High-sensitive measurement of uranium L_III-edge X-ray absorption near-edge structure (XANES) for the determination of the oxidation states of uranium in crustal materials     

Yuhei Yamamoto  Yoshio Takahashi  Yutaka Kanai  Yoshio Watanabe  Tomoya Uruga  Hajime Tanida  Yasuko Terada  Hiroshi Shimizu   《Applied Geochemistry》2008,23(8):2452-2461

The uranium L_III-edge XANES spectra for natural rocks at the concentration range of 0.96–124 mg kg⁻¹ were measured using a log spiral bent crystal Laue analyzer (BCLA) combined with a multi-element Ge detector. It was found that the quality of the XANES spectra using the BCLA was greatly improved due to a reduction of interfering fluorescence from major components such as Rb and Sr. The ratio of signal to background intensities in the U L_III-edge XANES spectra increased by a factor of 2.9–17 with the use of the BCLA, which greatly enhanced the detection limit for the speciation of the oxidation states of U or the U(IV)/U(VI) ratio of natural samples. In addition, it was demonstrated that the fluorescence XANES method coupled with the BCLA enable determination of the speciation of U for various natural samples such as acidic igneous rocks, ferromanganese nodules, sediments, and some sedimentary rocks such as shale and limestone.  相似文献   

Modeling households’ decisions on reconstruction of houses damaged by earthquakes––Japanese case study     

H. Sakakibara  H. Murakami  S. Esaki  D. Mori  H. Nakata 《Natural Hazards》2008,44(2):293-303

In this study, households’ decisions on reconstruction of damaged houses were modeled, using questionnaire data in Japan. Characteristics of households’ decisions were investigated using parameter estimation results. The effects of subsidizing policy were evaluated as follows. First, subsidy for rebuilding may be effective for the households whose houses were heavily damaged. Second, there is a possibility that subsidy accelerated rebuilding of houses by the households having children. Third, subsidy for rebuilding may not be effective for elderly people’s households and households in depopulated areas.  相似文献   

Satellite detection of red tide in Ariake Sound, 1998–2001     

Joji Ishizaka  Yasuhisa Kitaura  Yasuharu Touke  Hiroaki Sasaki  Akihiko Tanaka  Hiroshi Murakami  Toshikazu Suzuki  Kazumi Matsuoka  Hideaki Nakata 《Journal of Oceanography》2006,62(1):37-45

High resolution SeaWiFS data was used to detect red tide events that occurred in the Ariake Sound, Japan, a small embayment known as one of the most productive areas in Japan. SeaWiFS chlorophyll data clearly showed that a large red tide event, which damaged seaweed (Nori) cultures, started early in December 2000 in Isahaya Bay, expanded to the whole sound and persisted to the end of February 2001. The monthly average of SeaWiFS data from May 1998 to December 2001 indicated that the chlorophyll peaks appeared twice a year, in early summer and in fall, after the peaks of rain and river discharge. The SeaWiFS data showed that the red tide event during 2000–2001 winter was part of the fall bloom; however, it started later and continued significantly longer than other years. Satellite ocean color data is useful to detect the red tide; however the algorithms require improvement to accurately estimate chlorophyll in highly turbid water and in red tide areas.  相似文献   

The northward intruding eddy along the East coast of Korea   总被引：5，自引：0，他引：5  

Yutaka Isoda  Sei-ichi Saitoh 《Journal of Oceanography》1993,49(4):443-458

The current structures and their seasonal variations in the East Korean Warm Current (EKWC) region, which plays a significant role in the northward transport of warm and saline waters, were described by combining the sea surface temperature (SST) data of consecutive satellite inferred (IR) images and hydrographic data. The SST patterns in winter-spring clearly showed that the small meander of thermal front originating from the Tsushima/Korea Strait formed close to the Korean coast and grew an isolated warm eddy with horizontal dimension of order 100 km. Such warm eddy began to intrude slowly northward from spring to summer. At that time, interactions with neighboring synoptic warm eddy [Ks] around the Ulleung Basin were found to have strongly influence the movement of the intruding eddy and its structural change. In autumn, after the northward movement stopped at the north of eddy [Ks], the relative stable northward current along the Korean coast were formed. The evidence from observational results does not support a persistent branching of the EKWC from the Tsushima/Korea Strait, but a seasonal episodic supply of warm and saline waters due to the northward intruding eddy process described above.  相似文献   

Total amount of oceanic excess CO2 taken from the North Pacific subpolar region     

Yutaka W. Watanabe  Yoshiyuki Takahashi  Takashi Kitao  Koh Harada 《Journal of Oceanography》1996,52(3):301-312

Concentrations of total carbonate, alkalinity and dissolved oxygen were obtained near the 1973 GEOSECS stations in the North Pacific subpolar region north of 40°N along 175°E between 1993 and 1994. A difference of excess CO₂ content between the GEOSECS and our expeditions was estimated. The maximum difference in water column inventory of excess CO₂ has increased by about 280 gC m^–2 above 2000 m depth which apparently means an uptake of excess CO₂ taken from air to sea during the last two decades. An averaged value of the annual flux of excess CO₂ at 75–1000 m depth was 8.63±2.01 gC m^–2yr^–1 in the North Pacific subpolar region. By introducing the annual flux of excess CO₂ into a two-box model for the North Pacific subpolar region, a penetration factor of excess CO₂ from air to sea was obtained to be 1.08×10^–2 gC m^–3ppm^–1 in the North Pacific subpolar region. Based on this factor, the surface concentration of excess CO₂ in the North Pacific subpolar region was estimated to be 68 mole I^–1, suggesting that the North Pacific subpolar region absorbed atmospheric excess CO₂ more than the saturated concentration of excess CO₂. Total amount of excess CO₂ taken from the North Pacific subpolar region by 1993 was estimated to be 36.2×10¹⁵ gC, which was equal to about one tenth of that released by human activities after the preindustrial era.  相似文献   

A Preliminary Study of Oceanic Bomb Radiocarbon Inventory in the North Pacific during the Last Two Decades     

Yutaka W. Watanabe  Tsuneo Ono  Koh Harada  Masao Fukasawa 《Journal of Oceanography》1999,55(6):705-716

Radiocarbon and total carbonate data were obtained near the 1973 GEOSECS stations in the North Pacific along 30°N and along 175°E between 1993 and 1994. In these stations, we estimated radiocarbon originating from atomic bomb tests using tritium, trichlorofluoromethane and silicate contents. The average penetration depth of bomb radiocarbon during the two decades has deepened from 900 m to 1300 m. Bomb radiocarbon inventories above the average value for the whole North Pacific were found widely in the western subtropical region around 30°N both in the 1970s and 1990s, and its area in the 1990s was broader than that in the 1970s. In most of the North Pacific, while the bomb radiocarbon has decreased above 25.4, the bomb radiocarbon flux below 25.4 was over 1 × 10¹² atom m^-2yr^-1 in the subtropical region around 30°N. In the tropical area south of 20°N, the bomb radiocarbon inventory below 25.4 increased from zero to over 10 × 10¹² atom m^-2 during the last three decades. These distributions suggest that the bomb radiocarbon removed from the surface is currently accumulated with bomb ¹⁴C flux of over 1 × 10¹² atom m^-2yr^-1 below 25.4 in the subtropical region, mainly by advection from the higher latitude, and that part of the accumulated bomb ¹⁴C gradually spread southward with about 30 years.  相似文献   

Seasonal variations of water system distribution and flow patterns in the southern sea area of Hokkaido,Japan     

Ana Luisa Rosa  Yutaka Isoda  Kazuyuki Uehara  Tomokazu Aiki 《Journal of Oceanography》2007,63(4):573-588

Hydrographic data and composite current velocity data (ADCP and GEK) were used to examine the seasonal variations of upper-ocean flow in the southern sea area of Hokkaido, which includes the “off-Doto” and “Hidaka Bay” areas separated by Cape Erimo. During the heating season (April–September), the outflow of the Tsugaru Warm Current (TWC) from the Tsugaru Strait first extends north-eastward, and then one branch of TWC turns to the west along the shelf slope after it approaches the Hidaka Shelf. The main flow of TWC evolves continuously, extending eastward as far as the area off Cape Erimo. In the late cooling season (January–March), part of the Oyashio enters Hidaka Bay along the shallower part of the shelf slope through the area off Cape Erimo, replacing almost all of the TWC water, and hence the TWC devolves. It is suggested that the bottom-controlled barotropic flow of the Oyashio, which may be caused by the small density difference between the Oyashio and the TWC waters and the southward migration of main front of TWC, permits the Oyashio water to intrude along the Hidaka shelf slope.  相似文献   

Generation mechanism of higher mode nondispersive shelf waves by wind forcing     

Yutaka Isoda 《Journal of Oceanography》1993,49(5):535-549

The higher mode predominance in the current velocity fields associated with wind-induced shelf waves in the nondispersive regime is studied with a special attention to the effect of the geographical boundary, e.g. wide strait or wide bank areas. The effect of such large topographic change is represented by wind forcing with a finite dimension near the geographical boundary. The time development processes of the wind-induced shelf waves is examined in the context of an initial-value problem, where a spatially finite wind stress is applied att=0. Various modes of shelf waves excited at the boundary start propagating simultaneously and develop monotonically within the forcing region. After the passage of such wave, the energy of wind is used to maintain the attained equilibrium condition, i.e. the steady shelf circulation. The current evolution of the lower mode is restricted to the earlier stage because of the large propagation speed. In contrast, the higher mode waves can travel slowly within the forcing region so that the kinetic energy is supplied from wind stress for a long time before the equilibrium condition is established. Consequently, the observation at the fixed point near the geographical boundary would show that the higher mode waves gradually dominate as time goes on, i.e. for the long-term forcing.  相似文献   

Annual Anthropogenic Carbon Transport into the North Pacific Intermediate Water through the Kuroshio/Oyashio Interfrontal Zone: An Estimation from CFCs Distribution     

Tsuneo Ono  Yutaka W. Watanabe  Katsuyuki Sasaki 《Journal of Oceanography》2000,56(6):675-689

Vertical distribution of anthropogenic carbon content of the water (exDIC) in the Oyashio area just outside of the Kuroshio/Oyashio Interfrontal Zone (K/O Zone) was estimated by the simple 1-D advection-diffusion model calibrated by the distribution of chlorofluorocarbons (CFCs). The average concentration of exDIC for = 26.60–27.00 is multiplied by the volume transport of Oyashio water into the North Pacific Intermediate Water (NPIW) to estimate the annual transport of exDIC into NPIW through K/O Zone. The estimated transport of exDIC was 0.018–0.020 GtC/y, which corresponds to 15% of the whole total exDIC accumulation in the temperate North Pacific. A simple assessment using the NPIW 1-box model indicates that the current study explains at least 70% of the total annual transport of exDIC into NPIW, and that small exDIC sources for NPIW still exists in addition to K/O Zone.  相似文献   

Some features of jump in water temperature in aSargassum forest   总被引：1，自引：0，他引：1  

Teruhisa Komatsu  Shin-ichi Murakami  Hideo Kawai 《Journal of Oceanography》1996,52(1):109-124

To clarify the influence of aSargassum forest on water temperature distributions observations were made inside and outside aSargassum forest off the Nagata Shore on the northern Saiki Bay open to the Bungo Channel on the Pacific side of Kyushu, Japan. About sixty thermistor probes were deployed at 0.5 m depth intervals from the bottom to the sea surface at seven stations spaced at 50–80 m distances along two transects: one inside the forest and the other outside. Water temperature was measured at five minutes intervals from 6 to 9 August 1987 with thermistor probes. The spatial standing crop distribution of theSargassum forest along the transects was investigated. A water temperature jump of about 2°C, recorded during the observation, is probably caused by an intrusion of a warm water mass from the central Bungo Channel to Saiki Bay. The water temperature jump under theSargassum forest on the rough bottom with stones occurred one to two hours behind that outside the forest (sandy bed) although the distance between the transects inside and outside the forest was only 50–80 m. It is suggested that theSargassum forest and the rough bottom would prevent intruding warm water from smoothly replacing cold water due to resistance of theSargassum species and the bottom to a current.  相似文献