Nitric acid vapour measurements in the troposphere and lower stratosphere by chemical ionisation mass spectrometry     

G. Knop  F. Arnold 《Planetary and Space Science》1985,33(8):983-986

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Scanning electron microscopy,cathodoluminescence, and Raman spectroscopy of experimentally shock‐metamorphosed quartzite     

Arnold Gucsik  Christian Koeberl  Franz Brandsttter  Eugen Libowitzky  Wolf Uwe Reimold 《Meteoritics & planetary science》2003,38(8):1187-1197

Abstract— We studied unshocked and experimentally (at 12, 25, and 28 GPa, with 25, 100, 450, and 750°C pre‐shock temperatures) shock‐metamorphosed Hospital Hill quartzite from South Africa using cathodoluminescence (CL) images and spectroscopy and Raman spectroscopy to document systematic pressure or temperature‐related effects that could be used in shock barometry. In general, CL images of all samples show CL‐bright luminescent patchy areas and bands in otherwise nonluminescent quartz, as well as CL‐dark irregular fractures. Fluid inclusions appear dominant in CL images of the 25 GPa sample shocked at 750°C and of the 28 GPa sample shocked at 450°C. Only the optical image of our 28 GPa sample shocked at 25°C exhibits distinct planar deformation features (PDFs). Cathodoluminescence spectra of unshocked and experimentally shocked samples show broad bands in the near‐ultraviolet range and the visible light range at all shock stages, indicating the presence of defect centers on, e.g., SiO₄ groups. No systematic change in the appearance of the CL images was obvious, but the CL spectra do show changes between the shock stages. The Raman spectra are characteristic for quartz in the unshocked and 12 GPa samples. In the 25 and 28 GPa samples, broad bands indicate the presence of glassy SiO₂, while high‐pressure polymorphs are not detected. Apparently, some of the CL and Raman spectral properties can be used in shock barometry.  相似文献   

Quantifying hydrogen‐deuterium exchange of meteoritic dicarboxylic acids during aqueous extraction     

Megan FULLER  Yongsong HUANG 《Meteoritics & planetary science》2003,38(3):357-363

Abstract— Hydrogen isotope ratios of organic compounds in carbonaceous chondrites provide critical information about their origins and evolutionary history. However, because many of these compounds are obtained by aqueous extraction, the degree of hydrogen‐deuterium (H/D) exchange that occurs during the process needs to be quantitatively evaluated. This study uses compound‐specific hydrogen isotopic analysis to quantify the H/D exchange during aqueous extraction. Three common meteoritic dicarboxylic acids (succinic, glutaric, and 2‐methyl glutaric acids) were refluxed under conditions simulating the extraction process. Changes in δD values of the dicarboxylic acids were measured following the reflux experiments. A pseudo‐first order rate law was used to model the H/D exchange rates which were then used to calculate the isotope exchange resulting from aqueous extraction. The degree of H/D exchange varies as a result of differences in molecular structure, the alkalinity of the extraction solution and presence/absence of meteorite powder. However, our model indicates that succinic, glutaric, and 2‐methyl glutaric acids with a δD of 1800%***_o would experience isotope changes of 38_o, 10_o, and 6_o, respectively during the extraction process. Therefore, the overall change in δD values of the dicarboxylic acids during the aqueous extraction process is negligible. We also demonstrate that H/D exchange occurs on the chiral α‐carbon in 2‐methyl glutaric acid. The results suggest that the racemic mixture of 2‐methyl glutaric acid in the Tagish Lake meteorite could result from post‐synthesis aqueous alteration. The approach employed in this study can also be used to quantify H/D exchange for other important meteoritic compounds such as amino acids.  相似文献   

Balloon-borne fragment ion mass spectrometry studies of stratospheric positive ions: Unambiguous detection of H+(CH3CN)1(H2O)m-clusters     

H. Schlager  F. Arnold 《Planetary and Space Science》1985,33(11):1363-1366

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A computer simulation model for predicting rates and scales of movement of demersal fish on the European continental shelf   总被引：1，自引：1，他引：1  

Arnold  G. P.; Holford  B. H. 《ICES Journal of Marine Science》1995,52(6):981-990

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Facies reconstruction from resistivity-at-the-bit images recorded in a submarine felsic volcanic succession     

Juliane Arnold  Anne Bartetzko  Holger Paulick  Gerardo Iturrino 《Marine Geophysical Researches》2007,28(4):331-341

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On the geologic structure of the Explora Escarpment (Weddell Sea,Antarctica) revealed by satellite and Shipboard data evaluation     

Ute Christina Herzfeld  Arnold L. Brodscholl 《Marine Geophysical Researches》1994,16(5):325-345

Bathymetric, gravity, and magnetic data from Antarctic expeditions with RV POLARSTERN and satellite altimeter data from the Geosat Geodetic Mission are analysed using methods from geostatistics and geophysical inverse theory.The Explora Escarpment represents the edge between the Antarctic Continental Shelf and the Weddell Abyssal Plain. It is an important link in the reconstruction of Gondwana breakup, but a feature as large as the 2000 m deep Wegener Canyon was only discovered in 1984, when extensive bathymetric, gravimetric, and magnetic surveys with RV POLARSTERN began.Geostatistics, the theory of regionalized variables, is applied to integrate dense surveys of Wegener Canyon and sparse observations in adjacent areas into maps with full coverage of the 230 km by 330 km area at 10°–20° W/70°–72° S. The resultant highresolution bathymetric and gravity maps reveal detailed structures of the Explora Escarpment. Using geophysical inversion, the gravity terrain effect is calculated. Satellite data are used for their better coverage, but have much lower resolution. Nevertheless, the structures of Wegener Canyon and other more prominent features appear with surprisingly good correlation also in the Geosat altimeter data. While it was initially supposed that Wegener Canyon is purely an erosional structure, the magnetic map now provides evidence of the canyon's tectonic origin.  相似文献   

Influence of relative sea level changes on the construction of the Mississippi Fan     

Arnold H. Bouma  James M. Coleman  Charles E. Stelting  Barry Kohl 《Geo-Marine Letters》1989,9(3):161-170

A conceptual sea-level-driven depositional model for individual fanlobes (channel-overbank systems) of the Mississippi Fan does not permit direct application of the sequence stratigraphic principles of Vail and colleagues. Deep Sea Drilling Project Leg 96 results suggest that, during initial relative lowering of sea level, the canyon and upper fan channel were formed; excavated fine-grained slope sediments may have formed a debris flow deposit base for the fanlobe. Continued lowering produced constructional channel-levee-overbank deposits. Rising relative sea level inhibited input of coarse clastics, and channel depressions filled with muds. A blanket of (hemi)pelagics represents relative high sea level stand.  相似文献   

Naming of undersea features   总被引：2，自引：0，他引：2  

Arnold H. Bouma 《Geo-Marine Letters》1990,10(3):119-125

The Intergovernmental Oceanographic Commission (IOC), the International Hydrographic Organization (IHO), and the joint IOC/IHO Guiding Committee for the General Bathymetric Chart of the Oceans (GEBCO) have expressed considerable concern about the indiscriminate and unregulated naming of undersea features which often go into print without any close scrutiny. An author may not realize that the feature has a name already, maybe in another language, or that his terminology conflicts with established definitions.Geo-Marine Letters wants to follow the IOC/IHO/GEBCO recommendations and requests that its authors follow the set forth guidelines. Examples of terms and definitions are given and addresses of national authorities provided.  相似文献   

Type IV dm bursts: Onset and sudden reductions     

Arnold O. Benz  Jan Kuijpers 《Solar physics》1976,46(2):275-290

The effect of collisions of suprathermal electrons with a thermal background plasma is investigated and is shown to cause flattening of a monotonically descending velocity distribution of fast particles. As a result flare-produced energetic electrons that are trapped in a coronal magnetic arch and that are initially distributed in energy according to a power-law, can give rise to an instability of Langmuir waves in the background plasma and the subsequent emission of continuum radiation as observed in type IV dm bursts.To explain the appearance of sudden reductions observed in type IV dm outbursts the effects both of magnetic compressions of the source region and of renewed injections of fast particles on the continuum source are investigated. It is found that the latter process can explain the observed reductions.  相似文献