Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

对地方电视台转播CCTV时延的测定     

任燕  梁双有 《时间频率学报》1997,(1)

讲述了同步广播卫星电视时间信号的测量方法和测量结果，获得了CCTV1、CCTV2通过同一颗卫星（亚太－1A）转播的时延差值为16333μs，测量精度在10ns以内；CCTV2、CCTV4分别经两颗卫星（亚太－1A、亚洲－Ⅱ）转播，在陕西天文台卫星地面接收站时延差值为1644．20μs，精度为50μs，并分析了影响时延差值和精度的原因。同时测量了地方电视台转播亚太－1A的CCTV信号与直接接收亚太－1A的CCTV信号的时延差值，其测量精度为0．1μs。这些结果为利用同步广播卫星的电视信号进行高精度的时间服务提供了参考依据。  相似文献   

基于J2EE架构的企业卡资源管理系统的设计与实现     

任建豪  李成忠 《成都信息工程学院学报》2005,20(5):566-570

介绍了J2EE架构和多层体系结构的发展，在B／S三层架构的基础上给出了包含应用服务器中间件的多层分布式应用体系结构，并把此体系结构应用于电信氽业的有价卡管理系统项目中。分析了此项同的功能结构和体系结构，采用J2EE开发平台和技术设计实现了由浏览器、Web服务器、应用服务器、数据库服务器组成的多层体系架构。  相似文献   

海岩小说的几种叙述模式及弊端     

姚国军  李霞 《广东海洋大学学报》2006,26(5):87-90

海岩的长篇小说《河流如血》再创出版高记录，但作家仍局限于特有的小说叙述模式，这部作品设能做到相应的创新。概言之，模式第一面是“刑侦＋恋爱”；模式第二面是“财子＋佳人”；模式第三面是“道德＋法制”。文学创作需要不断创新，创新的过程也是对创作模式的不断突破过程。作家应该警惕的是，不要让模式成为创作的桎梏。  相似文献   

Tidal effects on temperature front in the Yellow Sea   总被引：5，自引：0，他引：5  

Ma Jian  Qiao Fangli  Xia Changshui  Yang Yongzeng 《中国海洋湖沼学报》2004,22(3):314-321

Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades in autumn as thermocline declines. TF intensity ⋎S _T ⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the TF. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).  相似文献   

PALEOSOLS　OF　SANDY　LANDS　AND　ENVIRONMENTAL　CHANGES　IN　THE　WESTERN　PART　OF　NORTHEAST　PLAIN　OF　CHINA　WESTERN　DURING　HOLOCENE     

裘善文  李取生  夏玉梅  王景璐 《中国地理科学(英文版)》1995,5(2):137-148

ＰＡＬＥＯＳＯＬＳＯＦＳＡＮＤＹＬＡＮＤＳＡＮＤＥＮＶＩＲＯＮＭＥＮＴＡＬＣＨＡＮＧＥＳＩＮＴＨＥＷＥＳＴＥＲＮＰＡＲＴＯＦＮＯＲＴＨＥＡＳＴＰＬＡＩＮＯＦＣＨＩＮＡＷＥＳＴＥＲＮＤＵＲＩＮＧＨＯＬＯＣＥＮＥ￥ＱｉｕＳｈａｎｗｅｎ（裘善文）ＬｉＱｕｓ...  相似文献   

Remarks on dynamical ellipticity at the Earth's     

C. Z. Zhang  Y. F. Xia 《Earth, Moon, and Planets》1994,65(3):269-276

In this paper, two factors — the redistribution of the density and the variation in the angular velocity of the Earth rotation, that affect the adopted value of the flattening for equidensity surface within the Earth, are discussed. The computational results show that the contribution of the redistribution of the density in the Earth interior (especially in the core) on the change of the flattening at the core-mantle boundary (CMB) is marginal, and that the calculated value of the flattening at the CMB can be in good agreement with the VLBI observed value so long as the fact that the angular velocity of the Earth rotation has undergone the tidal evolution is taken into account. As a result, this paper presents a set of recommended values of the dynamical parameters of the Earth (see Table III) for computing Earth's forced nutation series.  相似文献   

巴颜喀拉山东段及其邻区大地电磁测深成果地质解释     

庞存廉  方胜  夏元祁 《青海国土经略》1996,(1)

本文主要依据青海省囊歉至大河坝大地电磁测深成果,并结合重力资料对巴颜喀拉及南北两侧地区的壳幔结构进行了地质解释。指出了该区壳幔存在4个明显的低阻层,并简述了它们的形态特征,推断了其地质含意。认为昆中断裂带与昆南断裂带间是一个巨大的构造混杂岩带,影响深度亦很大。推断该区可能存在太古代地层。划出了8条壳幔断裂带,认为昆中断裂应是塔里木—华北板块与华南板块的分界线。  相似文献   

Simulation of double cold cores of the 35°N section in the Yellow Sea with a wave-tide-circulation coupled model   总被引：1，自引：0，他引：1  

Xia Changshui  Qiao Fangli  Zhang Mengning  Yang Yongzeng  Yuan Yeli 《中国海洋湖沼学报》2004,22(3):292-298

Based on the MASNUM wave-tide-circulation coupled numerical model, the temperature structure along 35°N in the Yellow Sea was simulated and compared with the observations. One of the notable features of the temperature structure along 35°N section is the double cold cores phenomena during spring and summer. The double cold cores refer to the two cold water centers located near 122°E and 125°E from the depth of 30m to bottom. The formation, maintenance and disappearance of the double cold cores are discussed. At least two reasons make the temperature in the center (near 123°E) of the section higher than that near the west and east shores in winter. One reason is that the water there is deeper than the west and east sides so its heat content is higher. The other is invasion of the warm water brought by the Yellow Sea Warm Current (YSWC) during winter. This temperature pattern of the lower layer (from 30m to bottom) is maintained through spring and summer when the upper layer (0 to 30m) is heated and strong thermocline is formed. Large zonal span of the 35°N section (about 600 km) makes the cold cores have more opportunity to survive. The double cold cores phenomena disappears in early autumn when the west cold core vanishes first with the dropping of the thermocline position. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).  相似文献   

Researches in China on the Effects of Tides on the Earth Rotation     

Naiyuan Xiao  Yifei Xia 《Celestial Mechanics and Dynamical Astronomy》2003,87(1-2):3-12

In this paper the tidal phenomena on the Earth are concisely specified, including solid tides, ocean tides and atmospheric tides due to the luni-solar tide-generating force, and the Earth pole tide due to the motion of the Earth's rotation axis (polar motion); as well as their effects on the Earth rotation. The outcomes of scientific researches of Chinese astronomers on these topics are described in some detail. These researches deal with the mechanisms responsible for tidal effects on the earth rotation, and on the measurements of the Earth rotation parameters. Finally, the effects discovered by Chinese researchers on the measurements of the period and change in period of pulsars are discussed. These effects are very small in magnitude but not negligible.  相似文献