Kaleidoscoping Landscapes,Shifting Perspectives     

Kenneth R. Young  Richard Aspinall 《The Professional geographer》2006,58(4):436-447

Landscapes change in complex ways, creating surface patterns reminiscent of forms seen through a kaleidoscope. On the Earth's surface, those forms are linked to, and caused by, processes that originate with bedrock‐soil‐vegetation‐atmosphere interactions. Human‐caused alterations to landscapes are additionally tied to socioeconomic processes. Evaluation of landscape‐level processes can benefit from examining (1) the influence of disturbance regimes in altering landscape patterns, (2) the importance of considering surficial processes, (3) the subtle and cryptic spatial relations that may be present, (4) the reciprocal relationships among local processes and regional consequences, (5) the increased likelihood of some land cover transitions compared to others, and (6) the special case of landscapes with long histories of human use. These are all examples of potential fruitful arenas for interactions and represent a path for expansion of landscape ecology through accommodation of a broad range of content covered by the international GIScience community.  相似文献   

High spatial resolution hyperspectral mapping of in-stream habitats, depths, and woody debris in mountain streams     

W. Andrew Marcus  Carl J. Legleiter  Richard J. Aspinall  Joseph W. Boardman  Robert L. Crabtree 《Geomorphology》2003,55(1-4):363

This article evaluates the potential of 1-m resolution, 128-band hyperspectral imagery for mapping in-stream habitats, depths, and woody debris in third- to fifth-order streams in the northern Yellowstone region. Maximum likelihood supervised classification using principal component images provided overall classification accuracies for in-stream habitats (glides, riffles, pools, and eddy drop zones) ranging from 69% for third-order streams to 86% for fifth-order streams. This scale dependency of classification accuracy was probably driven by the greater proportion of transitional boundary areas in the smaller streams. Multiple regressions of measured depths (y) versus principal component scores (x₁, x₂,…, x_n) generated R² values ranging from 67% for high-gradient riffles to 99% for glides in a fifth-order reach. R² values were lower in third-order reaches, ranging from 28% for runs and glides to 94% for pools. The less accurate depth estimates obtained for smaller streams probably resulted from the relative increase in the number of mixed pixels, where a wide range of depths and surface turbulence occurred within a single pixel. Matched filter (MF) mapping of woody debris generated overall accuracies of 83% in the fifth-order Lamar River. Accuracy figures for the in-stream habitat and wood mapping may have been misleadingly low because the fine-resolution imagery captured fine-scale variations not mapped by field teams, which in turn generated false “misclassifications” when the image and field maps were compared.The use of high spatial resolution hyperspectral (HSRH) imagery for stream mapping is limited by the need for clear water to measure depth, by any tree cover obscuring the stream, and by the limited availability of airborne hyperspectral sensors. Nonetheless, the high accuracies achieved in northern Yellowstone streams indicate that HSRH imagery can be a powerful tool for watershed-wide mapping, monitoring, and modeling of streams.  相似文献   

Assessing infrequent large earthquakes using geomorphology and geodesy: the Malawi Rift     

Michael Hodge  Juliet Biggs  Katsuichiro Goda  Willy Aspinall 《Natural Hazards》2015,76(3):1781-1806

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Formic and acetic acids in atmospheric condensate in Wilmington,North Carolina     

Joan D. Willey  Carol A. Wilson 《Journal of Atmospheric Chemistry》1993,16(2):123-133

Formic and acetic acids occurred in atmospheric condensate with concentrations similar to rainwater collected in Wilmington, North Carolina, during the sampling period from June to October of 1990. Atmospheric concentrations of these acids (calculated from the condensate concentrations) were higher in continental versus maritime air masses. Concentrations of formic and acetic acids were correlated with each other in both condensate and air. Traffic was a source of acetic acid and of bisulfite to atmospheric condensate in this study.  相似文献   

Exposure assessment using high spatial resolution hyperspectral (HSRH) imagery     

G.M. Jacquez  W. Andrew Marcus  Richard J. Aspinall  Dunrie A. Greiling 《Journal of Geographical Systems》2002,4(1):1-14

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Photobleaching of chromophoric dissolved organic matter (CDOM) in rainwater   总被引：1，自引：0，他引：1  

Robert J. Kieber  Joan D. Willey  Robert F. Whitehead  Seth N. Reid 《Journal of Atmospheric Chemistry》2007,58(3):219-235

Significant photodegradation of chromophoric dissolved organic matter (CDOM) in rainwater was observed after exposure to simulated sunlight. Fluorescence excitation emission spectra (EEMS) of precipitation revealed the presence of four major peaks all of which degraded upon photolysis with the greatest loss in the region characteristic of marine CDOM. Photobleaching of absorbance also occurred in the wavelength region between 250 and 375 nm with the greatest loss of absorbance in the upper end of the UV-A region near 275 nm. There was a strong positive correlation between absorbance loss and total integrated fluorescence loss suggesting these optical properties and the degree to which they are photobleached in rainwater are directly related. The quantum yield of CDOM photodegradation in rainwater decreased dramatically with increasing wavelength and decreasing energy of incoming radiation with the average quantum yield at 325 nm approximately an order of magnitude greater than at 460 nm. The similarity of photolytic response between rainwater and Cape Fear estuarine CDOM indicates that some fraction of the compounds that make up rainwater CDOM may be derived from surface sources and/or that the processes that produce or modify humic-like substances in the atmosphere result in similar types of compounds as non-atmospheric processes.  相似文献   

The partial molal volume of silicic acid in 0.725 m NaCl     

Iver W Duedall  Ramesh Dayal  Joan D Willey 《Geochimica et cosmochimica acta》1976,40(10):1185-1189

The partial molal volume ($\text{V}\text{?}$) of silicic acid in 0.725 m NaCl at 20°C has been calculated from (1) direct volume changes due to the dissolution of anhydrous sodium silicate and (2) some literature values for the partial molal volumes of NaOH and water. , unconnected for electrostriction effects, was found to be 53 ± 2 ml mole^?1. , corrected for volume changes due to solvent electrostriction by charged Si species, was estimated to be in the range 58–62 ml mole^?1; this range is 7–11 ml mole^?1 greater than the calculated from Willey's (Mar. Chem. 2, 239–250, 1974) solubility data obtained from the dissolution, in seawater, of amorphous silica subjected to hydrostatic pressure. Our does, however, agree within experimental error with the calculated from Jones and Pytkowicz's (Bull. Soc. Roy. Sci. Liege 42, 118–120, 1973) data for the solubility of amorphous silica in seawater at high pressure and is nearly in agreement with Willey's (Ph.D. thesis, Dalhousie University, 1975) solubility data for amorphous silica in 0.6 m NaCl.  相似文献   

Trends in Abundance Indices of Fishes in Maryland’s Coastal Bays During 1972–2009     

Jennifer Pincin  Michael J. Wilberg  Lora Harris  Angel Willey 《Estuaries and Coasts》2014,37(4):791-800

Maryland’s coastal bays provide habitat for juveniles of many commercially and recreationally important species of shellfish and finfish. Since 1972, the Maryland Department of Natural Resources has conducted the Maryland Coastal Bays Trawl and Seine Survey to monitor the populations of key species. The survey has undergone substantial spatial and methodological changes affecting the interpretation of simple indices of abundance. We developed generalized linear models to standardize the indices of abundance of five commonly caught fish species: Atlantic menhaden Brevoortia tyrannus, weakfish Cynoscion regalis, spot Leiostomus xanthurus, bay anchovy Anchoa mitchilli, and summer flounder Paralichthys dentatus. Density declined significantly since 1972 for menhaden, bay anchovy, and spot in at least one region within the coastal bays. The northern bays had significantly higher densities than the southern bays for all species. Changes in abundance indices of the five species examined were not related to sea grass coverage, temperature, salinity, nitrogen-to-phosphorus ratios, and other habitat variables but were likely a result of stock-wide recruitment processes.  相似文献   

The effect of seawater magnesium on natural fluorescence during estuarine mixing,and implications for tracer applications     

Joan D. Willey 《Marine Chemistry》1984,15(1):19-45

Natural fluorescence, which is thought to result from low molecular weight humic and fulvic compounds, can be used as a tracer to distinguish between individual river waters. Natural fluorescence exhibits conservative mixing with seawater, except for a slight fluorescence increase which is sometimes observed in the low salinity range (0–5‰). This increase is not due to the inner filter effect (internal quenching). Laboratory experiments can reproduce this low-salinity natural fluorescence increase. Of the major seawater ions, only magnesium can cause a similar natural fluorescence increase. Variation in sample pH, ionic strength, or particle content cannot explain the natural fluorescence increase, nor does it appear to be related to the estuarine flocculation of humic material. Addition of seawater magnesium to the fluorescent material with subsequent loss of hydrogen ions could enhance fluorescence by adding crosslinking to the structure. Replacement of a fluorescence-depressing metal like copper or iron by magnesium could also enhance fluorescence, essentially by removing the quenching effect of the metal. Experimental data in this study are consistent with both of these possible mechanisms. Calcium also enhances fluorescence, however the effect of seawater calcium during estuarine mixing is not as apparent as the magnesium effect. The implications of this low-salinity natural fluorescence increase with respect to estuarine and coastal tracer applications depend on whether individual rivers mix in the high or low salinity region of an estuary or coastal area.  相似文献   

The effect of pressure on the solubility of amorphous silica in seawater at 0°C     

Joan D. Willey   《Marine Chemistry》1974,2(4):239-250

The solubility of amorphous silica in seawater at 0°C and from 1 to 1,220 atm. was found to be a linear function of pressure above 270 atm., but to deviate from linearity below that pressure. Using a quadratic derivation of Planck's equation, ΔV for the dissolution was found to be −16.5 cm³mole⁻¹, and Δk was found to be −4.4 · 10⁻² cm³ mole⁻¹ atm⁻¹∂Δk/∂P was found to be 27.2 · 10⁻⁵ cm³ mole⁻¹ atm⁻² which is too significant a factor to allow the commonly made assumption that ∂Δk/∂P =0. North's (1973) model of hydration suggests that this non-zero ∂Δk/∂P may indicate that the silicic acid molecule is more extensively hydrated at lower pressures.If the pressure in an experiment is suddenly lowered to atmospheric pressure after equilibrium solubility had been attained at the higher pressure, the precipitation that occurs to reduce the resulting supersaturation is complete within one hour in the experimental system used in this study.  相似文献