The composition and crystallinity of the near-surface regions of weathered alkali feldspars     

Martin R. Lee  Mark E. Hodson  Maureen MacKenzie  Caroline L. Smith 《Geochimica et cosmochimica acta》2008,72(20):4962-4975

Our ability to identify thin non-stoichiometric and amorphous layers beneath mineral surfaces has been tested by undertaking X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM) work on alkali feldspars from pH 1 dissolution experiments. The outcomes of this work were used to help interpret XPS and TEM results from alkali feldspars weathered for <10,000 years in soils overlying the Shap Granite (north-west England). The chemistry of effluent solutions indicates that silica-rich layers a few nanometers in thickness formed during the pH 1 experiments. These layers can be successfully identified by XPS and have lower Al/Si, Na/Si, K/Si and Ca/Si values than the outermost ∼9 nm of unweathered controls. Development of Al-Si non-stoichiometry is coupled with loss of crystal structure to produce amorphous layers that are identifiable by TEM where >∼2.5 nm thick, whereas the crystallinity of albite is retained despite leaching of Na to depths of tens to hundreds on nanometers. Integration of XPS data over the outermost 6-9 nm of naturally weathered Shap feldspars shows that they have stoichiometric Al/Si and K/Si ratios, which is consistent with findings of previous TEM work on the same material that they lack amorphous layers. There is some XPS evidence for loss of K from the outermost couple of nanometers of Shap orthoclase, and the possibility of leaching of Na from albite to greater depths cannot be excluded using the XPS or TEM results. This study demonstrates that the leached layer model, as formulated from laboratory experiments, is inapplicable to the weathering of alkali feldspars within acidic soils, which is an essentially stoichiometric reaction.  相似文献   

Early formed regional antiforms and synforms that fold younger matrix schistosities: their effect on sites of mineral growth     

T. H. Bell  A. P. Ham  K. A. Hickey 《Tectonophysics》2003,367(3-4):253-278

In the metamorphic cores of many orogenic belts, large macroscopic folds in compositional layering also appear to fold one or more pervasive matrix foliations. The latter geometry suggests the folds formed relatively late in the tectonic history, after foliation development. However, microstructural analysis of four examples of such folds suggests this is not the case. The folds formed relatively early in the orogenic history and are the end product of multiple, near orthogonal, overprinting bulk shortening events. Once large macroscopic folds initiate, they may tighten further during successive periods of sub-parallel shortening, folding or reactivation of foliations that develop during intervening periods of near orthogonal shortening. Reactivation of the compositional layering defining the fold limbs causes foliation to be rotated into parallelism with the limbs.Multiple periods of porphyroblast growth accompanied the multiple phases of deformation that postdated the initial development of these folds. Some of these phases of deformation were attended by the development of large numbers of same asymmetry spiral-shaped inclusion trails in porphyroblasts on one limb of the fold and not the other, or larger numbers of opposite asymmetry spirals on the other limb, or similar numbers of the same asymmetry spirals on both limbs. Significantly, the largest disparity in numbers from limb to limb occurred for the first of these cases. For all four regional folds examined, the structural relationships that accompanied these large disparities were identical. In each case the shear sense operating on steeply dipping foliations was opposite to that required to originally develop the fold. Reactivation of the folded compositional layering was not possible for this shear sense. This favoured the development of sites of approximately coaxial shortening early during the deformation history, enhancing microfracture and promoting the growth of porphyroblasts on this limb in comparision to the other. These distributions of inclusion trail geometries from limb to limb cannot be explained by porphyroblast rotation, or folding of pre-existing rotated porphyroblasts within a shear zone, but can be explained by development of the inclusion trails synchronous with successive sub-vertical and sub-horizontal foliations.  相似文献   

Evidence for a regime shift after the 1997–1998 El Niño, based on 1995, 1998, and 2001 acoustic surveys in the Pacific Eastern Boundary Current     

Gordon Swartzman  Barbara Hickey 《Estuaries and Coasts》2003,26(4):1032-1043

Increasing physical oceanographic evidence suggests that a regime shift, which featured increased equatoward surface winds and upwelling in the Eastern Pacific Boundary Current region, occurred following the 1997–1998 El Niño. We expect the signal of this change in biota to be stronger in euphausiids than in pelagic fishes such as Pacific hake (Merluccius productus) because lower trophic levels are more responsive to changes in upwelling and primary production. We used acoustic backscatter data from acoustic surveys in summer 1995, 1998, and 2001 to explore whether significant changes in abundance and distribution of euphausiids and fishes have occurred between 1995 and 2001. Graphical and statistical results show that the density of fish schools and euphausiid patches increased significantly south of Cape Blanco between 1995 and both 1998 and 2001. North of Cape Blanco there was no consistent change in euphausiid abundance, although both fish and euphausiid distributions in 2001 appear to be significantly higher nearshore than in the other years. Pelagic fish abundance distributions appeared more closely linked to El Niño than to regime shifts, with abundance shifted much farther north in 1998, an El Niño year, than in the other years, while 1995 and 2001 fish abundance distributions are similar to each other. The regime shift appears so far to have had a stronger effect on euphausiids than on pelagic fishes. The change in euphausiid abundance and distribution between the survey years was linked, through a conceptual model, to the relative strength of the poleward flowing California undercurrent and equatorward flowing California current and to the distribution and abundance of hake.  相似文献   

Application of an extreme winter storm scenario to identify vulnerabilities,mitigation options,and science needs in the Sierra Nevada mountains,USA     

Christine M. Albano  Michael D. Dettinger  Maureen I. McCarthy  Kevin D. Schaller  Toby L. Welborn  Dale A. Cox 《Natural Hazards》2016,80(2):879-900

  相似文献   

Survey of Nitrate Contamination in Shallow Domestic Drinking Water Wells of the Inner Coastal Plain of Georgia   总被引：1，自引：0，他引：1  

Maureen A. Stuart  Fredrick J. Rich  Gale A. Bishop 《Ground water》1995,33(2):284-290

Beginning in 1990, 2,588 wells were sampled within the Inner Coastal Plain of Georgia in an effort to assess the quality of ground water in this major farm belt. The project was one aspect of an EPA-sponsored program to assess ground-water quality statewide. Several variables were measured, including pH, specific conductivity, dissolved oxygen, temperature, nitrate, nitrite, total hardness, calcium, magnesium, and bicarbonate. In some wells sulfate, chloride, potassium, iron, and manganese contents were also determined. Particular emphasis was placed, however, on pH, specific conductivity, temperature, and nitrite/nitrate content. Generally, pH was between 6 and 8, and temperatures were within a range of 18° and 24°Celsius. Measurements of specific conductivity varied, but averaged 250–275 microsiemens/cm. Nitrite contamination was negligible, and nitrate contamination of the ground water within the shallow aquifers did not appear to be significant. In fact, 56% of the wells sampled showed no detectable signs of nitrate or nitrite contamination. There were, however, a few isolated wells where nitrate as nitrogen measurements exceeded the EPA's Safe Drinking Water Standard of 10 ppm. The general lack of contamination may be the result of the nature of the agricultural practices used in this region and/or the effect of natural denitrification.  相似文献   

Geochemical characteristics of boninite series volcanics: implications for their source   总被引：2，自引：0，他引：2  

Rosemary L. Hickey  Frederick A. Frey 《Geochimica et cosmochimica acta》1982,46(11):2099-2115

  相似文献   

Magnetization of Jurassic red deep-sea sediments in the Atlantic (DSDP site 105)     

Maureen B. Steiner 《Earth and Planetary Science Letters》1977,35(2):205-214

Measurement of the remanent magnetization of samples of Jurassic oceanic red sediments recovered in the western Atlantic on Leg 11, site 105 of the Deep Sea Drilling Project yields quite different results, depending on the demagnetization processes used. Both the Jurassic section and the Berriasian-Valanginian part of the Lower Cretaceous were measured, but with less satisfactory results for the Lower Cretaceous. The natural remanent magnetization of the Jurassic section is almost entirely normal, with 44.6° inclinations (standard deviation = 13.9°) and is not changed by 1000 Oe alternating field (AF) demagnetization. Thermal demagnetization to temperatures of 630°C brings the inclination and polarity sequence in line with that expected for Oxfordian through Tithonian time at this site. The average inclination after thermal demagnetization is 22.1°, standard deviation = 12.1°, and the polarity pattern is one of frequently alternating polarity, much more similar to published reversal patterns for this time than the all normal results of AF demagnetization. The polarity pattern is not identical to the published ones as a result of insufficiently detailed sampling. Thermomagnetic and X-ray analyses were ambiguous, but suggest the presence of titanomagnetite, hematite, and possibly titanomaghemite and pyrrhotite. The primary remanence is carried by hematite.  相似文献   

Freshwater harpacticoid copepods of New Zealand     

Maureen H. Lewis 《新西兰海洋与淡水研究杂志》2013,47(1-2):23-47

  相似文献   

Lake sediment phosphorus release management—Decision support and risk assessment framework     

Christopher W. Hickey  Max M. Gibbs 《新西兰海洋与淡水研究杂志》2013,47(3):819-856

The release of phosphorus (P) from the sediments of eutrophic lakes is often associated with the proliferation of nuisance algal blooms, especially cyanobacteria. The successful implementation of management actions aimed at reducing such algal blooms requires an integrated approach, including both external and internal nutrient loads. The internal load of P can be a significant source of P for primary production, with greatest inputs occurring when lakes stratify and the hypolimnetic waters become anoxic. We reviewed the nature and characteristics of New Zealand lakes in relation to factors which affect the application of technologies to manage internal P loads within individual lakes. New Zealand's windy maritime climate causes lakes to mix more deeply than lakes in continental areas, which are characterised by relatively hot, calm summers. We assessed a range of management options which may be used to control internal P loads, and considered these in a de cision‐support framework aimed at identifying the key factors which may limit successful application. Methods to reduce P release from sediments include: physical approaches—such as artificial destratification, hypolimnetic aeration, enhanced lake flushing, and dredging/discing; and geochemical approaches—such as the application of alum and iron as flocculation agents, and other products as “capping” materials. The capping materials may be either a passive physical barrier (e.g., sand, gravel, clay) or an active barrier. The active barrier systems are generally pervious chemical or geochemical materials capable of binding contaminants by adsorption or precipitation processes. A decision‐support and risk assessment framework is provided to assist managers in the development of appropriate strategies for reducing or controlling internal P loads, and thus cyanobacteria blooms. A review of the sediment characteristics of lakes in the Taupo volcanic zone showed marked variability in sediment P content, and elevated geothermal arsenic concentrations in some lake sediments, which may affect the efficacy of chemical capping agents, indicating that site‐specific consideration of capping agent dose is required.  相似文献   

Glacial forest refugium in Howard Valley,South Island,New Zealand     

Maureen J. Marra  Glenn D. Thackray 《第四纪科学杂志》2010,25(3):309-319

Fossils of forest habitat beetles and leaves of Nothofagus menziesii provide evidence of a forest refugium at times between ca. 34 000 and ca. 18 500 cal. a BP at an upland site in Howard Valley, located adjacent to glaciated valleys in South Island, New Zealand. The stratigraphy of the glacial‐aged terrace sequence of organic‐rich silts and fluvial sand/gravels indicates that soil development occurred episodically for around 15 000 a. Fifty‐four beetle taxa represent seven habitat types: forest, forest or scrub, riparian and aquatic, litter, grass/tussock, marshland and moss habitats. Leaf and beetle fossils indicate that forest dominated by N. menziesii persisted at the site for most of the time period represented, and tree line taxa such as Taenarthrus sp. 1 (Carabidae) and Podocarpus sp. (Podocarpaceae) indicate that the site may represent the upper tree limit for full‐glacial time. The finding of forest at this elevated site adds to the growing fossil evidence for multiple forest refugia in New Zealand during the last glaciation and is consistent with the pollen records, which have consistently indicated the presence of forest species during the last glaciations. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献