Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

小波分析理论在GPS技术中的应用     

ZHENG Zuoya HUANG Cheng LU Xiushan 《中国科学院上海天文台年刊》2003,(1)

在GPS数据处理中 ,存在着误差影响、影响波的干扰、周跳和数据量大等问题。误差影响和影响波的干扰实质是在接收卫星信号时受到其它因素的影响 ;周跳是由于卫星信号的失锁而造成信号的不连续 ;数据量大是因为GPS观测需要采样间隔小又连续观测所致。由于小波理论具有时频分析、波形分解、特征提取和快速小波变换等特性 ,应用小波变换和波形分解可以解决误差影响和影响波的干扰的问题 ;应用特征提取可以解决周跳检测问题 ;应用快速小波变换可进行数据压缩  相似文献   

基于PowerBuilder的信息系统的权限控制     

罗卫敏 《成都信息工程学院学报》2004,19(2):209-213

针对信息系统安全的考虑,介绍在PowerBuilder环境中对用户权限的具体控制.  相似文献   

从ROSAT数据中寻找河内X射线暂现源     

卢方军  孙学军 《中国天文和天体物理学报》1997,(3)

从ＲＯＳＡＴ巡天和定点观测结果的对比出发，发现了几个低银纬的巡天源表中的Ｘ射线源在定点观测中没有出现．本文计算了在这些位置的定点观测中出现点源的流强上限，发现比巡天源表中这些源的流强值低很多，这表明它们的流强变化很大，可能是Ｘ射线双星系统中的一类———Ｘ射线暂现源．  相似文献   

The nature of parallax microlensing events towards the Galactic bulge     

Martin C. Smith  Vasily Belokurov  N. Wyn Evans  Shude Mao  Jin H. An 《Monthly notices of the Royal Astronomical Society》2005,361(1):128-140

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GPS中BOC调制的FPGA实现     

刘音华  卢晓春  边玉敬 《时间频率学报》2006,29(1):35-42

GPS系统中提出了一种新的信号形式,二进制偏移载波(BOC)调制是这种新的信号形式产生的技术关键。首先介绍了BOC调制的定义及其频谱特性,然后阐述了基于FPGA(现场可编程门阵列)硬件平台的BOC调制实现方法,并给出了仿真波形。结果表明,该实现方法是值得提倡的。  相似文献   

黑洞吸积盘的演化及温度分布的热不稳定性     

汪定雄  杨兰田  陆烨 《中国天文和天体物理学报》1994,(4)

本文在Ｔｈｏｒｎｅ工作的基础上讨论了吸积盘中黑洞的有关参量的演化，以及由Ｓｃｈｗａｒｚｓｃｈｉｌｄ黑洞吸积盘向Ｋｅｒｒ黑洞吸积盘演化过程中对吸积盘辐射通量的影响，最后针对几个典型的辐射过程，分别讨论了黑洞吸积盘在牛顿框架中的温度分布方程与广义相对论的温度分布方程的热不稳定性，并给出此类问题的热不稳定性的判据。  相似文献   

利用核对软件降低MARK IV格式磁带回放数据的误码率     

LU Chunmei 《中国科学院上海天文台年刊》2003,(1)

由于磁带回放的不稳定性及磁带与处理机的不匹配 ,导致由磁带导入硬盘的数据误码率很高 ,影响了送入处理机的数据可用率。结果显示 ,采用核对软件能将数据可用率提高一个数量级  相似文献   

STUDY ON BEIJING''''S EMERGING MOBILE COMMUNICATION INDUSTRIAL CLUSTER AND ITS POLICY IMPLICATIONS   总被引：1，自引：0，他引：1  

SUN Tie-shan  LI Guo-ping  LU Ming-hua 《中国地理科学(英文版)》2003,13(2)

1INTRODUCTIONClusters,definedasgeographicallyproximategroupsofinterconnectedcompaniesandassociatedinstitutionsinparticularfields,linkedbycommonalitiesandcomple-mentarities(PORTER,2000),havearousedanintenseinterestofurbanandregionalplanningresearchersandpolicymakersoverthepastdecades.Itiswidelyrecog-nizedthatclusterscanpromoteproductivityandinno-vation,developlocalcompetitiveadvantages.Popular-izedbyMichaelPORTERinhisbook“TheCompetitiveAdvantageofNationsin1990,theclusterisnotanewcon…  相似文献   

桂东南宁潭岩体地质特征及其构造环境初探     

陆济璞  蔡贺清 《南方国土资源》2002,15(4):11-16

宁潭岩体是由马田、亭子、陈冲、老虎头 4个单元组成的遭受了变形变质改造的花岗岩复式岩体。岩石学、岩石化学、地球化学特征反映该岩体属后碰撞强过铝花岗岩。其源区既包含有不成熟的富含长英质物质的特性 ,也有成熟的、富含粘土的特性。岩体的形成温度为 85 0～ 92 5℃ ,同位素年龄为 35 4～ 4 4 0Ma。可能是加里东期扬子板块与华夏板块碰撞后 ,在拉伸构造作用下岩浆底辟侵位而成  相似文献