Sedimentological and geochemical responses of Lake Żabińskie (north-eastern Poland) to erosion changes during the last millennium     

Alicja Bonk  Małgorzata Kinder  Dirk Enters  Martin Grosjean  Carsten Meyer-Jacob  Wojciech Tylmann 《Journal of Paleolimnology》2016,56(2-3):239-252

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Tracking deepwater oxygen recovery using sedimentary chironomid assemblages: Peninsula Lake revisited     

Jeziorski  Adam  Nelligan  Clare  Corrigan  Dara  Meyer-Jacob  Carsten  Paterson  Andrew M.  Smol  John P. 《Journal of Paleolimnology》2021,66(4):371-387

Journal of Paleolimnology - Peninsula Lake, Ontario, Canada, is a Precambrian Shield lake that has experienced many environmental stressors since European settlement of the watershed in the...  相似文献   

Independent measurement of biogenic silica in sediments by FTIR spectroscopy and PLS regression     

Carsten Meyer-Jacob  Hendrik Vogel  Florian Boxberg  Peter Rosén  Michael E. Weber  Richard Bindler 《Journal of Paleolimnology》2014,52(3):245-255

We present an independent calibration model for the determination of biogenic silica (BSi) in sediments, developed from analysis of synthetic sediment mixtures and application of Fourier transform infrared spectroscopy (FTIRS) and partial least squares regression (PLSR) modeling. In contrast to current FTIRS applications for quantifying BSi, this new calibration is independent from conventional wet-chemical techniques and their associated measurement uncertainties. This approach also removes the need for developing internal calibrations between the two methods for individual sediments records. For the independent calibration, we produced six series of different synthetic sediment mixtures using two purified diatom extracts, with one extract mixed with quartz sand, calcite, 60/40 quartz/calcite and two different natural sediments, and a second extract mixed with one of the natural sediments. A total of 306 samples—51 samples per series—yielded BSi contents ranging from 0 to 100 %. The resulting PLSR calibration model between the FTIR spectral information and the defined BSi concentration of the synthetic sediment mixtures exhibits a strong cross-validated correlation ( \( {\text{R}}^{ 2}_{\text{cv}} \)  = 0.97) and a low root-mean square error of cross-validation (RMSECV = 4.7 %). Application of the independent calibration to natural lacustrine and marine sediments yields robust BSi reconstructions. At present, the synthetic mixtures do not include the variation in organic matter that occurs in natural samples, which may explain the somewhat lower prediction accuracy of the calibration model for organic-rich samples.  相似文献