Diagenesis, palaeoclimate and tectono-sedimentary influences on clay mineralogy and stable isotopes from Upper Cretaceous marine successions of the Basque-Cantabrian Basin (N Spain)     

lvaro Jimnez Berrocoso  Maria Cruz Zuluaga  Javier Elorza 《Cretaceous Research》2008,29(3):386-404

Clay mineralogy and whole-rock stable isotopes (δ¹⁸O and δ¹³C) of Upper Cretaceous marly sediments on the Basque-Cantabrian Basin have been integrated to determine the main effects of diagenesis, palaeoclimate and tectono-sedimentary factors in sections belonging to deep- (Barrika) and platform-marine (Isla de Castro, Villamartín and Olazagutía) settings.The mean values for the clay assemblages and δ¹⁸O exhibit notable differences among the sections, partially explainable by the influence of diagenesis. The Barrika sediments, with more diagenetically advanced illite-smectite (I-S) mixed-layer (R1, 70% illite), authigenic chlorite, and low δ¹⁸O (−4.05‰ PDB), experienced higher diagenetic grade than Isla de Castro and Olazagutía, which have R0 I-S (20% illite) and heavier δ¹⁸O. Villamartín was also affected by higher diagenesis than Isla de Castro and Olazagutía, given the occurrence of R1 I-S (60% illite) and low δ¹⁸O (−4.11‰ PDB). However, the absence of other clays in Villamartín (e.g. authigenic chlorite) is indicative of less diagenetic grade than Barrika. These results show the useful integration of clay mineralogy and stable isotopes to detect different diagenetic grades in distinct marine successions of the same basin.Despite being influenced by diagenesis, the clay mineralogy partially preserves its inherited signature. This allows detection of major contents of I-S and mica, and minor kaolinite, interpreted as indicative of warm palaeoclimatic conditions. High kaolinite content in Villamartín and absence of kaolinite in Isla de Castro, though, are considered to be a product of neither diagenesis nor palaeoclimatic influences. Instead, tectono-sedimentary causes, related to unsuitable conditions for clay formation and transport from the local source areas, contributed to original clay differences. The inferred effects of diagenesis, palaeoclimate and tectono-sedimentary factors make this work important to show the potentially great variety of controls on the clay mineralogy of marine sections, which are often uncritically treated in studies concerning the Late Cretaceous.  相似文献   

Weibull statistical analysis of granite bending strength     

P. M. Amaral  J. Cruz Fernandes  L. Guerra Rosa 《Rock Mechanics and Rock Engineering》2008,41(6):917-928

Summary  This paper describes and discusses the adequacy of Weibull statistical analysis to analyse the bending strength of granite. The experimental results show that strength variability is related with a specific origin of failure. This conclusion is based on analysing the influence of the surface condition (extrinsic defects) on the bending strength results treated by the Weibull statistics. The conclusions drawn from this study have been validated by analysing the results of the critical flaw dimension estimated by applying the linear elastic fracture mechanics (LEFM) formulae. Results obtained from fractographic examination also have been used to describe the location of the origin of the fracture and understand the distribution of defects; i.e., there is a unimodal distribution of defects (intrinsic defects), despite the fact that some outlier values are normally observed in the fractured surfaces. Correspndence: P. M. Amaral, Department of Materials Engineering, Instituto Superior Técnico, Technical University of Lisbon, Av. Rovisco Pais, 1049-001 Lisboa, Portugal  相似文献   

Methodology for preliminary assessment of Natech risk in urban areas   总被引：1，自引：0，他引：1  

Ana Maria Cruz  Norio Okada 《Natural Hazards》2008,46(2):199-220

Concern for natural hazard-triggered technological disasters (Natech disasters) in densely populated and industrialized areas is growing. Residents living in urban areas subject to high natural hazard risk are often unaware of the potential for secondary disasters such as hazardous materials releases from neighboring industrial facilities, chemical storage warehouses or other establishments housing hazardous materials. Lessons from previous disasters, such as the Natech disaster during the Kocaeli earthquake in Turkey in 1999 call for the need to manage low frequency/high consequence events, particularly in today’s densely populated areas. However, there is little guidance available on how local governments and communities can assess Natech risk. To add to the problem, local governments often do not have the human or economic resources or expertise to carry out detailed risk assessments. In this article, we propose a methodology for preliminary assessment of Natech risk in urban areas. The proposed methodology is intended for use by local government officials in consultation with the public. The methodology considers possible interactions between the various systems in the urban environment: the physical infrastructure (e.g., industrial plants, lifeline systems, critical facilities), the community (e.g., population exposed), the natural environment (e.g., delicate ecosystems, river basins), and the risk and emergency management systems (e.g., structural and nonstructural measures). Factors related to vulnerability and hazard are analyzed and qualitative measures are recommended. Data from hazardous materials releases during the Kocaeli, Turkey earthquake of August 17, 1999 are used as a case study to demonstrate the applicability of the methodology. Limitations of the proposed methodology are discussed as well as future research needs.

Norio OkadaEmail:

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Analysis of the 2003 Varunawat Landslide,Uttarkashi, India using Earth Observation data     

K. Vinod kumar  R. C. Lakhera  Tapas R. Martha  R. S. Chatterjee  A. Bhattacharya 《Environmental Geology》2008,55(4):789-799

Mass movements such as landslides in mountainous terrains are natural degradation processes and one of the most important landscape-building factors. Varunawat Parbat overlooking Uttarkashi town witnessed a series of landslides on 23 September 2003 and the debris slides and rock falls continued for 2 weeks. This landslide complex was triggered due to the incessant rainfall prior to the event, and its occurrence led to the blockage of the pilgrim route to Gangotri (source of the Ganges river) and evacuation of thousands of people to safer places. Though there was no loss of lives due to timely evacuation, heavy losses to the property were reported. High-resolution stereoscopic earth observation data were acquired after the incidence to study the landslide in detail with emphasis on the cause of the landslide and mode of failure. Areas along the road and below the Varunawat foothill region are mapped for landslide risk. It was found that the foothill region of the Varunawat Parbat was highly disturbed by man-made activities and houses are dangerously located below steep slopes. The potential zones for landslides along with the existing active and old landslides are mapped. These areas are critical and their treatment with priority is required in order to minimise further landslide occurrences.  相似文献   

Measurement of the redox speciation of iron in seawater by catalytic cathodic stripping voltammetry     

Martha Gledhill  Constant M. G. van den Berg 《Marine Chemistry》1995,50(1-4)

Catalytic cathodic stripping voltammetry (CSV) preceded by adsorptive collection of complexes of 1-nitroso-2-napthol (NN) can be used to determine iron in seawater. It is shown here that iron(II) is effectively masked in the presence of 2,2-dipyridyl (Dp) so that iron(III) is measured selectively. The concentration of iron(II) is then calculated as the difference between the concentrations of reactive iron (Fe_R) in the absence and presence of 2 μM Dp, Fe_R being defined as that which was complexed by 20 μM NN at pH 6.9 in the presence of 1.8 mM H₂O₂ and 5 ppm sodium dodecyl sulphate. A 30 min reaction time was allowed for Dp to react with iron(II) in seawater prior to the determination of reactive iron(III) using the same conditions as used for Fe_R. Detection limits of 0.08 nM, 0.077 nM and 0.12 nM were obtained for Fe_R, iron(III) and iron(II), respectively, using a 60 s deposition time.The method was utilised to determine the redox speciation of iron in the northern North Sea. Concentrations of Fe_R ranged between 0.8 and 3.5 nM with nutrient-like depth profiles. Iron(II) was found to be present at concentrations up to 1.2 nM, the highest concentrations occurring in the upper 20 m of the water column.  相似文献   

Gas hydrate disturbance fabrics of southern Hydrate Ridge sediments (ODP Leg 204): Relationship with texture and physical properties   总被引：1，自引：0，他引：1  

Elena Piñero  Eulàlia Gràcia  Francisca Martínez-Ruiz  Juan Cruz Larrasoaña  Alexis Vizcaino  Gemma Ercilla 《Geo-Marine Letters》2007,27(2-4):279-288

Soupy and mousse-like fabrics are disturbance sedimentary features that result from the dissociation of gas hydrate, a process that releases water. During the core retrieval process, soupy and mousse-like fabrics are produced in the gas hydrate-bearing sediments due to changes in pressure and temperature conditions. Therefore, the identification of soupy and mousse-like fabrics can be used as a proxy for the presence of gas hydrate in addition to other evidence, such as pore water freshening or anomalously cool temperature. We present here grain-size results, mineralogical composition and magnetic susceptibility data of soupy and mousse-like samples from the southern Hydrate Ridge (Cascadia accretionary complex) acquired during Leg 204 of the Ocean Drilling Program. In order to study the relationship between sedimentary texture and the presence of gas hydrates, we have compared these results with the main textural and compositional data available from the same area. Most of the disturbed analyzed samples from the summit and the western flank of southern Hydrate Ridge show a mean grain size coarser than the average mean grain size of the hemipelagic samples from the same area. The depositional features of the sediments are not recognised due to disturbance. However, their granulometric statistical parameters and distribution curves, and magnetic susceptibility logs indicate that they correspond to a turbidite facies. These results suggest that gas hydrates in the southern Hydrate Ridge could form preferentially in coarser grain-size layers that could act as conduits feeding gas from below the BSR. Two samples from the uppermost metres near the seafloor at the summit of the southern Hydrate Ridge show a finer mean grain-size value than the average of hemipelagic samples. They were located where the highest amount of gas hydrates was detected, suggesting that in this area the availability of methane gas was high enough to generate gas hydrates, even within low-permeability layers. The mineralogical composition of the soupy and mousse-like sediments does not show any specific characteristic with respect to the other samples from the southern Hydrate Ridge.  相似文献   

Microphytobenthos vertical migratory photoresponse as characterised by light-response curves of surface biomass     

Joo Serdio  Helena Coelho  Snia Vieira  Snia Cruz 《Estuarine, Coastal and Shelf Science》2006,68(3-4):547

The migratory response of intertidal microphytobenthos to changes in irradiance was studied on undisturbed estuarine sediments. Two non-destructive optical techniques were used to trace variations in vivo of surface biomass: PAM fluorometry, for measuring the minimum fluorescence level (F_o); and spectral reflectance analysis, for quantifying the normalized difference vegetation index (NDVI). Following the formation of a dense biofilm at the surface, replicated sediment samples were simultaneously exposed to six different irradiance levels, ranging from 50 to 1500 μmol m⁻² s⁻¹, during a period of 120 min. The migratory photoresponse of the biofilms was characterised by constructing biomass vs. light curves (BLC), relating the accumulation of microalgal biomass after that period (estimated by F_o or NDVI) to the irradiance level incident on the surface. BLCs allow characterising the main features of the migratory photoresponse of intact biofilms. Typical BLC showed a clear biphasic pattern, with an increase in microalgal accumulation under irradiances below 100 μmol m⁻² s⁻¹, maximum values under 100–250 μmol m⁻² s⁻¹, and a gradual decrease of surface biomass under higher irradiances, indicating a strong photophobic downward migratory response. Similar BLC patterns were obtained when measuring F_o or NDVI. The construction of BLCs for biofilms from intertidal sites with distinctive sediment characteristics and diatom taxonomic composition allowed to detected significant differences in the migratory photoresponse. Biofilms from a muddy sediment exhibited considerably larger amplitude in the migratory photoresponse than the biofilms from a sandy mud site, especially under high irradiances. The photophobic migratory response to high light was found to vary among diatom species, particularly in the case of the biofilms from the muddy sediments.  相似文献   

Factors affecting spatial and temporal variability in material exchange between the Southern Everglades wetlands and Florida Bay (USA)     

Martha A. Sutula  Brian C. Perez  Enrique Reyes  Daniel L. Childers  Steve Davis  John W. Day  Jr.  David Rudnick  Fred Sklar 《Estuarine, Coastal and Shelf Science》2003,57(5-6):757-781

Physical and biological processes controlling spatial and temporal variations in material concentration and exchange between the Southern Everglades wetlands and Florida Bay were studied for 2.5 years in three of the five major creek systems draining the watershed. Daily total nitrogen (TN), and total phosphorus (TP) fluxes were measured for 2 years in Taylor River, and ten 10-day intensive studies were conducted in this creek to estimate the seasonal flux of dissolved inorganic nitrogen (N), phosphorus (P), total organic carbon (TOC), and suspended matter. Four 10-day studies were conducted simultaneously in Taylor, McCormick, and Trout Creeks to study the spatial variation in concentration and flux. The annual fluxes of TOC, TN, and TP from the Southern Everglades were estimated from regression equations. The Southern Everglades watershed, a 460-km² area that includes Taylor Slough and the area south of the C-111 canal, exported 7.1 g C m⁻², 0.46 g N m⁻², and 0.007 g P m⁻², annually. Everglades P flux is three to four orders of magnitude lower than published flux estimates from wetlands influenced by terrigenous sedimentary inputs. These low P flux values reflect both the inherently low P content of Everglades surface water and the efficiency of Everglades carbonate sediments and biota in conserving and recycling this limiting nutrient. The seasonal variation of freshwater input to the watershed was responsible for major temporal variations in N, P, and C export to Florida Bay; approximately 99% of the export occurred during the rainy season. Wind-driven forcing was most important during the later stages of the dry season when low freshwater head coincided with southerly winds, resulting in a net import of water and materials into the wetlands. We also observed an east to west decrease in TN:TP ratio from 212:1 to 127:1. Major spatial gradients in N:P ratios and nutrient concentration and flux among the creek were consistent with the westward decrease in surface water runoff from the P-limited Everglades and increased advection of relatively P-rich Gulf of Mexico (GOM) waters into Florida Bay. Comparison of measured nutrient flux from Everglades surface water inputs from this study with published estimates of other sources of nutrients to Florida Bay (i.e. atmospheric deposition, anthropogenic inputs from the Florida Keys, advection from the GOM) show that Everglades runoff represents only 2% of N inputs and 0.5% of P input to Florida Bay.  相似文献   

Numerical modeling of nonlinear water waves over heterogeneous porous beds   总被引：1，自引：0，他引：1  

Eric C. Cruz  Qin Chen   《Ocean Engineering》2007,34(8-9):1303-1321

The transformation of nonlinear water waves over porous beds is studied by applying a numerical model based on Chen's [2006. Fully nonlinear Boussinesq-type equations for waves and currents over porous beds. Journal of Engineering Mechanics, 132:2, 220–230] Boussinesq-type equations for highly nonlinear waves on permeable beds. The numerical model uses a high-order time-marching solution and fourth-order finite-difference schemes for discretization of first-order spatial derivatives to obtain a computational accuracy consistent with the model equations. By forcing the wave celerity and spatial porous-damping rate of the linearized model to match the exact linear theory for horizontal porous bed over a prescribed range of relative depths, the values of the model parameters are optimally determined. Numerical simulations of the damped wave propagation over finite-thickness porous layer demonstrate the accuracy of both the numerical model and governing equations, which have been shown by prior theoretical analyses to be accurate for both nominal and thick porous layers. These simulations also elucidate on the significance of the higher-order porous-damping terms and the influence of the hydraulic parameters. Application of the model to the simulation of the wave field around a laboratory-scale submerged porous mound provides a measure of its capability, as well as useful insight into the scaling of the porous-resistance coefficients. For application to heterogeneous porous beds, the assumption of weak spatial variation of the porous resistance is examined using truncated forms of the governing equations. The results indicate that the complete set of Boussinesq-type equations is applicable to porous beds of nonhomogeneous makeup.  相似文献   

Avian and mammalian bone taphonomy in southern continental Patagonia: A comparative approach   总被引：1，自引：0，他引：1  

Isabel Cruz   《Quaternary International》2008,180(1):30

In southern Patagonia, the occurrence of large seabird nesting colonies condition the features of the regional bone record, which is characterized by a large amount of bird remains, despite their small body size. Bird and mammal bones have remarkably different taphonomic histories in this region: mammal remains are less damaged by carnivores and resist weathering for long periods, whereas bird bones show a greater initial destruction by carnivore activities and faster deterioration by weathering. A comparison of these results with results from research conducted in several African parks (particularly Amboseli) shows that differences in both records are mainly due to differences in community composition and predator–prey dynamics in both ecosystems. Furthermore, while in both ecosystems bird bones weather more rapidly than mammal bones, destruction by this process is more rapid in Patagonia. Overall, the analysis reinforces the need to generate specific models to understand taphonomic histories of archaeofaunal assemblages from Patagonia.  相似文献