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Increasing emphasis is being given to the search for blind mineral deposits and the presence of geochemical dispersion halos in wallrocks may significantly enhance the chances of exploration success. Accordingly, the nature of wallrock dispersion associated with the Lake Dufault Cu-Zn-Au-Ag massive sulphide deposit, Noranda, Quebec, was examined to see if any such patterns existed. On the basis of relatively well defined geology, the area offered an opportunity to establish the relation between geochemical alteration and metallogeny, texture, structure and mineralogy.Anomalous element contents spatially related to mineralization are confined to the stratigraphic footwall (Waite Rhyolite) where Na2O, SiO2 and possibly CaO depletions and total Fe1 Mn and MgO enrichments can be related to the hydrothermal vent. Dispersion halos 150–500 m in diameter are at least twice as wide as the obvious mineralogical alteration halo. Cu, Zn, Ag and S distributions show roughly similar patterns which are not obviously related to the main alteration pipe but do reveal broad enrichment zones in the general area of mineralization.The dispersion appears to be partly controlled by texture. Because of greater primary permeability, the halos produced in rhyolite breccia are wider and better defined than those in more massive rhyolites. On a wider scale (10 km2) dispersion patterns are related to the fault and fracture systems of the area.As many as five stages of metamorphism have affected the area, altering all rocks to some extent. Samples can be classified petrographically into alteration groups, both related and unrelated to mineralization. Comparison of these groups reveals the inadequacy of certain elements for outlining alteration related to mineralization. For example, the range of K2O in relatively unaltered rhyolite overlaps the composition of all other groups, including those related to mineralization. Similarly apparent is that the distribution of certain elements, e.g., Na2O, may adequately define one part of an alteration zone such as the sericite-rich zone, but not another.It is concluded that careful use of lithogeochemistry in conjunction with detailed geological mapping and core logging can provide information otherwise obtainable only by time-consuming petrographic analysis. Thus it can be a potent weapon in the search for blind ore deposits. 相似文献
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Surveys of natural populations of mussels have identified areas of mercury contamination in the Firth of Forth, Scotland. A field bio-assay technique has been devised which accurately reflects the mean total mercury concentration in the surrounding seawater. The detection limit of the technique is estimated at 5–20 ng Hg l.?1, and consequently the method can detect comparatively small enhancements over background mercury concentrations in estuarine and sea water. 相似文献
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A bioassay experiment using caged mussels has suggested a total concentration of methylmercury in the seawater of a polluted estuary of 0.06 ng dm?3. The technique may provide a useful tool for the assessment of relative concentrations of methylmercury in seawater at different locations. 相似文献
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The cellular distribution and chemical forms of Ag were determined in mussels after accumulation of the metal from sea water. The major accumulations were either in the vacuoles of connective tissue macrophages, where it was associated with S, or in deposits in the fibrillar layer of the basement membranes of the digestive diverticulum and kidney epithelia, where it was bound to the sulphydryl and sulphate groups of glycoproteins and proteoglycans. In acutely exposed animals, about 10 % of the accumulated Ag was found in a (Ag, Cu)-binding protein with characteristics indicating that it may be a metallothionein. There was a concomitant increase in the body Cu levels after Ag exposure and 40 % of this was bound to this low molecular weight metal-binding protein. 相似文献
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Analysis of thermally generated night-time volcanic radiances recorded with a 1-km pixel size at 1.6 and 11 µm during 1991-1993 and 1996-1999 for Mount Etna shows that lava flows extending beyond the summit craters can be distinguished from vent activity. The two phenomena plot in different regions of feature space when the mean volcanic radiance (per anomalous pixel) at 11 µm is plotted against the mean volcanic radiance at 1.6 µm. The distinct feature space characteristics of lava flow fields are apparent within 1-2 days of the onset of each effusive event. Such a plot also enables lava flow fields being fed by open channels to be distinguished from tube-fed flow fields. Rank order analysis of the total 1.6-µm volcanic radiance series shows that vent activity and lava flows belong to different populations, and offers further scope for remotely identifying changes in eruptive state. 相似文献