for the use of remote sensing data, we defined (1) a relevant spatial scale corresponding to an agrarian locality, (2) relevant indices to qualify the land-use types and (3) rules applied on land-use types to define the frontier’s location. Our results highlight the dynamic of the agricultural frontier towards northern areas. We identified four main agricultural regions with different levels of agricultural intensification. We finally discuss these results with respect to governmental policies and economics for a better understanding of the frontier’s dynamic.  相似文献   
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The Amazonian state of Mato Grosso is the main production area for soybeans in Brazil and contains 31.3% of the national production as of 2009. The rapid evolution of the agricultural systems in this area shows that the region is experiencing a rapid agricultural transition. In this paper, we broke down this transition process into three steps: crop expansion, agricultural intensification and ecological intensification. We used remote sensing products to develop and compute satellite-derived indices describing the main agricultural dynamics during the cropping years from 2000-2001 to 2006-2007. Our results indicated that Mato Grosso is continuing to expand its agricultural sector, with a 43% increase in the net cropped area during the study period. Although this expansion mainly occurred in the cerrado ecoregion until the early 2000s, the forest ecoregion is experiencing expansion at this time. We observed that 65% of the crop expansion in Mato Grosso from 2000 to 2006 occurred in this ecoregion. However, we did not identify this crop expansion as the major driver of deforestation in Mato Grosso because only 12.6% of the cleared areas were directly converted into croplands. Agricultural intensification also evolved rapidly, as the proportion of the net cropped area cultivated with double cropping systems harvesting two successive commercial crops (i.e., soybean and corn or soybean and cotton) increased from 6% to 30% during the study period. Finally, we found that ecological intensification occurred because the region’s farmers planted a non-commercial crop (i.e., millet or sorghum) after the soybean harvest to prevent soil erosion, improve soil quality, break pest cycles, maintain soil moisture and set the conditions for high-quality no-tillage operations. In 2006-2007, 62% of the net cropped area was permanently covered by crops during the entire rainy season. This practice allowed the farmers to diversify their production, as shown by the positive evolution of the Area Diversity Index. Future scholars can use the method proposed in this paper to improve their understanding of the forces driving the agricultural dynamics in Mato Grosso.  相似文献   
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Determinations of the volatile elements carbon, hydrogen, sulfur and nitrogen in many geological RM, performed with the LECO CHN and SC analysers, are presented. The method allowed the determination of S in concentrations from a few % m/m to 0.001% m/m or less, of C from % m/m to 0.01% m/m and of H from % m/m to 0.004% m/m. Accuracy was usually better than the XRF method (for S). All obtained values passed the Sutarno-Steger test, which establishes that |(meananalysed - meancertified)|/ Scertified < 2, for the cases with an appropriate number of determinations (n > 10 for each element). It was possible to perform routine determination of C, H and S with the instrumentation, coupled with the determination of major and minor elements in geological materials. Determination of nitrogen could also be performed on an exploratory basis, with improvements in the method dependent on the future availability of more reference materials with reliable composition of this element.  相似文献   
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Tests are described showing the results obtained for the determination of REE and the trace elements Rb, Y, Zr, Nb, Cs, Ba, Hf, Ta, Pb, Th and U with ICP-MS methodology for nine basaltic reference materials, and thirteen basalts and amphibolites from the mafic-ultramafic Niquelândia Complex, central Brazil. Sample decomposition for the reference materials was performed by microwave oven digestion (HF and HNO3, 100 mg of sample), and that for the Niquelândia samples also by Parr bomb treatment (5 days at 200°C, 40 mg of sample). Results for the reference materials were similar to published values, thus showing that the microwave technique can be used with confidence for basaltic rocks. No fluoride precipitates were observed in the microwave-digested solutions. Total recovery of elements, including Zr and Hf, was obtained for the Niquelândia samples, with the exception of an amphibolite. For this latter sample, the Parr method achieved a total digestion, but not so the microwave decomposition; losses, however, were observed only for Zr and Hf, indicating difficulty in dissolving Zr-bearing minerals by microwave acid attack.  相似文献   
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The complete dissolution of representative test portions of powdered rock samples for the determination of the mass fractions of trace elements by ICP‐MS relies either on aggressive and time‐consuming acid digestions or fusion/sintering with appropriate fluxes. Here, we evaluate a microwave oven dissolution method that employs a solution of NH4HF2 and HNO3. The entire procedure occurs in a closed vessel system and takes up to 4 h. In hundreds of digestions, the precipitation of fluorides was never observed. Replicate decomposition of 100 mg of twenty‐one international reference materials (RMs) of igneous rocks, and also one of a shale presented mostly satisfactory recoveries of forty‐one trace elements. Important exceptions were Zr and Hf in G‐2 and GSP‐2 (mean recoveries of ca. 70%), although for four other felsic rock RMs, the digestion was complete. For ultramafic rock RMs, we present Cr results that indicate quantitative dissolution of Cr‐bearing phases. We discuss the findings and conclude that advances in sample preparation of geological materials for instrumental analysis would benefit from a better understanding of how specific characteristics, such as composition and crystallinity of certain minerals, may affect their reactivity.  相似文献   
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Biomarkers of exposure and effect of pollutants were analyzed in croakers Micropogonias furnieri (Teleostei: Sciaenidae) captured in winter and summer in a polluted and in a non-polluted site at the Patos Lagoon estuary (Southern Brazil). Catalase and glutathione S-transferase activities (exposure biomarkers) and lipid peroxidation (effect biomarker) were analyzed in liver samples. Other two effect biomarkers were also studied: blood cells DNA damage (through comet assay and micronucleus test) and respiratory burst measurements. In a broad view, results point to an important seasonal variation of the biochemical biomarkers analyzed. However, data obtained clearly indicate that croakers collected in winter at the polluted site were subjected to a level of clastogenic agents sufficient to generate irreversible genetic damages (mutations) and impair the fish immune system.  相似文献   
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