Evaluation of approaches to calculate debris-flow parameters for hazard assessment   总被引：2，自引：0，他引：2  

Marcel Hürlimann  Dieter Rickenmann  Vicente Medina  Allen Bateman 《Engineering Geology》2008,102(3-4):152

Many different runout prediction methods can be applied to estimate the mobility of future debris flows during hazard assessment. The present article reviews the empirical, analytical, simple flow routing and numerical techniques. All these techniques were applied to back-calculate a debris flow, which occurred in 1982 at La Guingueta catchment, in the Eastern Pyrenees. A sensitivity analysis of input parameters was carried out, while special attention was paid to the influence of rheological parameters. We used the Voellmy fluid rheology for our analytical and numerical modelling, since this flow resistance law coincided best with field observations. The simulation results indicated that the “basal” friction coefficients rather affect the runout distance, while the “turbulence” terms mainly influence flow velocity. A comparison of the velocity computed on the fan showed that the analytical model calculated values similar to the numerical ones. The values of our rheological parameters calibrated at La Guingueta agree with data back-calculated for other debris flows. Empirical relationships represent another method to estimate total runout distance. The results confirmed that they contain an important uncertainty and they are strictly valid only for the conditions, which were the basis for their development. With regards to the simple flow routing algorithm, this methods could satisfactorily simulate the total area affected by the 1982 debris flow, but it was not able to directly calculate total runout distance and velocity. Finally, a suggestion on how different runout prediction methods can be applied to generate debris-flow hazard maps is presented. Taking into account the definition of hazard and intensity, the best choice would be to divide the resulting hazard maps into two types: “final hazard maps” and “preliminary hazard maps”. Only the use of numerical models provided final hazard maps, because they could incorporate different event magnitudes and they supplied output-values for intensity calculation. In contrast, empirical relationships and flow routing algorithms, or a combination of both, could be applied to create preliminary hazard maps. The present study only focussed on runout prediction methods. Other necessary tasks to complete the hazard assessment can be looked up in the “Guidelines for landslide susceptibility, hazard and risk zoning” included in this Special Issue.  相似文献   

Mobilization analysis of the dolmen of Dombate (Northwest Spain)     

Vicente Navarro  Luis E. Romera  ngel Yustres  Miguel Candel 《Engineering Geology》2008,100(1-2):59-68

This paper presents an analysis of the mobilization of the dolmen of Dombate, a megalithic monument situated in the Northwest of Spain. The study is founded on simple static principles, with the application of basic concepts of soil mechanics (soil reactions were computed by the reaction modulus method) and rock mechanics (a simple secant approach was adopted to model the contact between orthostats). In addition, a simplified geometric model for dolmens was adopted. On the basis of these concepts, a numerical solver able to provide quick estimations of the system's mobilization was developed. Using this tool, a number of sensitivity analyses were conducted to estimate the mobilization that could be caused by a conservation project currently under consideration. It was found that mobilization might be excessive, and therefore, a safer procedure is proposed. In short, this paper puts forth a new rational approach for archaeological practices which may help to estimate the possible consequences of excavations and rehabilitations on megalithic structures.  相似文献   

The passivation of calcite by acid mine water. Column experiments with ferric sulfate and ferric chloride solutions at pH 2   总被引：2，自引：1，他引：1  

Josep M. Soler  Marco Boi  Jos Luis Mogolln  Jordi Cama  Carlos Ayora  Peter S. Nico  Nobumichi Tamura  Martin Kunz 《Applied Geochemistry》2008,23(12):3579-3588

Column experiments, simulating the behavior of passive treatment systems for acid mine drainage, have been performed. Acid solutions (HCl or H₂SO₄, pH 2), with initial concentrations of Fe(III) ranging from 250 to 1500 mg L⁻¹, were injected into column reactors packed with calcite grains at a constant flow rate. The composition of the solutions was monitored during the experiments. At the end of the experiments (passivation of the columns), the composition and structure of the solids were measured. The dissolution of calcite in the columns caused an increase in pH and the release of Ca into the solution, leading to the precipitation of gypsum and Fe–oxyhydroxysulfates (Fe(III)–SO₄–H⁺ solutions) or Fe–oxyhydroxychlorides (Fe(III)–Cl–H⁺ solutions). The columns worked as an efficient barrier for some time, increasing the pH of the circulating solutions from 2 to 6–7 and removing its metal content. However, after some time (several weeks, depending on the conditions), the columns became chemically inert. The results showed that passivation time increased with decreasing anion and metal content of the solutions. Gypsum was the phase responsible for the passivation of calcite in the experiments with Fe(III)–SO₄–H⁺ solutions. Schwertmannite and goethite appeared as the Fe(III) secondary phases in those experiments. Akaganeite was the phase responsible for the passivation of the system in the experiments with Fe(III)–Cl–H⁺ solutions.  相似文献   

Controls of δS and δO in dissolved sulphate: Learning from a detailed survey in the Llobregat River (Spain)     

Neus Otero  Albert Soler  Àngels Canals 《Applied Geochemistry》2008

The S and O isotopic composition of dissolved SO₄, used as a tracer for SO₄ sources, was applied to the water of the Llobregat River system (NE Spain). The survey was carried out at 30 sites where surface water was sampled on a monthly basis over a period of 2a. The concentration of dissolved SO₄ varied from 20 to 1575 mg L⁻¹. Sulphur isotopic compositions clustered in two populations: one – 93% of the samples – had positive values with a mode of +9‰; the other had negative values and a mode of −5‰. Data for δ¹⁸O_SO4 showed a mean value of +11‰, with no bi-modal distribution, though lower values of δ¹⁸O corresponded to samples with negative δ³⁴S. These values can not be explained solely by the contribution of bedrock SO₄ sources: that is, sulphide oxidation and the weathering of outcrops of sulphates, though numerous chemical sediments exist in the basin. Even in a river with a high concentration of natural sources of dissolved SO₄, such as the Llobregat River, the δ³⁴S values suggest that dissolved SO₄ is controlled by a complex mix of both natural and anthropogenic sources. The main anthropogenic sources in this basin are fertilizers, sewage, potash mine effluent and power plant emissions. Detailed river water sampling, together with the chemical and isotopic characterisation of the main anthropogenic inputs, allowed determination of the influence of redox processes, as well as identification of the contribution of natural and anthropogenic SO₄ sources and detection of spatial variations and seasonal changes among these sources. For instance, in the Llobregat River the input of fertilisers is well marked seasonally. Minimum values of δ³⁴S are reported during fertilization periods – from January to March – indicating a higher contribution of this source. The dual isotope approach, δ³⁴S and δ¹⁸O, is useful to better constrain the sources of SO₄. Moreover, in small-scale studies, where the inputs are well known and limited, the mixing models can be enhanced and the contribution of the different sources can be quantified to some extent.  相似文献   

Equilibrium constants of triethanolamine in major seawater salts     

I. Brandariz  P. Castro  M. Montes  F. Penedo  M.E. Sastre de Vicente 《Marine Chemistry》2006,102(3-4):291-299

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.  相似文献   

Zooplankton variability and climatic anomalies from 1994 to 2001 in the Balearic Sea (Western Mediterranean)     

Fernandez de Puelles  M. Luz; Valencia  Joaquin; Vicente  Laura 《ICES Journal of Marine Science》2004,61(4):492-500

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Application of FLATModel, a 2D finite volume code, to debris flows in the northeastern part of the Iberian Peninsula   总被引：7，自引：3，他引：4  

Vicente Medina  Marcel Hürlimann  Allen Bateman 《Landslides》2008,5(1):127-142

FLATModel is a two-dimensional shallow-water approximation code with corrections and modifications that create a simulation tool adapted to debris-flows behaviour. FLATModel uses the finite volume method with the numerical implementation of the Godunov scheme and includes correction terms regarding the effect of flow over high slopes and curvature. Additionally, the stop-and-go phenomenon, the basal entrainment and a correction regarding the front inclination of the final deposit are incorporated into FLATModel. In addition, different flow resistance laws were integrated in the numerical code including Bingham, Herschel–Bulkley and Voellmy fluid model. Firstly, our numerical model was validated using analytical solutions of a dam-break scenario and published data on a laboratory experiment. Secondly, three real events, which occurred in the northeastern part of the Iberian Peninsula, were back-calculated. Although field observations of the three events are not very detailed, the back-analyses revealed interesting patterns on the flow dynamics, and the numerical results generally showed good agreement with field data. Comparing the different flow resistance laws, the Voellmy fluid model presents the best behaviour regarding both the flow behaviour and the deposit characteristics. Preliminary simulation runs incorporating the effect of basal entrainment offered satisfactory results, although the final volume is rather sensitive on the selected friction angle of channel-bed material. The outcomes regarding the correction of the calculated front inclination of the final deposit showed that this implementation strongly improves the simulation results and better represents steep fronts of final deposits.  相似文献   

Observations Of Nocturnal Drainage Flow In A Shallow Gully     

M.R. Soler  C. Infante  P. Buenestado  Larry Mahrt 《Boundary-Layer Meteorology》2002,105(2):253-273

The formation of cold air drainage flows in a shallow gully is studied during CASES-99 (Cooperative Atmosphere-Surface Exchange Study). Fast and slow response wind and temperature measurements were obtained on an instrumented 10-m tower located in the gully and from a network of thermistors and two-dimensional sonic anemometers, situated across the gully. Gully flow formed on clear nights even with significant synoptic flow. Large variations in surface temperature developed within an hour after sunset and in situ cooling was the dominant factor in wind sheltered locations. The depth of the drainage flow and the height of the down-gully wind speed maximum were found to be largest when the external wind speed above the gully flow is less than 2 m s^-1. The shallow drainage current is restricted to a depth of a few metres, and is deepest when the stratification is stronger and the external flow is weaker. During the night the drainage flow breaks down, sometimes on several occasions, due to intermittent turbulence and downward fluxes of heat and momentum. The near surface temperature may increase by 6 ° C in less than 30 min due to the vertical convergence of downward heat flux. The mixing events are related to acceleration of the flow above the gully flow and decreased Richardson number. These warming events also lead to warming of the near surface soil and reduction of the upward soil heat flux. To examine the relative importance of different physical mechanisms that could contribute to the rapid warming, and to characterize the turbulence generated during the intermittent turbulent periods, the sensible heat budget is analyzed and the behaviour of different turbulent parameters is discussed.  相似文献   

A profile of General Carlos Ibáñez e Ibáñez de Ibero: first president of the International Geodetic Association     

T. Soler 《Journal of Geodesy》1997,71(3):176-188

 The exploits of the multifaceted scientist (engineer-geodesist-metrologist) General Carlos Ibá?ez e Ibá?ez de Ibero (1825–1891), Marqués de Mulhacén, are recounted. A bibliography of his relevant work is included. Received 27 September 1996; Accepted 2 October 1996  相似文献   

A mass transfer model of bauxite formation   总被引：1，自引：0，他引：1  

Josep M. Soler  Antonio C. Lasaga 《Geochimica et cosmochimica acta》1996,60(24):4913-4931

The formation of bauxite due to weathering of a granitic protolith has been simulated by means of a one-dimensional flow and reaction model based on the mass transfer principle. The model couples mineral dissolution and precipitation reactions, speciation in solution, and advective solute transport in a porous medium. A very important aspect of the modeling study is the use of mineral reaction rates determined experimentally in the laboratory. The important effects of solution saturation state and pH have been incorporated into the kinetic rate laws governing the heterogeneous reactions. The values of these parameters have been obtained from the scientific literature to guarantee that realistic reaction rates are used in the simulations. Albite and quartz are the minerals that make up the parent rock in the model. Gibbsite, kaolinite, and a Na-mica (as a surrogate for smectite) are the secondary minerals that have been taken into account. Long-term simulations (>1 Ma) have been run, and the formation of a bauxitic profile, with an upper gibbsite-rich and a lower kaolinite-rich zone, is predicted. In early stages of the process (up to a few hundreds of thousands of years), both gibbsite and kaolinite precipitate directly from solution as a consequence of albite dissolution. In later stages, the bulk of gibbsite precipitation derives from the incongruent dissolution of kaolinite, while kaolinite precipitation is still caused by the dissolution of albite. This is also reflected by the formation of two reaction fronts in the profile. These results are compared with weathering sequences from the Los Pijiguaos bauxite deposit, Venezuela. The overlap between the gibbsite and kaolinite zones and the replacement of kaolinite by gibbsite are consistent with model calculations. Mechanical denudation has to be called upon to explain the limited thicknesses of the weathering profiles in the field. The role of mechanical erosion is supported by the presence of microsedimentary structures in the bauxite and the balance between dissolved and suspended loads in the streams draining the area.  相似文献