Microtextures and crystal chemistry in P21/c pigeonites     

M. Tribaudino  D. Pasqual  G. Molin  L. Secco 《Mineralogy and Petrology》2003,77(3-4):161-176

Summary ?A single-crystal X-ray investigation was performed on crystals of P2₁/c natural pigeonite with varying Ca and Fe^* ( = Fe²⁺ + Mn²⁺) contents, in order to verify the effect of microtextural disorder on structure refinements and to constrain the crystal chemistry of pigeonite. Antiphase domains and exsolution lamellae affect differently the refinement results. In a crystal free of exsolution the structure obtained after refinement with all reflections is an average of that of the antiphase domains and of their boundaries, whereas in an exsolved crystal it represents only the structure of the prevailing pigeonite lamellae. The refinement using only h + k odd reflections seems to give the structure of the Ca-free pigeonite characteristic of the antiphase domains rather than that of Ca-rich domain walls. The ratio of the scale factors in refinements with all reflections and with only h + k odd reflections allows the ratios of the exsolved augite and pigeonite phases to be estimated. The crystal chemistry of the investigated samples follows the trends outlined by data on Ca-free and Fe-free synthetic samples. In particular, it is shown that Ca and Fe^* substitution for Mg induce similar changes in the average structure, i.e. both induce an expansion in the M1 polyhedron and decrease the difference between the M2–O3 distances. Received October 18, 2001; revised version accepted February 15, 2002  相似文献   

Effect of wave-directionality on second-order loads induced by the set-down     

B. Molin  V. Fauveau 《Applied Ocean Research》1984,6(2):66-72

At first-order of approximation a sea-state may be considered as an infinite sum of Airy components with angular frequencies ω_i and wave-number vectors k_i. A second-order analysis shows the co-existence of long waves appearing at the difference frequencies ω_i—ω_j with wave-number vectors k_i—k_j. In shallow water they become appreciable in amplitudes and may induce slow-drift motion of moored structures.For small values of ω_i—ω_j,k_i—k_j may take all kinds of directions for an angular-spread wave system. Then it may be questioned how the in-line and transverse second-order accelerations compare to those obtained for a mono-directional wave-system.This analysis is carried out here by relating the spectra of the second-order horizontal accelerations to the directional wave-spectrum. Numerical applications are first performed for deep water. They show that at low frequencies, even for very narrowly spread wave systems, the transverse component is larger than the in-line component. In shallow water both components are dratically reduced as compared to the mono-directional case. As a consequence one may question the validity of model-testings or numerical models which take no account of the directionality of the wave-system.  相似文献   

Crystal-chemistry of clinopyroxene from Sunda volcanic arc     

G. Salviulo  G. M. Molin 《Mineralogy and Petrology》1993,49(3-4):233-248

Summary The crystal-chemistry of clinopyroxene from a suite of Sunda arc volcanic rocks was investigated by X-ray structure refinement and microprobe analysis. Relationships with clinopyroxene from volcanic rocks of the intraplate environment were highlighted.Sunda clinopyroxenes were distinguished into two groups. The first consists of clinopyroxene from SiO₂-saturated rock types and crystal rim from SiO₂-undersaturated rock types, the second of crystal core from SiO₂-undersaturated rock types. The crystal chemical behaviour of the two groups differs significantly, mainly in the geometrical relationships between M2 and T sites. While in the first group M2-O3 and T-O3 bond lengths shorten and lengthen respectively due to Ca and Al^IV increase, in the second group in which M2 site is almost fully coordinated by Ca, -O3 bond lengths are forced to lengthen in spite of low Al^IV content, in order to mantain the local charge balance around the O3 oxygens.It is noteworthy that Sunda clinopyroxene shows strong analogies with that from basaltic rocks from the Ethiopian plateau and K-rich lavas from the Roman Province respectively, reflecting similarities between the composition and mineralogical assemblages of the host rocks, although they all came from different tectonic environments. A relationship between intracrystalline Mg-Fe 2+ disorder and the explosive character of the volcanism is demonstrated.

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Kristallchemie von Klinopyroxenen aus Gesteinen des Vulkanbogens der Sunda-Inseln

Zusammenfassung Die Kristallchemie von Klinopyroxenen aus einer Serie von vulkanischen Gesteinen des Sunda-Bogens wurde mit Röntgen-Strukturverfeinerungen und Mikrosonden-analysen untersucht. Beziehungen zu Klinopyroxenen vulkanischer Gesteine aus intra-Plattenpositionen werden beleuchtet. Die Sunda-Klinopyroxene wurden in zwei Gruppen eingeteilt. Die erste umfaßt Klinopyroxene SiO₂-gesättigter Gesteinstypen und Kristallsäume SiO₂-untersättigter Gesteinstypen, die zweite Kristallkerne SiO₂-untersättigter Gesteinstypen. Das kristallchemische Verhalten der beiden Gruppen unterscheidet sich beträchtlich, hauptsächlich in den geometrischen Beziehungen zwischen den M2 und T Positionen. Während in der ersten Gruppe die M2-O3 und T-O3 Bindungsldngen durch Zunahme von Ca und Al^IV kleiner bzw. größer werden, sind in der zweiten Gruppe die T-O3 Bindungslängen trotz niedrigen Al^IV Gehaltes zu einer Vergrößerung gezwungen, damit um die O3 Atome der lokale Ladungsausgleich erhalten bleibt.Es ist bemerkenswert, daß die Sunda-Klinopyroxene große Analogien zu denen aus basaltischen Gesteinen des Abessinischen Plateaus und aus K-reichen Laven sowohl der Römischen Provinz als auch des Westafrikanischen Grabens zeigen. Dies spiegelt Ähnlichkeiten zwischen Zusammensetzung und Mineralbestand der Muttergesteine wider, obwohl sie all aus tektonisch unterschiedlichen Positionen kommen.Eine Beziehung zwischen intrakristalliner Mg-Fe²⁺ Unordnung und dem explosiven Charakter des Vulkanismus wird aufgezeigt.

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Compositional variation in Hg-bearing sphalerite from the polymetallic Eskay Creek deposit, British Columbia, Canada   总被引：1，自引：0，他引：1  

Tassos A. Grammatikopoulos  Oleg Valeyev  Tina Roth 《Chemie der Erde / Geochemistry》2006,66(4):307-314

The Eskay Creek, British Columbia, Canada, is a polymetallic, gold- and silver-rich, volcanic-hosted, massive sulfide deposit. The ore in the deposit is divided into subzones distinguished by mineralogy, texture, grade and metallurgical characteristics. This study presents the results of a mineralogical examination of three composite field samples, with emphasis on the chemistry of sphalerite. Sphalerite is associated with variable amounts of Hg-tetrahedrite and cinnabar, and an array of sulfides, sulphosalts and non-opaque minerals. Electron micro probe analyses of sphalerite in the three composite samples reveal wide variations in compositions. The Hg content in sphalerite in the three samples varies between 0.08 and 16.35 wt%, whereas the Fe content ranges from 0.33 to 2.29 wt%. The chemical formula of the sphalerite shows the compositional range (Zn_0.89–0.98Hg_0.01–0.09.Fe_0.005–0.02)S. Sphalerite exhibits an almost perfect substitution of Hg and Zn, as shown by the negative covariance between them. Sphalerite with the highest Hg contents tends to have the lowest Fe concentrations. The highest Hg contents in sphalerite are recorded in the samples with the highest bulk Hg concentrations and with the highest cinnabar contents.

The compositional variations of sphalerite are important because they can be used in mapping ore forming fluids and indicate possible temporal variations. Second, determination of the compositional variation of the sphalerite in the mine has metallurgical implications because the mineral is an important Zn source. The mineralogical data indicate that non-physical processes (e.g. pyrometallurgy) must be used to separate Hg from Zn concentrates, with direct environmental implications, that is, release of metals, such as Hg, into the environment during mining and processing.  相似文献   

Lower crustal melting and the role of open-system processes in the genesis of syn-orogenic quartz diorite–granite–leucogranite associations: constraints from Sr–Nd–O isotopes from the Bandombaai Complex, Namibia     

Tina van de Flierdt  Stephan Hoernes  Stefan Jung  Peter Masberg  Edgar Hoffer  Urs Schaltegger  Hans Friedrichsen 《Lithos》2003,67(3-4):205-226

The Bandombaai Complex (southern Kaoko Belt, Namibia) consists of three main intrusive rock types including metaluminous hornblende- and sphene-bearing quartz diorites, allanite-bearing granodiorites and granites, and peraluminous garnet- and muscovite-bearing leucogranites. Intrusion of the quartz diorites is constrained by a U–Pb zircon age of 540±3 Ma.

Quartz diorites, granodiorites and granites display heterogeneous initial Nd- and O isotope compositions (_{Nd (540 Ma)}=−6.3 to −19.8; δ¹⁸O=9.0–11.6‰) but rather low and uniform initial Sr isotope compositions (⁸⁷Sr/⁸⁶Sr_initial=0.70794–0.70982). Two leucogranites and one aplite have higher initial ⁸⁷Sr/⁸⁶Sr ratios (0.70828–0.71559), but similar initial _Nd (−11.9 to −15.8) and oxygen isotope values (10.5–12.9‰). The geochemical and isotopic characteristics of the Bandombaai Complex are distinct from other granitoids of the Kaoko Belt and the Central Zone of the Damara orogen. Our study suggests that the quartz diorites of the Bandombaai Complex are generated by melting of heterogeneous mafic lower crust. Based on a comparison with results from amphibolite-dehydration melting experiments, a lower crustal garnet- and amphibole-bearing metabasalt, probably enriched in K₂O, is a likely source rock for the quartz diorites. The granodiorites/granites show low Rb/Sr (<0.6) ratios and are probably generated by partial melting of meta-igneous (intermediate) lower crustal sources by amphibole-dehydration melting. Most of the leucogranites display higher Rb/Sr ratios (>1) and are most likely generated by biotite-dehydration melting of heterogeneous felsic lower crust. All segments of the lower crust underwent partial melting during the Pan-African orogeny at a time (540 Ma) when the middle crust of the central Damara orogen also underwent high T, medium P regional metamorphism and melting. Geochemical and isotope data from the Bandombaai Complex suggest that the Pan-African orogeny in this part of the orogen was not a major crust-forming episode. Instead, even the most primitive rock types of the region, the quartz diorites, represent recycled lower crustal material.  相似文献   

Hot Spots of Nitrification in the Elbe Estuary and Their Impact on Nitrate Regeneration     

Tina Sanders  Andreas Schöl  Kirstin Dähnke 《Estuaries and Coasts》2018,41(1):128-138

Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L^?1, respectively), and nitrification rates in this region were up to 7 μmol L^?1 day^?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate.  相似文献   

Conjoint modeling of residential group preferences: A comparison of the internal validity of hierarchical information integration approaches     

Eric J.E. Molin  Harmen Oppewal  Harry J.P. Timmermans 《Journal of Geographical Systems》2002,4(4):343-358

 In this paper, two approaches for measuring residential group preferences, based on the method of Hierarchical Information Integration (HII), are compared. In particular, the hypothesis that group-based preference models estimated from integrated HII experiments better predict group preferences than part individual-based group models estimated from classical HII experiments is tested. To that effect, the models' ability to predict group preferences for new residential alternatives is compared in a study of residential preferences of co-ops. Results indicate that integrated HII group experiments indeed result in better predictions of residential preferences.  相似文献   

镇江市运河滑坡机理分析     

梁敬方  唐末林 《上海国土资源》1993,(4):19-25

镇江市古运河边岸滑坡干扰了城市交通、航运和河道整治工程的正常运行。本文研究了城市边岸的工程环境、滑坡形态、特有的城市地质环境恶化所诱发的边岸破坏机制及其稳定性,它对我同城市水陆交通发展所导致的斜坡地质灾害及其治理有实用价值。  相似文献   

利用树轮宽度重建黄河源区1618—2009年5—6月最高气温   总被引：1，自引：0，他引：1  

叶秣麟  秦宁生  白爱娟  李金建  李媛媛  赵艺 《气候变化研究进展》2015,(2):86-92

利用采集自青海省雪山乡的祁连圆柏建立树轮宽度标准年表,将标准年表与黄河源区内4个气象站各气象要素作相关分析,结果显示整个源区5—6月最高气温与标准年表相关性最显著,相关系数为-0.65。根据相关分析结果,重建了黄河源区1618—2009年5—6月最高气温距平序列,重建方程经过逐一剔除检验,方差解释量达42.2%,具有一定的可靠性。重建序列在近400年间先后经历了8个较暖时间段和8个较冷时间段,暖期时段有1644—1656、1727—1746、1786—1797、1817—1835、1860—1885、1916—1934、1952—1968和1992—2005年,冷期的时段分别为1632—1643、1657—1696、1747—1764、1798—1816、1836—1859、1898—1915、1935—1951和1969—1991年。对比本次重建序列与杂多、青藏高原东部以及长江源的气温重建序列,发现以上序列在公共时段变化趋势一致,另外,一些文献和历史记载也证实了此次重建的可靠性。  相似文献   

Deep-sea coral aragonite as a recorder for the neodymium isotopic composition of seawater     

Tina van de Flierdt  Laura F. Robinson 《Geochimica et cosmochimica acta》2010,74(21):6014-6032

Deep-sea corals have been shown to be useful archives of rapid changes in ocean chemistry during the last glacial cycle. Their aragonitic skeleton can be absolutely dated by U-Th data, freeing radiocarbon to be used as a water-mass proxy. For certain species of deep-sea corals, the growth rate allows time resolution that is comparable to ice cores. An additional proxy is needed to exploit this opportunity and turn radiocarbon data into rates of ocean overturning in the past.Neodymium isotopes in seawater can serve as a quasi-conservative water-mass tracer and initial results indicate that deep-sea corals may be reliable archives of seawater Nd isotopes. Here we present a systematic study exploring Nd isotopes as a water-mass proxy in deep-sea coral aragonite. We investigated five different genera of modern deep-sea corals (Caryophyllia, Desmophyllum, Enallopsamia, Flabellum, Lophelia), from global locations covering a large potential range of Nd isotopic compositions. Comparison with ambient seawater measurements yields excellent agreement and suggests that deep-sea corals are reliable archives for seawater Nd isotopes.A parallel study of Nd concentrations in these corals yields distribution coefficients for Nd between seawater and coral aragonite of 1-10, omitting one particular genus (Enallopsamia). The corals and seawater did however not come from exactly the same location, and further investigations are needed to reach robust conclusions on the incorporation of Nd into deep-sea coral aragonite.Lastly, we studied the viability of extracting the Nd isotope signal from fossil deep-sea corals by carrying out stepwise cleaning experiments. Our results show that physical removal of the ferromanganese coating and chemical pre-cleaning have the highest impact on Nd concentrations, but that oxidative/reductive cleaning is also needed to acquire a seawater Nd isotope signal.  相似文献