Comparison of atmospheric aerosol backscattering and air mass back trajectories     

J. M. Vaughan  R. H. Maryon  N. J. Geddes 《Meteorology and Atmospheric Physics》2002,79(1-2):33-46

Summary Atmospheric backscattering from aerosol particulates has been measured over the Atlantic at 10.6 μm wavelength with an airborne, coherent heterodyne, lidar, and corresponding air mass back trajectories have been calculated. These back trajectories (usually extended up to 10 days prior to the backscatter measurement) have shown very diverse origins for the air parcels at different altitudes. In many cases it has been possible to attribute the observed levels of scattering to these origins over oceanic, arctic, continental, industrial etc. regions. This is illustrated by 6 flight records: out of Ascension Island in the South Atlantic; over the Azores in the mid North Atlantic; over the UK and the North Sea; and in the Arctic along 71° North. In each of these regions the profiles of backscatter versus altitude show highly variable features; remarkably different origins for air masses at different altitudes are evident from the corresponding back trajectory analyses. It is thus possible for the first time to present probable explanations for the different levels of scattering observed at different altitudes. Received July 14, 2000 Revised May 14, 2001  相似文献   

Depositional and post‐depositional history of warm stage deposits at Knocknacran,Co. Monaghan,Ireland: implications for preservation of Irish last interglacial deposits     

A. P. M. Vaughan  L. A. Dowling  F. J. G. Mitchell  S.‐E. Lauritzen  A. M. McCabe  P. Coxon 《第四纪科学杂志》2004,19(6):577-590

Organic‐rich deposits, uncovered during overburden removal from mantled gypsum karst at Knocknacran opencast gypsum mine, Co. Monaghan, are the best candidate to date for a last interglacial record in Ireland. The two till and organic‐rich deposits (preserved at different quarry elevations) were emplaced on to a Tertiary dolerite surface during high‐energy flood events and subsequently folded and faulted by movement towards sinkholes in underlying gypsum. Uranium–thorium disequilibrium dating suggests that the organic‐rich deposits in the upper section were hydrologically isolated at ca. 41 ka and those in the lower section at ca. 86 ka. Interpretation of the pollen content, although tentative because of the depositional and post‐depositional history of the material, suggests that the organic material originated in a warm stage possibly warmer than the post‐Eemian interstadials. The unusual setting of preservation may indicate that in situ, last interglacial deposits have generally been removed by erosion in Ireland. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

XMM–Newton spectral properties of the narrow-line Seyfert 1 galaxy IRAS 13224 – 3809     

Th. Boller  Y. Tanaka  A. Fabian  W. N. Brandt  L. Gallo  N. Anabuki  Y. Haba  S. Vaughan 《Monthly notices of the Royal Astronomical Society》2003,343(4):L89-L93

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Neoliberalism and natural resource management: Agri-environmental standards and the governing of farming practices   总被引：1，自引：0，他引：1  

Vaughan Higgins  Jacqui Dibden  Chris Cocklin 《Geoforum》2008,39(5):1776-1785

Private standards and certification schemes are widely acknowledged as playing an increasingly important role in agri-environmental governance. While much of the existing research concludes that these mechanisms consolidate the global extension of neoliberalism – enhancing the power of corporate actors to the detriment of smaller producers – we argue that this overlooks the complex ways in which standards are used by governments and farmers in the governing of farming practices. Focusing specifically on a process standard – Environmental Management Systems (EMS) – promoted by the Australian government as a way of verifying the ‘clean and green’ status of agricultural exports, we examine how one regional group of producers has sought to use EMS standards in practice. Our analysis of a case study in the state of Victoria appears to confirm that EMS was a successful instrument for the extension of neoliberal governance, reinforcing the production of neoliberal subjectivities and practices amongst farmer participants and enabling the government to compensate for gaps in environmental provision. However, it would be a mistake to interpret the development of this EMS scheme as an example of naïve farmers manipulated by the state. In practice, farmers used the opportunities provided by government funding to undertake actions which expressed their own agri-environmental values and practices. Establishment of an EMS and associated eco-label enabled producers to demonstrate and extend their capacity to act as good environmental stewards. Our research highlights how the local application of environmental standards negotiates and shapes, rather than simply contributes to, neoliberal rule.  相似文献   

Recent Rapid Regional Climate Warming on the Antarctic Peninsula   总被引：15，自引：1，他引：15  

David G. Vaughan  Gareth J. Marshall  William M. Connolley  Claire Parkinson  Robert Mulvaney  Dominic A. Hodgson  John C. King  Carol J. Pudsey  John Turner 《Climatic change》2003,60(3):243-274

The Intergovernmental Panel on Climate Change (IPCC) confirmed that mean global warming was 0.6 ± 0.2 °C during the 20th century and cited anthropogenic increases in greenhouse gases as the likely cause of temperature rise in the last 50 years. But this mean value conceals the substantial complexity of observed climate change, which is seasonally- and diurnally-biased, decadally-variable and geographically patchy. In particular, over the last 50 years three high-latitude areas have undergone recent rapid regional (RRR) warming, which was substantially more rapid than the global mean. However, each RRR warming occupies a different climatic regime and may have an entirely different underlying cause. We discuss the significance of RRR warming in one area, the Antarctic Peninsula. Here warming was much more rapid than in the rest of Antarctica where it was not significantly different to the global mean. We highlight climate proxies that appear to show that RRR warming on the Antarctic Peninsula is unprecedented over the last two millennia, and so unlikely to be a natural mode of variability. So while the station records do not indicate a ubiquitous polar amplification of global warming, the RRR warming on the Antarctic Peninsula might be a regional amplification of such warming. This, however, remains unproven since we cannot yet be sure what mechanism leads to such an amplification. We discuss several possible candidate mechanisms: changing oceanographic or changing atmospheric circulation, or a regional air-sea-ice feedback amplifying greenhouse warming. We can show that atmospheric warming and reduction in sea-ice duration coincide in a small area on the west of the Antarctic Peninsula, but here we cannot yet distinguish cause and effect. Thus for the present we cannot determine which process is the probable cause of RRR warming on the Antarctic Peninsula and until the mechanism initiating and sustaining the RRR warming is understood, and is convincingly reproduced in climate models, we lack a sound basis for predicting climate change in this region over the coming century.  相似文献   

Oxidation state and electronic configuration determination of copper in tetrahedrite group minerals by L-edge X-ray absorption spectroscopy     

R. A. D. Pattrick  G. van der Laan  D. J. Vaughan  C. M. B. Henderson 《Physics and Chemistry of Minerals》1993,20(6):395-401

L-edge X-ray absorption spectroscopy employing a synchrotron radiation source has been used to study the electronic structure and valency of Cu in the chemically and structurally complex tetrahedrite group of minerals. Mechanical mixtures of Cu²⁺O and Cu⁺FeS₂ were used to estimate the relative cross sections of Cu²⁺ and Cu⁺; the absorption of Cu²⁺ at 931 eV is 25 times greater than that of Cu⁺ at 945 eV. Using this calibration, Cu²⁺/Cu ratios were found to vary from 0.00 to 0.054 in the tetrahedrite samples studied; the highest proportion of Cu²⁺ occurs in synthetic tetrahedrites with a composition close to Cu₁₂Sb₄S₁₃. This study reveals the utility of the technique for determining the valence state of copper in complex minerals, allowing the crystal chemistry to be more fully characterised.  相似文献   

A simulation model of how life history strategies mediate pollution effects on fish populations     

W. E. Schaaf  D. S. Peters  L. Coston-Clements  D. S. Vaughan  C. W. Krouse 《Estuaries and Coasts》1993,16(4):697-702

Pollution effects on fish populations were estimated with a simulation model, using Leslie matrices. Results from changing only first-year survival rate (S_o) have already been published (Schaaf et al. 1987). This paper explores the effects of perturbing both S_o and the adult survival rate (S_i) for 12 spatial-temporal stocks. Most stocks examined are more sensitive to permanent change in S_i than to changes in S_o. The relative importance of these two rates in determining the population growth rate (λ) depends upon the age distribution of the expected lifetime egg production of age i females (V_i). In turn, the vector V_i, as measured by its mean and standard deviation, is shown to vary among geographic or temporal stocks of a single species. Hence, we quantify the impact on population size of destroying a fixed percentage of habitat, relative to where and when it occurs (i.e., relative impact on S_i and S_o). For example, destroying 1% of the Atlantic menhaden habitat would reduce λ by 0.8% and the population by 8.0% in 10 yr, if the impact affected only adults (e.g., offshore in winter). If the 1% habitat destruction all occurred in the estuaries, affecting juveniles as well, λ would be reduced by almost 5%, and in 10 yr drive the population down to 58% of its former equilibrium. We show that knowledge of the mean and variance of the age distribution of V_i permits prediction of relative sensitivity among species to pollution. Within species, this knowledge of V_i permits comparison of the effects of impacting different life stages and at different times and places.  相似文献   

Electronic structures of sulfide minerals — Theory and experiment     

David J. Vaughan  John A. Tossell 《Physics and Chemistry of Minerals》1983,9(6):253-262

The sulfide minerals exhibit a rich diversity in sturctural chemistry and in electrical, magnetic and other physical properties. Models based on molecular orbital theory and incorporating some elements of band theory can be developed to describe the diverse valence electron behavior in these minerals. Qualitative models can be proposed on the basis of observed properties, and the models can be tested and refined using experimental data from X-ray emission and X-ray photoelectron spectroscopy and quantum mechanical calculations performed on cluster units which form the basic building blocks of the crystals. This approach to chemical bonding in sulfide minerals is illustrated for binary non-transition metal sulfides (ZnS, CdS, HgS, PbS), binary transition metal sulfides (FeS₂, CoS₂, NiS₂, CuS₂ ZnS₂) and more complex sulfides (CuFeS₂, Cu₂S, Ag₂S, CuS, Co₃S₄, CuCo₂S₄, Fe₃S₄). The relationship between qualitative and quantitative theories is reviewed with reference to the pyrite-marcasite-arsenopyrite-loellingite series of minerals. Application of the models to understanding structure-determining principles, relative stabilities, solid solution limits and properties such as color, reflectance and hardness are discussed.  相似文献   

Accuracy of ozonesonde measurements in the troposphere     

S. J. Reid  G. Vaughan  A. R. W. Marsh  H. G. J. Smit 《Journal of Atmospheric Chemistry》1996,25(2):215-226

Measurements of atmospheric ozone at concentrations typical of the free troposphere have been compared for ECC sondes and a UV-absorption photometer, using a Bendix chemiluminescent analyser as a transfer standard. Comparisons were conducted in the laboratory and in the tropospheric part of the atmosphere. It was found that the measurements agreed to within 4% provided that the background current for the ECC sonde was measured before exposure to ozone in the preparation procedure, and was assumed to be constant throughout the sonde flight. These results confirm those of earlier experiments and mean that the methods currently used to correct for the background current in the troposphere need to be revised.  相似文献   

L'élimination des déchets solides aux Etats-Unis d'Amérique     

R. D. Vaughan 《Aquatic Sciences - Research Across Boundaries》1969,31(2):294-308

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