Calcite precipitation instability under laminar, open-channel flow     

Ø. Hammer  D.K. Dysthe  H. Lund  P. Meakin  B. Jamtveit 《Geochimica et cosmochimica acta》2008,72(20):5009-5021

We present a 2D numerical model for the growth of calcite from supersaturated aqueous solutions under laminar, open-channel flow conditions. The model couples solution chemistry, precipitation at solution/calcite interfaces, hydrodynamics, diffusion and degassing. The model output is compared with experimental results obtained using an oversaturated calcite solution produced by mixing CaCl₂ and Na₂CO₃. The precipitation rate is observed to increase when the supersaturated solution flows over an obstruction, leading to a growth instability that causes the formation of terraces. At relatively high flow rates, the most important mechanism for this behaviour seems to be hydrodynamic advection of dissolved species either towards or away from the calcite surface, depending on location relative to the obstruction, which deforms the concentration gradients. At lower flow rates, steepening of diffusion gradients around protrusions becomes important. Enhanced degassing over the obstruction due to shallowing and pressure drop is not important on small scales. Diffusion controlled transport close to the calcite surface can lead to a fingering-type growth instability, which generates porous textures. Our results are consistent with existing diffusive boundary layer theory, but for flow over non-smooth surfaces, simple calcite precipitation models that include empirical correlations between fluid flow rate and calcite precipitation rate are inaccurate.  相似文献   

Surface complexation modeling of Cu(II) adsorption on mixtures of hydrous ferric oxide and kaolinite     

Tracy J Lund  Carla M Koretsky  Christopher J Landry  Melinda S Schaller  Soumya Das 《Geochemical transactions》2008,9(1):9

Background  

The application of surface complexation models (SCMs) to natural sediments and soils is hindered by a lack of consistent models and data for large suites of metals and minerals of interest. Furthermore, the surface complexation approach has mostly been developed and tested for single solid systems. Few studies have extended the SCM approach to systems containing multiple solids.  相似文献   

Local co-operation, ethnic diversity and state territoriality – The case of Haparanda and Tornio on the Sweden – Finland border     

Thomas Lundén  Dennis Zalamans 《GeoJournal》2001,54(1):33-42

The neighbouring towns of Haparanda and Tornio, separated only by a narrow strip of grass and wetland, are divided by the only inhabited land boundary between Finland and Sweden in the southern part of the Torne River. The population represents four different groups in relation to linguistic and cultural backgrounds. In the daily lives of the inhabitants, the state boundary is probably of less significance than linguistic, social and ‘ethnic’ differences. On the local government level there is a strong will to unite forces to make the total area a viable region in spite of its peripheral location, but state legislation makes co-ordination difficult. This may be seen as a necessity, but in the daily lives of the populations, the state boundary defines an area of unequal access, sometimes working in favour of and sometimes barring contacts and co-operation. The media consumption reflects a clear ‘national’ interest with a strong local bias. In their attitudes, Finnish speakers and bilinguals show a greater appreciation of ‘the other’ than unilingual Swedes. This may reflect the actual possibility space (reach) in the local area. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

An Intercomparison of Large-Eddy Simulations of the Stable Boundary Layer   总被引：2，自引：27，他引：2  

Robert J. Beare  Malcolm K. Macvean  Albert A. M. Holtslag  Joan Cuxart  Igor Esau  Jean-Christophe Golaz  Maria A. Jimenez  Marat Khairoutdinov  Branko Kosovic  David Lewellen  Thomas S. Lund  Julie K. Lundquist  Anne Mccabe  Arnold F. Moene  Yign Noh  Siegfried Raasch  Peter Sullivan 《Boundary-Layer Meteorology》2006,118(2):247-272

Results are presented from the first intercomparison of large-eddy simulation (LES) models for the stable boundary layer (SBL), as part of the Global Energy and Water Cycle Experiment Atmospheric Boundary Layer Study initiative. A moderately stable case is used, based on Arctic observations. All models produce successful simulations, in as much as they generate resolved turbulence and reflect many of the results from local scaling theory and observations. Simulations performed at 1-m and 2-m resolution show only small changes in the mean profiles compared to coarser resolutions. Also, sensitivity to subgrid models for individual models highlights their importance in SBL simulation at moderate resolution (6.25 m). Stability functions are derived from the LES using typical mixing lengths used in numerical weather prediction (NWP) and climate models. The functions have smaller values than those used in NWP. There is also support for the use of K-profile similarity in parametrizations. Thus, the results provide improved understanding and motivate future developments of the parametrization of the SBL.  相似文献   

Climate Warming and Water Management Adaptation for California   总被引：1，自引：3，他引：1  

Stacy K. Tanaka  Tingju Zhu  Jay R. Lund  Richard E. Howitt  Marion W. Jenkins  Manuel A. Pulido  Mélanie Tauber  Randall S. Ritzema  Inês C. Ferreira 《Climatic change》2006,76(3-4):361-387

The ability of California's water supply system to adapt to long-term climatic and demographic changes is examined. Two climate warming and a historical climate scenario are examined with population and land use estimates for the year 2100 using a statewide economic-engineering optimization model of water supply management. Methodologically, the results of this analysis indicate that for long-term climate change studies of complex systems, there is considerable value in including other major changes expected during a long-term time-frame (such as population changes), allowing the system to adapt to changes in conditions (a common feature of human societies), and representing the system in sufficient hydrologic and operational detail and breadth to allow significant adaptation. While the policy results of this study are preliminary, they point to a considerable engineering and economic ability of complex, diverse, and inter-tied systems to adapt to significant changes in climate and population. More specifically, California's water supply system appears physically capable of adapting to significant changes in climate and population, albeit at a significant cost. Such adaptation would entail large changes in the operation of California's large groundwater storage capacity, significant transfers of water among water users, and some adoption of new technologies.  相似文献   

Tropical cyclone activity and western North Atlantic stratification over the last millennium: a comparative review with viable connections     

Jonathan D. Woodruff  Ryan L. Sriver  David C. Lund 《第四纪科学杂志》2012,27(4):337-343

Tropical cyclones (TC) are recognized to modify the thermal structure of the upper ocean through the process of vertical mixing. Assessing the role this mixing plays in the overall stratification of the upper ocean is difficult, due to the relatively short and incomplete instrumental record. Proxy records for both TC landfalls and oceanographic stratification are preserved within the geological record and provide insight for how past changes in TC‐induced mixing have potentially affected water column structure prior to the instrumental record. Here we provide the first comparison between previously published paleo‐reconstructions of vertical ocean density and tropical cyclone activity from the western North Atlantic. A prominent lull in TC activity has been observed prior to approximately 1700 CE that extends back several centuries. This interval of low TC activity is shown to be concurrent with the timing of increased ocean stratification near Great Bahama Bank, potentially due in part to reduced TC‐induced mixing. To test whether this relationship is feasible, we present numerical results from a coarse‐resolution ocean general circulation model experiment isolating the effect of TC surface wind forcing on the upper ocean. An anomaly of roughly 0.12 kg m^?3 in vertical stratification occurs above and below the mixed layer for model runs with and without TC mixing. This anomaly is roughly 25% of the entire paleo‐density signal observed just prior to 1700 CE. These results suggest that TC mixing alone cannot completely explain the density anomaly observed prior to 1700 CE, but support TC variability as an important contributor to enhancing oceanic stratification during this interval. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

The use of land recorded long-range marine airgun data in crustal reflection-refraction investigations     

C-E. Lund  R.G. Roberts  C. Juhlin  R. Bödvarson  H. Palm 《Geophysical Journal International》1987,89(1):365-370

Summary. During the EUGENO-S field campaign in 1984 a large number of airgun shots were fired at sea in the Skagerrak and Kattegat and in Lake Vänern in southwestern Sweden. The signals were recorded on land by analogue "MARS" and digital "SN-PCM-80" three channel stations, by a digital 48 channel "SERCEL SN348" reflection instrument, and by "Geostore" stations. The airguns were shot about every 300 m along profiles up to 100 km in length. Clear reflected and refracted arrivals were observed from 5 km to 250 km shot-receiver offset. The field and data processing techniques used are briefly described, and two examples of data are discussed.  相似文献   

Crustal reflections underneath Lake Vänern, Sweden     

C. Juhlin  D. Dyrelius  C.-E. Lund  H. Palm 《Geophysical Journal International》1989,99(3):567-578

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The determination of weakly and strongly bound copper,lead and cadmium in oslofjord samples     

Steinar K. Nilsen  Walter Lund 《Marine Chemistry》1982,11(3):223-233

Weakly and strongly bound copper, lead and cadmium have been determined in the dissolved and particulate fractions of water samples from Oslofjord. The differentiation was made possible by using different sequences of filtration, acidification and digestion. The quantitative measurements were done by differential pulse anodic stripping voltammetry. Lead was found to be associated mostly with particulate matter, while cadmium was present only in the dissolved fraction. A strong digestion was needed for the determination of total metal. The advantage of pretreating sample bottles and filters with a conditioning solution is illustrated.  相似文献   

Late Holocene lake level dynamics inferred from magnetic susceptibility and stable oxygen isotope data: Lake Elsinore, southern California (USA)     

Matthew E. Kirby  Christopher J. Poulsen  Steve P. Lund  William P. Patterson  Liam Reidy  Douglas E. Hammond 《Journal of Paleolimnology》2004,31(3):275-293

Southern California faces an imminent freshwater shortage. To better assess the future impact of this water crisis, it is essential that we develop continental archives of past hydrological variability. Using four sediment cores from Lake Elsinore in Southern California, we reconstruct late Holocene (3800 calendar years B.P.) hydrological change using a twentieth-century calibrated, proxy methodology. We compared magnetic susceptibility from Lake Elsinore deep basin sediments, lake level from Lake Elsinore, and regional winter precipitation data over the twentieth century to calibrate the late Holocene lake sediment record. The comparison revealed a strong positive, first-order relationship between the three variables. As a working hypothesis, we suggest that periods of greater precipitation produce higher lake levels. Greater precipitation also increases the supply of detritus (i.e., magnetic-rich minerals) from the lake's surrounding drainage basin into the lake environment. As a result, magnetic susceptibility values increase during periods of high lake level. We apply this modern calibration to late Holocene sediments from the lake's littoral zone. As an independent verification of this hypothesis, we analyzed ¹⁸O_(calcite), interpreted as a proxy for variations in the precipitation:evaporation ratio, which reflect first order hydrological variability. The results of this verification support our hypothesis that magnetic susceptibility records regional hydrological change as related to precipitation and lake level. Using both proxy data, we analyzed the past 3800 calendar years of hydrological variability. Our analyses indicate a long period of dry, less variable climate between 3800 and 2000 calendar years B.P. followed by a wet, more variable climate to the present. These results suggest that droughts of greater magnitude and duration than those observed in the modern record have occurred in the recent geological past. This conclusion presents insight to the potential impact of future droughts on the over-populated, water-poor region of Southern California.  相似文献