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Secular Geochemistry of Central Puerto Rican Island Arc Lavas: Constraints on Mesozoic Tectonism in the Eastern Greater Antilles 总被引：2，自引：0，他引：2
JOLLY WAYNE T.; LIDIAK EDWARD G.; DICKIN ALAN P.; WU TSAI-WAY 《Journal of Petrology》2001,42(12):2197-2214
Island arc volcanism in the Greater Antilles persisted for >70m.y. from Middle Cretaceous to Late Eocene time. During theinitial 50 m.y., lavas in central Puerto Rico shifted from predominantlyisland arc tholeiites (volcanic phase I, Aptian to Early Albian,120–105 Ma), to calc-alkaline basalts (phase II, LateAlbian, 105–97 Ma), and finally to high-K, incompatible-element-enrichedbasalts (phases III and IV, Cenomanian–Maastrichtian,97–70 Ma). Following an island-wide eruptive hiatus, geochemicaltrends were reversed in the Eocene with renewed eruption ofcalc-alkaline basalts (phase V, 60–45 Ma). Progressiveincreases in large-ion lithophile elements (LILE)/light rareearth elements (LREE), LILE/high field strength elements (HFSE),LREE/HFSE, and HFSE/heavy rare earth elements (HREE) characterizethe compositional evolution of the first four volcanic phases.The shift in trace element compositions is mirrored by increasingradiogenic content of the lavas. Pb 相似文献
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WAYNE AHR 《Geology Today》1985,1(3):84-89
Environmental processes such as tides, waves, storms, drought and flood leave tell–tale responses in sedimentary deposits. Careful study of modern environments and their standard depositional sequences has led to sophisticated reconstruction of ancient sedimentary environments. Only recently have 'ideal' carbonate rock sequences been constructed and used to interpret geological history. When the lateral array of contemporaneous carbonate sequences is known, it becomes possible to trace the evolutionary history of continents and ocean basins. 相似文献
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The Portage Lake Lava Series of the Keweenaw Peninsula, northernMichigan, is composed of over 5000 m of tholeiitic lava flows.Chemical and petrologic study of thin undifferentiated flowsfrom this sequence shows that the bulk of the flows are olivinetholeiites; highly ironenriched tholeiites comprise up to 10per cent of the volume. In addition, a few small rhyolitic intrusives,exceedingly rich in alkalis, are exposed in the region. Duringburial the amygdular tops of each flow acted as channelwaysfor migrating fluids during a regional metamorphic event thatproduced a progressive sequence of secondary phases within theflow tops. In the upper part of the stratigraphic section, laumontite,analcime, albite, and chlorite dominate assemblages characteristicof the zeolite facies. Stratigraphically deeper. flow tops arecharacterized by metamorphic assemblages of the prehnite-pumpellyitefacies. Within the higher rank facies, rocks along fractureshave been transformed to calcium-rich monomineralic domains(metadomains) of epidote or pumpellyite. These metadomains gradeoutward through incompletely reconstituted rocks containingalbitized feldspars, and finally, in flow centers, to basaltdisplaying few signs of mineralogical readjustment. Extremechemical disparity exists within the altered flow tops, particularlywith respect to calcium and sodium content. Calculations revealthat bulk compositions of metamorphically adjusted flow topsare similar to unaltered basalts. Thus, the chemical variationdisplayed by the metamorphic rock types resulted from localizedmetamorphic differentiation. The Keweenawan sequence displays progressive dehydration fromthe top to the base of the stratigraphic section. At the topchlorite (H2O = 12 per cent) and pumpellyite (H2O = 6 per cent)metadomains formed by dehydration. The fact that most of theserocks were hydrated strongly suggests that fluid pressures wereless than total pressures during the metamorphic event. In rocksundergoing hydration in the uper part of the stratigraphic section,therefore, water pressures decreased away from channelways.As a result, the most hydrous rock types formed in these regions.Conversely, in rock undergoing dehydration water pressures increasedaway from channelwasys, so that the most dehydrated rocks formedin such regions. Water content of an individual rock is dependenton both position in the stratigraphic pile and position withrespect to fluid channelways. 相似文献
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WAYNE R. ROUSE MARIANNE S. V. DOUGLAS ROBERT E. HECKY ANNE E. HERSHEY GEORGE W. KLING LANCE LESACK PHILIP MARSH MICHAEL MCDONALD BARBARA J. NICHOLSON NIGEL T. ROULET JOHN P. SMOL 《水文研究》1997,11(8):873-902
Region 2 comprises arctic and subarctic North America and is underlain by continuous or discontinuous permafrost. Its freshwater systems are dominated by a low energy environment and cold region processes. Central northern areas are almost totally influenced by arctic air masses while Pacific air becomes more prominent in the west, Atlantic air in the east and southern air masses at the lower latitudes. Air mass changes will play an important role in precipitation changes associated with climate warming. The snow season in the region is prolonged resulting in long-term storage of water so that the spring flood is often the major hydrological event of the year, even though, annual rainfall usually exceeds annual snowfall. The unique character of ponds and lakes is a result of the long frozen period, which affects nutrient status and gas exchange during the cold season and during thaw. GCM models are in close agreement for this region and predict temperature increases as large as 4°C in summer and 9°C in winter for a 2 × CO2 scenario. Palaeoclimate indicators support the probability that substantial temperature increases have occurred previously during the Holocene. The historical record indicates a temperature increase of > 1°C in parts of the region during the last century. GCM predictions of precipitation change indicate an increase, but there is little agreement amongst the various models on regional disposition or magnitude. Precipitation change is as important as temperature change in determining the water balance. The water balance is critical to every aspect of hydrology and limnology in the far north. Permafrost close to the surface plays a major role in freshwater systems because it often maintains lakes and wetlands above an impermeable frost table, which limits the water storage capabilities of the subsurface. Thawing associated with climate change would, particularly in areas of massive ice, stimulate landscape changes, which can affect every aspect of the environment. The normal spring flooding of ice-jammed north-flowing rivers, such as the Mackenzie, is a major event, which renews the water supply of lakes in delta regions and which determines the availability of habitat for aquatic organisms. Climate warming or river damming and diversion would probably lead to the complete drying of many delta lakes. Climate warming would also change the characteristics of ponds that presently freeze to the bottom and result in fundamental changes in their limnological characteristics. At present, the food chain is rather simple usually culminating in lake trout or arctic char. A lengthening of the growing season and warmer water temperature would affect the chemical, mineral and nutrient status of lakes and most likely have deleterious effects on the food chain. Peatlands are extensive in region 2. They would move northwards at their southern boundaries, and, with sustained drying, many would change form or become inactive. Extensive wetlands and peatlands are an important component of the global carbon budget, and warmer and drier conditions would most likely change them from a sink to a source for atmospheric carbon. There is some evidence that this may be occurring already. Region 2 is very vulnerable to global warming. Its freshwater systems are probably the least studied and most poorly understood in North America. There are clear needs to improve our current knowledge of temperature and precipitation patterns; to model the thermal behaviour of wetlands, lakes and rivers; to understand better the interrelationships of cold region rivers with their basins; to begin studies on the very large lakes in the region; to obtain a firm grasp of the role of northern peatlands in the global carbon cycle; and to link the terrestrial water balance to the thermal and hydrological regime of the polar sea. Overall, there is a strong need for basic research and long-term monitoring. © 1997 John Wiley & Sons, Ltd. 相似文献
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MICHAEL D. CHEETHAM ANNABELLE F. KEENE RICHARD T. BUSH LEIGH A. SULLIVAN WAYNE D. ERSKINE 《Sedimentology》2008,55(6):1905-1913
Grain‐size distribution is a fundamental tool for interpreting sedimentary units within depositional systems. The techniques assessed in this study are commonly used to determine grain‐size distributions for sand‐dominated sediments. However, the degree of consistency and differences in interpretation when using a combination of grain‐size methods have not yet been assessed systematically for sand‐dominated fluvial sediments. Results obtained from laser diffraction, X‐ray attenuation and scanning electron microscopy grain‐size analysis techniques were compared with those obtained from the traditional sieve/hydrometer method. Scanning electron microscopy was shown to provide an inaccurate quantitative analysis of grain‐size distributions because of difficulties in obtaining representative samples for examination. The X‐ray attenuation method is unsuitable for sand‐dominated sediments because of its upper size range of only 300 μm. The consistently strong correlation between the laser diffraction results and the sieve/hydrometer results shows that these methods are comparable for sand‐dominated fluvial sediments. Provided that sample preparation is consistent, the latter two methods can be used together within a study of such sediments while maintaining a high degree of accuracy. These results indicate that data for sand‐dominated fluvial sediments gained from the long‐established sieve/hydrometer method can be compared with confidence to those obtained by modern studies using laser diffraction techniques. 相似文献
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A new thermobarometer, based on the equilibrium:
has been calibrated with experiments carried out in the piston-cylinderapparatus. Reversed equilibria were obtained using well-calibrated2.54 cm NaCl furnace assemblies and Ag80Pd20capsules with fO2bufferedat or near iron-wustite. The equilibrium is located between5.2–5.4, 6.6–6.8, and 8.6–8.8 kb at 880, 940,and 1020?C, respectively, and at 5.2 and 8.8 kb between 865–880and 1020–1030?C, respectively. X-ray refinement data indicate that the hercynite (a = 8.15546?) has approximately 18 per cent inverse character. M?ssbauerspectra reveal that 4 mol per cent of the Fe is ferric (2 percent magnetite component). Broad Mossbauer lines and a Fe2+energy level splitting of 3.7 kJ mol–1 calculated fromthe Mossbauer spectra are consistent with the X-ray determineddegree of inversion, although no separate octahedral Fe2+ spectraldoublet is resolved. Calibration of this equation allows calculation of the equilibrium:
Thermobarometers based on the above equilibria are widely applicablein granulite fades rocks and yield pressure/temperature datathat are consistent with other well-calibrated barometers andthermometers. 相似文献
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Holocene and post‐European settlement alluvial histories of three nested drainage basins were reconstructed from detailed litho‐ and chronostratigraphy of cut and fill terraces and flood‐plains in the upper Wollombi Brook catchment. Fernances Creek (13.8 km2) valley fill consisted of intercalated thin mud sheets deposited in ephemeral swamps and thick sand sheets deposited by discontinuous channels. Dairy Arm (39.8 km2) valley fill was more complex, with inset alluvial fills in the upper basin and overlapping vertically stacked fills in the lower basin. However, correlative lithostrati‐graphic units were not found on all tributaries. Furthermore, basal radiocarbon dates on the last inset fill of four tributaries did not overlap, allowing for plus or minus twice the standard deviation of the reported ages. Wollombi Brook (341 km2) valley fill was also complex, with longitudinally discontinuous units, most of which were not found in the two tributaries. Upstream late Holocene channel incision was coeval with downstream chain of ponds because sediment generated by incision was stored in the intervening valley. Historical channel incision occurred between 1838 and 1867 on Fernances Creek at a locally steeper section of valley floor during the period of peak population and frequent floods immediately after a road crossing was constructed, but coincided with a catastrophic flood on Dairy Arm (June 1949) and on Wollombi Brook (1927). Lack of correlative litho‐ and chronostrati‐graphic units plus out‐of‐phase post‐European incision indicate that stratigraphic complexity is a function of geomorphic complexity due to the operation of geomorphic thresholds and complex response. 相似文献
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WAYNE OSBORN DAVID MATTY MICHAEL VELBEL PETER BROWN JOHN WACKER 《Meteoritics & planetary science》1997,32(6):781-790
Abstract— A 0.5 kg stony meteorite associated with a bright bolide seen over southeastern Michigan on 1994 October 20 has been recovered. The circumstances of the fall and recovery of this chondrite, named Coleman, are presented. The most likely trajectory from the observations of the event implies preatmospheric orbital parameters typical of meteorites. Gamma-ray spectrometry of the cosmogenic radionuclides showed that the recovered mass was an interior fragment of a larger body and revealed abnormally high 22Na and 26Al activity. Electron microprobe analysis yielded compositions of Fa24.1 and Fs20.3, which are consistent with an L-chondrite classification. Petrographically, the presence of chondrules, the observed mineralogy and the degree of chondrule-matrix integration suggests assignment to petrologic type 6. 相似文献